引用本文:
邢欣, 李效东, 郭爱青, 曹峰, 鲍晓恒, 王军. 硅取代聚硅烷的合成与表征[J]. 应用化学,
2004, 21(9): 942-945.
Citation: XING Xin, LI Xiao-Dong, G UO Ai-Qing, CAO Feng, BAO Xiao-Heng, WANG Jun. Synthesis and Characterization of Silicon-substituted Polysilane(SPS)[J]. Chinese Journal of Applied Chemistry, 2004, 21(9): 942-945.
Citation: XING Xin, LI Xiao-Dong, G UO Ai-Qing, CAO Feng, BAO Xiao-Heng, WANG Jun. Synthesis and Characterization of Silicon-substituted Polysilane(SPS)[J]. Chinese Journal of Applied Chemistry, 2004, 21(9): 942-945.
硅取代聚硅烷的合成与表征
English
Synthesis and Characterization of Silicon-substituted Polysilane(SPS)
Abstract:
The silicon-substituted polysilane(SPS) as a novel class of polysilane was prepared by polymer reaction of polymethylsilane(PMS) with substitution degree being 43% and characterized by FT-IR,1H NMR,29Si CP MAS-NMR, UV and GPC techniques. The polymer is soluble in common organic solvents, and its molecular weight could be increased by crosslinking reaction.
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Key words:
- silicon-substituted polysilane
- / polymethylsilane
- / synthesis
- / polymer reaction
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