
Citation: GUO Hui-qing, XIE Li-li, WANG Xin-long, LIU Fen-rong, WANG Mei-jun, HU Rui-sheng. Sulfur removal and release behaviors of sulfur-containing model compounds during pyrolysis under inert atmosphere by TG-MS connected with Py-GC[J]. Journal of Fuel Chemistry and Technology, 2014, 42(10): 1160-1166.

TG-MS与Py-GC相结合法研究惰性气氛下含硫模型化合物热解过程中硫的脱除及释放行为研究
English
Sulfur removal and release behaviors of sulfur-containing model compounds during pyrolysis under inert atmosphere by TG-MS connected with Py-GC
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Key words:
- pyrolysis
- / sulfur release
- / sulfur-containing model compounds
- / TG-MS
- / Py-GC
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[1] HUANG C, LINKOUS C A, ADEBIYI O, T-RAISSIET A. Hydrogen production via photolytic oxidation of aqueous sodium sulfite solutions[J]. Environ Sci Technol, 2010, 44(13): 5283-5288.[1] HUANG C, LINKOUS C A, ADEBIYI O, T-RAISSIET A. Hydrogen production via photolytic oxidation of aqueous sodium sulfite solutions[J]. Environ Sci Technol, 2010, 44(13): 5283-5288.
-
[2] YU J, YIN F, WANG S, CHANG L, GUPTA S. Sulfur removal property of activated-char-supported Fe-Mo sorbents for integrated cleaning of hot coal gases[J]. Fuel, 2013, 108(6): 91-98.[2] YU J, YIN F, WANG S, CHANG L, GUPTA S. Sulfur removal property of activated-char-supported Fe-Mo sorbents for integrated cleaning of hot coal gases[J]. Fuel, 2013, 108(6): 91-98.
-
[3] YU J, CHANG L, XIE W, WANG D. Correlation of H2S and COS in the hot coal gas stream and its importance for high temperature desulfurization[J]. Korean J Chem Eng, 2011, 28(4): 1054-1057.[3] YU J, CHANG L, XIE W, WANG D. Correlation of H2S and COS in the hot coal gas stream and its importance for high temperature desulfurization[J]. Korean J Chem Eng, 2011, 28(4): 1054-1057.
-
[4] XU G, YANG Y, LU S, LI L,SONG X. Comprehensive evaluation of coal-fired power plants based on grey relational analysis and analytic hierarchy process[J]. Energy Policy, 2011, 39(5): 2343-2351.[4] XU G, YANG Y, LU S, LI L,SONG X. Comprehensive evaluation of coal-fired power plants based on grey relational analysis and analytic hierarchy process[J]. Energy Policy, 2011, 39(5): 2343-2351.
-
[5] ATTAR A. Chemistry, thermodynamics and kinetics of reactions of sulphur in coal-gas reactions: A review[J]. Fuel, 1978, 57(4): 201-212.[5] ATTAR A. Chemistry, thermodynamics and kinetics of reactions of sulphur in coal-gas reactions: A review[J]. Fuel, 1978, 57(4): 201-212.
-
[6] YAN J, YANG J, LIU Z. SH radical: The key intermediate in sulfur transformation during thermal processing of coal[J]. Environ Sci Technol, 2005, 39(13): 5043-5051.[6] YAN J, YANG J, LIU Z. SH radical: The key intermediate in sulfur transformation during thermal processing of coal[J]. Environ Sci Technol, 2005, 39(13): 5043-5051.
-
[7] MULLENS S, YPERMAN J, REGGERS G, CARLEERA R, BUCHANAN A.C, BRITT P F, RUTKOWSKI P, GRYGLEWICZ G. A study of the reductive pyrolysis behaviour of sulphur model compounds[J]. J Anal Appl Pyrolysis, 2003, 70(2): 469-491.[7] MULLENS S, YPERMAN J, REGGERS G, CARLEERA R, BUCHANAN A.C, BRITT P F, RUTKOWSKI P, GRYGLEWICZ G. A study of the reductive pyrolysis behaviour of sulphur model compounds[J]. J Anal Appl Pyrolysis, 2003, 70(2): 469-491.
-
[8] MAES II, GRYGLEWICZ G, YPERMAN J, FRANCO DV, D'HAES J, D'OLIESLAEGERS M, VAN POUKE LC. Effect of siderite in coal on reductive pyrolytic analyses[J]. Fuel, 2000, 79(15): 1873-1881.[8] MAES II, GRYGLEWICZ G, YPERMAN J, FRANCO DV, D'HAES J, D'OLIESLAEGERS M, VAN POUKE LC. Effect of siderite in coal on reductive pyrolytic analyses[J]. Fuel, 2000, 79(15): 1873-1881.
-
[9] MAES II, YPERMAN J, VAN DEN RUL H, FRANCO D V, MULLENS J, VAN POUCKE L C, GRYGLEWICZ G, WILK P. Study of coal-derived pyrite and its conversion products using atmospheric pressure temperature-programmed reduction (AP-TPR)[J]. Energy Fuels, 1995, 9(6): 950-955.[9] MAES II, YPERMAN J, VAN DEN RUL H, FRANCO D V, MULLENS J, VAN POUCKE L C, GRYGLEWICZ G, WILK P. Study of coal-derived pyrite and its conversion products using atmospheric pressure temperature-programmed reduction (AP-TPR)[J]. Energy Fuels, 1995, 9(6): 950-955.
-
[10] YI P, YU Q, ZONG H. The chemical thermodynamics analysis of pyrite desulfurization[J]. Coal Convers, 1999, 22(1): 48-52.[10] YI P, YU Q, ZONG H. The chemical thermodynamics analysis of pyrite desulfurization[J]. Coal Convers, 1999, 22(1): 48-52.
-
[11] SUGAWARA K, ENDA Y, SUGAWARA T, SHIRAI M. XANES analysis of sulfur form change during pyrolysis of coals[J]. Synchrot Radiat, 2001, 8(2): 955-957.[11] SUGAWARA K, ENDA Y, SUGAWARA T, SHIRAI M. XANES analysis of sulfur form change during pyrolysis of coals[J]. Synchrot Radiat, 2001, 8(2): 955-957.
-
[12] MIURA K, MAE K, SHIMADA M, MINAMI H. Analysis of formation rates of sulfur-containing gases during the pyrolysis of various coals[J]. Energy fuels, 2001, 15(3): 629-636.[12] MIURA K, MAE K, SHIMADA M, MINAMI H. Analysis of formation rates of sulfur-containing gases during the pyrolysis of various coals[J]. Energy fuels, 2001, 15(3): 629-636.
-
[13] XU L, YANG J, LI Y, LIU Z. Behavior of organic sulfur model compounds in pyrolysis under coal-like environment[J]. Fuel Process Technol, 2004, 85(8): 1013-1024.[13] XU L, YANG J, LI Y, LIU Z. Behavior of organic sulfur model compounds in pyrolysis under coal-like environment[J]. Fuel Process Technol, 2004, 85(8): 1013-1024.
-
[14] KARR JR C. Analytical methods for coal and coal products[J]. Academic Press,1979, 19(3): 588-624.[14] KARR JR C. Analytical methods for coal and coal products[J]. Academic Press,1979, 19(3): 588-624.
-
[15] [JP6]KATSUYASU S,KEIKO A, TAKUO S. Dynamic behavior of sulfur forms in rapid pyrolysis of density-separated coals[J]. Fuel, 1995, 74(12): 1823-1829.[15] [JP6]KATSUYASU S,KEIKO A, TAKUO S. Dynamic behavior of sulfur forms in rapid pyrolysis of density-separated coals[J]. Fuel, 1995, 74(12): 1823-1829.
-
[16] SUGAWARA K, TOZUKA Y, KAMOSHITA T, TAKUO S, MARK A S. Dynamic behaviour of sulfur forms in rapid pyrolysis of density-separated coals[J]. Fuel, 1994, 73(7): 1224-1228.[16] SUGAWARA K, TOZUKA Y, KAMOSHITA T, TAKUO S, MARK A S. Dynamic behaviour of sulfur forms in rapid pyrolysis of density-separated coals[J]. Fuel, 1994, 73(7): 1224-1228.
-
[17] LIU F, LI W, CHEN H, LI B. Uneven distribution of sulfurs and their transformation during coal pyrolysis[J]. Fuel, 2007, 86(3): 360-366.[17] LIU F, LI W, CHEN H, LI B. Uneven distribution of sulfurs and their transformation during coal pyrolysis[J]. Fuel, 2007, 86(3): 360-366.
-
[18] [JP5]刘粉荣, 郭慧卿, 胡瑞生, 赫淑颖, 胡浩权. 含硫模型化合物在不同载体上的担载及其燃烧过程硫的释放行为[J]. 化工进展, 2012, 31(11): 2570-2573.[18] [JP5]刘粉荣, 郭慧卿, 胡瑞生, 赫淑颖, 胡浩权. 含硫模型化合物在不同载体上的担载及其燃烧过程硫的释放行为[J]. 化工进展, 2012, 31(11): 2570-2573.
-
[19]
(LIU Fen-rong, GUO Hui-qing, HU Ru-sheng, HE Shu-ying, HU Hao-quan. A study on the loading behavior of sulfur-containg compounds on the different carriers and sulfur release behavior during combustion process[J]. Chemical Industry and Engineering Progress, 2012, 31(11): 2570-2573.)(LIU Fen-rong, GUO Hui-qing, HU Ru-sheng, HE Shu-ying, HU Hao-quan. A study on the loading behavior of sulfur-containg compounds on the different carriers and sulfur release behavior during combustion process[J]. Chemical Industry and Engineering Progress, 2012, 31(11): 2570-2573.)
-
[19] 刘粉荣, 李文, 李保庆, 陈皓侃. 氧化性气氛下流化床中煤的热解脱硫及硫的分布[J]. 燃料化学学报, 2006, 34(4): 404-407.[19] 刘粉荣, 李文, 李保庆, 陈皓侃. 氧化性气氛下流化床中煤的热解脱硫及硫的分布[J]. 燃料化学学报, 2006, 34(4): 404-407.
-
[21]
(LIU Fen-rong, LI Wen, CHEN Hao-kan, LI Bao-qing. Sulfur removal and its distribution during coal pyrolysis in fluidized bed reactor under oxidative atmospheres[J]. Journal of Fuel Chemistry and Technology, 2006, 34(4): 404-407.)(LIU Fen-rong, LI Wen, CHEN Hao-kan, LI Bao-qing. Sulfur removal and its distribution during coal pyrolysis in fluidized bed reactor under oxidative atmospheres[J]. Journal of Fuel Chemistry and Technology, 2006, 34(4): 404-407.)
-
[20] LIU F, LI W, CHEN H, LI B. Gas analysis and sulfur removal from coal during fluidized bed pyrolysis under different oxygen contents[C]. 2005 ICCS&T Okinawa, 2005-10.[20] LIU F, LI W, CHEN H, LI B. Gas analysis and sulfur removal from coal during fluidized bed pyrolysis under different oxygen contents[C]. 2005 ICCS&T Okinawa, 2005-10.
-
[21] 刘粉荣, 李文, 郭慧卿, 李保庆, 白宗庆, 胡瑞生. XPS法研究煤表面碳官能团的变化及硫迁移行为[J]. 燃料化学学报, 2011, 39(2): 81-84.[21] 刘粉荣, 李文, 郭慧卿, 李保庆, 白宗庆, 胡瑞生. XPS法研究煤表面碳官能团的变化及硫迁移行为[J]. 燃料化学学报, 2011, 39(2): 81-84.
-
[24]
(LIU Fen-rong, LI Wen, GUO Hui-qing, LI Bao-qing, BAI Zong-qing, HU Rui-sheng. XPS study on the change of carbon-containing groups and sulfur transformation on coal surface[J]. Journal of Fuel Chemistry and Technology, 2011, 39(2): 81-84.)(LIU Fen-rong, LI Wen, GUO Hui-qing, LI Bao-qing, BAI Zong-qing, HU Rui-sheng. XPS study on the change of carbon-containing groups and sulfur transformation on coal surface[J]. Journal of Fuel Chemistry and Technology, 2011, 39(2): 81-84.)
-
[22] LIU F, LI B, LI W, BAI Z, YPERMAN J. Py-MS study of sulfur behavior during pyrolysis of high-sulfur coals under different atmospheres[J]. Fuel Process Technol, 2010, 91(11): 1486-1490.[22] LIU F, LI B, LI W, BAI Z, YPERMAN J. Py-MS study of sulfur behavior during pyrolysis of high-sulfur coals under different atmospheres[J]. Fuel Process Technol, 2010, 91(11): 1486-1490.
-
[23] MAJCHROWICZ. B, YPERMAN. J, MULLENS J, VAN POUCKE. L. Automated potentiometric determination of sulfur functional groups in fossil fuels[J]. Anal Chem, 1991, 63(8): 760-763.[23] MAJCHROWICZ. B, YPERMAN. J, MULLENS J, VAN POUCKE. L. Automated potentiometric determination of sulfur functional groups in fossil fuels[J]. Anal Chem, 1991, 63(8): 760-763.
-
[24] YPERMAN J, MAES II, VAN DEL RUL H, MULLENS S, VAN AELST J, FRANCO D, JULES M, LUCIEN C, POUCKE V. Sulphur group analysis in solid matrices by atmospheric pressure-temperature programmed reduction[J]. Anal Chim Acta, 1999, 395(1): 143-155.[24] YPERMAN J, MAES II, VAN DEL RUL H, MULLENS S, VAN AELST J, FRANCO D, JULES M, LUCIEN C, POUCKE V. Sulphur group analysis in solid matrices by atmospheric pressure-temperature programmed reduction[J]. Anal Chim Acta, 1999, 395(1): 143-155.
-
[25] VAN AELST J, YPERMAN J, FRANCO D, VAN POUCKE L, BUCHANAN A, BRITT P. Study of silica-immobilized sulfur model compounds as calibrants for the AP-TPR study of oxidized coal samples[J]. Energy Fuels, 2000, 14(5): 1002-1008.[25] VAN AELST J, YPERMAN J, FRANCO D, VAN POUCKE L, BUCHANAN A, BRITT P. Study of silica-immobilized sulfur model compounds as calibrants for the AP-TPR study of oxidized coal samples[J]. Energy Fuels, 2000, 14(5): 1002-1008.
-
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