Citation: Meiyu Cong, Deshuai Sun, Linlin Zhang, Xin Ding. In situ assembly of metal-organic framework-derived N-doped carbon/Co/CoP catalysts on carbon paper for water splitting in alkaline electrolytes[J]. Chinese Journal of Catalysis, 2020, 41(2): 242-248. doi: S1872-2067(19)63410-8
原位组装在碳纸上的有机金属骨架材料衍生的NC/Co/CoP催化剂用于碱性环境水分解
本文通过电泳的方法,将ZIF-67负载到碳纸上,进一步通过碳化、部分磷化过程得到NC/Co/CoP/CP催化电极.研究发现,在碱性环境(1mol/L KOH)下,催化电流达到10mA/cm2的析氢过电位只有208mV,析氧反应的过电位为350mV,在二电极体系中所需的电压也只有1.72V,催化活性明显高于通过传统方法组装的电极.在长时间的电化学稳定性测试中,经过20 h的电流测试和1000次的CV测试后,该电极的催化活性没有明显下降.我们报道了一种基于MOF材料的复合电极组装新方法,为MOF材料在能源储存与转化领域应用提供了新思路.
English
In situ assembly of metal-organic framework-derived N-doped carbon/Co/CoP catalysts on carbon paper for water splitting in alkaline electrolytes
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