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基于3,6-二肼基-1,2,4,5-四嗪的两种高氮含能离子盐

张建国 ,  殷昕 ,  吴金婷 ,  孙谋 ,  冯金玲 ,  张同来 ,  周遵宁

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引用本文: 张建国, 殷昕, 吴金婷, 孙谋, 冯金玲, 张同来, 周遵宁. 基于3,6-二肼基-1,2,4,5-四嗪的两种高氮含能离子盐[J]. 无机化学学报, 2013, 29(12): 2587-2594. doi: 10.3969/j.issn.1001-4861.2013.00.391 shu
Citation:  ZHANG Jian-Guo, YIN Xin, WU Jin-Ting, SUN Mou, FENG Jin-Ling, ZHANG Tong-Lai, ZHOU Zun-Ning. Two High-Nitrogen Energetic Salts Based on 3,6-Dihydrazino-1,2,4,5-tetrazine[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(12): 2587-2594. doi: 10.3969/j.issn.1001-4861.2013.00.391 shu

基于3,6-二肼基-1,2,4,5-四嗪的两种高氮含能离子盐

  • 基金项目:

    国家自然科学基金项目(No.10776002)，爆炸科学与技术国家重点实验室自主课题(No.ZDKT12-03) (No.10776002)，爆炸科学与技术国家重点实验室自主课题(No.ZDKT12-03)

    教育部新世纪优秀人才支持计划(No.NCET-09-0051)资助项目。 (No.NCET-09-0051)

摘要: 本文通过3，6-二肼基-1，2，4，5-四嗪(DHT)分别与高氯酸和硝酸反应得到2种高氮含能离子盐，并通过X-射线单晶衍射技术对它们的结构进行了表征。(DHT)(NO3)2(1)属于单斜晶系，C2/c空间群，晶胞参数：a=1.300 0(6) nm，b=0.834 9(3) nm，c=1.018 7(5) nm，β=118.89(5)°，Z=4；(DHT)(ClO4)2(2)属于正交晶系，P21212空间群，晶胞参数：a=0.980 4(4) nm，b=1.074 7(4) nm，c=0.532 5(2) nm，Z=2。采用DSC和TG-DTG技术研究了这两种含能离子盐的热分解机理，并对这两种含能离子盐的非等温动力学、爆热及感度进行了测试分析。研究表明这两种含能离子盐在敏感型含能材料领域具有潜在的应用前景。

English

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  • 收稿日期:  2013-04-22
  • 网络出版日期:  2013-08-29
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