共掺稀土离子对Er<sup>3+</sup>激活中红外激光晶体光谱性能的影响

引用本文: 张保童, 王燕, 李坚富, 游振宇, 夏侯平, 朱昭捷, 徐金龙, 涂朝阳, 王鸿雁. 共掺稀土离子对Er³⁺激活中红外激光晶体光谱性能的影响[J]. 应用化学, 2016, 33(9): 994-1001. doi: 10.11944/j.issn.1000-0518.2016.09.160231 shu

Citation: ZHANG Baotong, WANG Yan, LI Jianfu, YOU Zhenyu, XIA Houping, ZHU Zhaojie, XU Jinlong, TU Chaoyang, WANG Hongyan. Effect of Co-Dopant Rare-Earth Ions on the Spectroscopic Properties of Er³⁺ Activated Mid-Infrared Laser Crystals[J]. Chinese Journal of Applied Chemistry, 2016, 33(9): 994-1001. doi: 10.11944/j.issn.1000-0518.2016.09.160231 shu

共掺稀土离子对Er³⁺激活中红外激光晶体光谱性能的影响

张保童 ^a,b, ,
王燕 ^{a,
,} ,
李坚富 ^a, ,
游振宇 ^a, ,
夏侯平 ^a, ,
朱昭捷 ^a, ,
徐金龙 ^a, ,
涂朝阳 ^a, ,
王鸿雁 ^c,

1.
a 中国科学院福建物质结构研究所, 中国科学院光电材料化学与物理重点实验室福州 350002;
2.
b 福建师范大学材料科学与工程学院福州 350007;
3.
c 青岛海泰光电技术有限公司山东青岛 266107

通讯作者: 王燕,副研究员;Tel:0591-83173412;Fax:0591-83173068;E-mail:wy@fjirsm.ac.cn;研究方向:晶体生长和性能

基金项目:
国家自然科学基金（51472240，91122033)

山东大学功能晶体材料及器件教育部重点实验室开放课题项目（JG1403)

中国科学院长春应化所稀土资源利用国家重点实验室开放课题基金（RERU2015018)

中国科学院福建物构所结构化学国家重点实验室（20160012）资助

摘要: Er³⁺掺杂的晶体能够产生2.7~3.0 μm波段中红外激光，在激光医疗、光通讯、环境探测和光电对抗等领域具有重要的应用。基于本课题组近年来开展的Er³⁺激活中红外激光晶体的相关工作，本文综述了共掺稀土离子对Er³⁺激活晶体光谱性能的影响：包括敏化离子Cr³⁺、Yb³⁺等的敏化作用增强了Er³⁺的特征吸收峰；退激活离子Pr³⁺、Ho³⁺等的退激活效应抑制了自终态瓶颈效应；以及共掺Nd³⁺所起的敏化和退激活双重作用，并对中红外激光的研究趋势和前景进行了展望。

关键词:

English

Effect of Co-Dopant Rare-Earth Ions on the Spectroscopic Properties of Er³⁺ Activated Mid-Infrared Laser Crystals

1.
a Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;
2.
b College of Material Science and Engineering, Fujian Normal University, Fuzhou 350007, China;
3.
c CRYSTECH Inc., Qingdao, Shandong 266107, China

Corresponding author: 王燕,副研究员;Tel:0591-83173412;Fax:0591-83173068;E-mail:wy@fjirsm.ac.cn;研究方向:晶体生长和性能

Received Date: 01 June 2016
Fund Project:
国家自然科学基金（51472240，91122033)

山东大学功能晶体材料及器件教育部重点实验室开放课题项目（JG1403)

中国科学院长春应化所稀土资源利用国家重点实验室开放课题基金（RERU2015018)

中国科学院福建物构所结构化学国家重点实验室（20160012）资助

Abstract: The Er³⁺-doped crystals can produce 2.7~3.0 μm mid-infrared(MIR) lasers, which have attracted much attention for their numerous applications in laser medical surgery, optical communication, enviromental detector and electro-optical countermeasure, etc. Based on the past few years' work on the study of Er³⁺ activated crystals by our team, we review the effect of co-dopant rare-earth ions on the spectroscopic properties of Er³⁺ activated MIR laser crystals, including the sensitizing ions Cr³⁺, Yb³⁺, etc. which can enhance the intensity of characteristic absorption peaks of Er³⁺; the deactivating ions Ho³⁺, Pr³⁺, etc. which can inhibit the self-termination bottleneck effects, furthermore, the co-dopant Nd³⁺ ion can play a dual role at the same time. In the end, the expectations on the study of MIR lasers are presented.

Key words:

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

共掺稀土离子对Er³⁺激活中红外激光晶体光谱性能的影响

通讯作者: 王燕,副研究员;Tel:0591-83173412;Fax:0591-83173068;E-mail:wy@fjirsm.ac.cn;研究方向:晶体生长和性能

English

Effect of Co-Dopant Rare-Earth Ions on the Spectroscopic Properties of Er³⁺ Activated Mid-Infrared Laser Crystals

Corresponding author: 王燕,副研究员;Tel:0591-83173412;Fax:0591-83173068;E-mail:wy@fjirsm.ac.cn;研究方向:晶体生长和性能

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中国化学会秘书处

共掺稀土离子对Er3+激活中红外激光晶体光谱性能的影响

通讯作者: 王燕,副研究员;Tel:0591-83173412;Fax:0591-83173068;E-mail:wy@fjirsm.ac.cn;研究方向:晶体生长和性能

English

Effect of Co-Dopant Rare-Earth Ions on the Spectroscopic Properties of Er3+ Activated Mid-Infrared Laser Crystals

Corresponding author: 王燕,副研究员;Tel:0591-83173412;Fax:0591-83173068;E-mail:wy@fjirsm.ac.cn;研究方向:晶体生长和性能

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

共掺稀土离子对Er³⁺激活中红外激光晶体光谱性能的影响

Effect of Co-Dopant Rare-Earth Ions on the Spectroscopic Properties of Er³⁺ Activated Mid-Infrared Laser Crystals

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs