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金属有机骨架及其复合材料在分离领域中的应用进展

张晓琼 ,  汪彤 ,  王培怡 ,  姚伟 ,  丁明玉

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引用本文: 张晓琼,  汪彤,  王培怡,  姚伟,  丁明玉. 金属有机骨架及其复合材料在分离领域中的应用进展[J]. 色谱, 2016, 34(12): 1176-1185. doi: 10.3724/SP.J.1123.2016.08018 shu
Citation:  ZHANG Xiaoqiong,  WANG Tong,  WANG Peiyi,  YAO Wei,  DING Mingyu. Application of metal-organic frameworks and their composites in separation[J]. Chinese Journal of Chromatography, 2016, 34(12): 1176-1185. doi: 10.3724/SP.J.1123.2016.08018 shu

金属有机骨架及其复合材料在分离领域中的应用进展

  • 1.

    北京市劳动保护科学研究所, 城市有毒有害易燃易爆危险源控制技术 北京市重点实验室, 北京 100054;

  • 2.

    清华大学化学系, 北京 100084

  • 基金项目:

    国家科技支撑计划课题项目（2015BAK16B00）；国家自然科学基金项目（21575076）；国家自然科学基金创新团队项目（21621003；北京市科委科研项目（D161100002116001）；北京市财政项目（PXM2016_178304_000026，PXM2016_178304_000027）.

摘要: 金属有机骨架（MOFs）是一类由无机金属离子与有机配体自组装形成的新型有机-无机杂化多孔材料，因具有比表面积超高、结构多样、热稳定性良好、孔道尺寸和性质可调等优势，在分离领域表现出重要的应用价值。然而，采用传统方法制备的MOFs多为粒径在微米或亚微米尺度的晶体，且颗粒形貌不规则，因此限制了MOFs在样品前处理和色谱固定相等领域的应用和发展。构建基于MOFs的复合材料是弥补MOFs应用缺陷的一项有效措施，有望在保留MOFs优越的分离特性的同时，引入基体材料的特定性能。该文简要综述了近年来MOFs及其复合材料在吸附、样品前处理和色谱固定相等分离领域中的应用进展，并对MOFs在分离科学中的应用前景做出展望。

English

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  • 收稿日期:  2016-08-17
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