引用本文:
韩景立, 陈健, 陆九芳, 何向明. 应用模式耦合理论求离子极限摩尔电导率[J]. 应用化学,
2003, 20(9): 845-848.
Citation: HAN Jing-Li, CHEN Jian, LU Jiu-Fang, HE Xiang-Ming. Application of Mode Coupling Theory to Calculation of the Ionic Limiting Molar Conductivity[J]. Chinese Journal of Applied Chemistry, 2003, 20(9): 845-848.
Citation: HAN Jing-Li, CHEN Jian, LU Jiu-Fang, HE Xiang-Ming. Application of Mode Coupling Theory to Calculation of the Ionic Limiting Molar Conductivity[J]. Chinese Journal of Applied Chemistry, 2003, 20(9): 845-848.
应用模式耦合理论求离子极限摩尔电导率
English
Application of Mode Coupling Theory to Calculation of the Ionic Limiting Molar Conductivity
Abstract:
The ion transfer number is introduced in the formula describing the relationship between ionic limiting molar conductivity and ionic concentration based on mode coupling theory(MCT). A series of calculated for the ionic limiting molar conductivity are present. The ionic limiting molar conductivities of seven lithium salts in two single organic solvents and two mixed solvents are calculated. The results are in good agreement with the literature's results which are calculated either from transport number obtained by empirical formula or from transport number obtained by electrochemiscal experiments.
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