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高稳定性金属有机骨架UiO-66的合成与应用

韩易潼 ,  刘民 ,  李克艳 ,  左轶 ,  张国亮 ,  张宗超 ,  郭新闻

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引用本文: 韩易潼, 刘民, 李克艳, 左轶, 张国亮, 张宗超, 郭新闻. 高稳定性金属有机骨架UiO-66的合成与应用[J]. 应用化学, 2016, 33(4): 367-378. doi: 10.11944/j.issn.1000-0518.2016.04.150439 shu
Citation:  HAN Yitong, LIU Min, LI Keyan, ZUO Yi, ZHANG Guoliang, ZHANG Zongchao, GUO Xinwen. Preparation and Application of High Stability Metal-Organic Framework UiO-66[J]. Chinese Journal of Applied Chemistry, 2016, 33(4): 367-378. doi: 10.11944/j.issn.1000-0518.2016.04.150439 shu

高稳定性金属有机骨架UiO-66的合成与应用

  • 1.

    a 大连理工大学化工学院, 宾州-大连联合能源研究中心, 精细化工重点实验室 辽宁 大连 116024;

  • 2.

    b 浙江工业大学生物与环境工程学院 杭州 310014;

  • 3.

    c 中国科学院大连化学物理研究所, 洁净能源国家实验室 辽宁 大连 116023

    • 通讯作者: 郭新闻,教授;Tel/Fax:0411-84986133;E-mail:guoxw@dlut.edu.cn;研究方向:纳米孔材料,新催化反应工艺
  • 基金项目:

    国家自然科学基金重点项目（21236008) 

    中央高校基本科研业务费（2342013DUT13RC（3）704）以及中国博士后科学基金（2014M551094）资助 

摘要: 金属有机骨架（metal-organic frameworks，MOFs）是一种由金属中心与有机配体自组装而成的、具有三维网状有序孔结构的新型多孔晶体材料，其具有超高的比表面积、种类和结构多样性、可化学功能化等特点，在多个研究领域显示出了潜在的应用前景，已成为当前化学、材料学科的研究热点之一。然而大多数MOFs材料的稳定性较差，极大地束缚了MOFs材料的发展。以Zr为金属中心，对苯二甲酸为有机配体的UiO-66具有较好的热稳定性，结构可在500 ℃保持稳定，并且其还具有很高的耐酸性和一定的耐碱性，引起了人们的关注。本文主要综述了UiO-66在合成调控、功能化合成和后改性方面的研究现状，以及其在吸附和催化等领域的应用前景。

English

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  • 收稿日期:  2015-12-09
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