等离子共振效应的Ag纳米颗粒修饰生物炭点/Bi4Ti3O12纳米片复合材料的制备及其光催化性能

引用本文: 汪涛, 刘锡清, 门秋月, 马长畅, 刘洋, 马威, 刘志, 魏茂彬, 李春香, 闫永胜. 等离子共振效应的Ag纳米颗粒修饰生物炭点/Bi₄Ti₃O₁₂纳米片复合材料的制备及其光催化性能[J]. 催化学报, 2019, 40(6): 886-894. doi: S1872-2067(19)63330-9 shu

Citation: Tao Wang, Xiqing Liu, Qiuyue Men, Changchang Ma, Yang Liu, Wei Ma, Zhi Liu, Maobin Wei, Chunxiang Li, Yongsheng Yan. Surface plasmon resonance effect of Ag nanoparticles for improving the photocatalytic performance of biochar quantum-dot/Bi₄Ti₃O₁₂ nanosheets[J]. Chinese Journal of Catalysis, 2019, 40(6): 886-894. doi: S1872-2067(19)63330-9 shu

等离子共振效应的Ag纳米颗粒修饰生物炭点/Bi₄Ti₃O₁₂纳米片复合材料的制备及其光催化性能

a 江苏大学化学与化工学院, 江苏镇江 212013;
b 江苏大学材料科学与工程学院, 江苏镇江 212013;
c 江苏大学绿色化学与化工研究院, 江苏镇江 212013;
d 吉林师范大学物理学院, 吉林四平 136000;
e 江苏联合化工有限公司, 江苏镇江 212212;
f 辽宁师范大学化学与化工学院, 辽宁大连 116029
基金项目:
国家自然科学基金（U1510126，21676115）；江苏省自然科学基金（BK20180884）.

摘要: 众所周知，能源危机和环境污染是当前人们所面临的巨大难题和挑战，因此寻找或开发一种高新的技术解决上述难题尤为重要.近年来，基于半导体的光催化技术被广泛应用于能源制备和环境污染物去除领域，该技术通过直接转化太阳能为化学反应所需的能量来产生催化作用，使周围的氧气或水分子激发成活性物质，进而进行催化反应，且同时催化材料自身不受损耗，被认为是一种高效、安全的环境友好型技术.
Bi₄Ti₃O₁₂是一种物理化学性质稳定、环境友好型的半导体材料，也是当前研究较多的一类铋系半导体光催化材料.然而，纯相的Bi₄Ti₃O₁₂纳米材料自身电子分离效率低且可见光响应范围窄，严重限制了其在光催化领域的应用.Ag纳米颗粒具有等离子共振效应，可以形成强的电场作用，从而增强光的利用和电子-空穴对的产生.碳点（CDs）是一类表面基团丰富、具有独特光物理性质的纳米级碳材料.碳点修饰的半导体光催化剂具有良好的稳定性和光催化活性.因此，制备Ag/CDs/Bi₄Ti₃O₁₂复合光催化剂可以有效扩宽Bi₄Ti₃O₁₂的光吸收范围，增强电子-空穴对的分离效率，从而提高光催化活性.
本文利用竹子作为碳源，通过简单的水热法合成碳点，以熔盐法合成Bi₄Ti₃O₁₂纳米片，用简单的物理混合法将碳点修饰在Bi₄Ti₃O₁₂表面，再通过光沉积法将Ag⁺还原在CDs/Bi₄Ti₃O₁₂的表面，从而制备出Ag/CDs/Bi₄Ti₃O₁₂复合光催化剂.以10mg/L的四环素水溶液作为目标污染物，测试光催化剂在可见光下对目标污染物的降解能力.采用X射线衍射（XRD）、傅里叶红外光谱（FT-IR）、透射电镜（TEM）、扫描电镜（SEM）、荧光光谱（PL）和光电流等表征方法分析了催化剂的结构特征、微观形貌和光电性质等.XRD分析表明Bi₄Ti₃O₁₂材料被成功合成，在CDs和Ag纳米颗粒进行修饰后未改变Bi₄Ti₃O₁₂的晶型结构.XPS和EDS mapping的结果均表明复合材料由Ag，C，Bi，Ti和O元素组成，说明Ag/CDs/Bi₄Ti₃O₁₂复合光催化剂成功制备.UV-vis DRS结果表明，Ag和CDs的修饰扩宽了Bi₄Ti₃O₁₂的可见光吸收范围.荧光光谱和光电流结果也证明了Ag/CDs/Bi₄Ti₃O₁₂复合光催化剂具有更好的光响应能力和电子分离效率.光催化性能测试最终证实Ag/CDs/Bi₄Ti₃O₁₂复合光催化剂在可见光下具有良好的催化降解能力.循环实验说明Ag/CDs/Bi₄Ti₃O₁₂复合光催化剂具有很好的稳定性，是一种具有潜力的催化材料.
用不同捕获剂进行了自由基捕获实验，研究了Ag/CDs/Bi₄Ti₃O₁₂复合光催化剂的催化机理，结果证实超氧自由基和空穴在光催化过程中起主要作用，羟基自由基也部分参与反应.总之，将碳点、Ag纳米颗粒与Bi₄Ti₃O₁₂结合制备的Ag/CDs/Bi₄Ti₃O₁₂复合光催化剂具有良好的光催化性能，该工作为相关材料的制备和光催化研究提供了理论依据.

关键词:

English

Surface plasmon resonance effect of Ag nanoparticles for improving the photocatalytic performance of biochar quantum-dot/Bi₄Ti₃O₁₂ nanosheets

a School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu, China;
b School of Material Science and Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu, China;
c Institute of Green Chemistry and Chemical Technology, Jiangsu University, Zhenjiang 212013, Jiangsu, China;
d College of Physics, Jilin Normal University, Siping 13600, Jilin, China;
e Jiangsu United Chemical Co., Ltd., Zhenjiang 212212, Jiangsu, China;
f School of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, Liaoning, China
Received Date: 06 December 2018
Revised Date: 08 February 2019
Fund Project:
This work was financially supported by the National Natural Science Foundation of China (U1510126, 21676115), and the Natural Science Foundation of Jiangsu Provincial (BK20180884).

Abstract: Herein, we report a novel ternary material comprised of Ag nanoparticles and carbon quantum dots (CDs), which are co-loaded using 2D Bi₄Ti₃O₁₂ (BIT) sheets. In this system, Ag can be applied as excited electron-hole pairs in the Bi₄Ti₃O₁₂ by transferring the plasmonic energy from the metal to the semiconductor. The surface plasmon resonance of Ag can promote the electron transfer properties of the CDs, thereby improving the separation efficiency of the electron-hole pairs. Meanwhile, the CDs can act as an electron buffer to decrease the recombination rate of the electron hole. Moreover, CDs are prepared using a biomaterial, which can provide a chemical group to enhance the electron transfer and connection. The synergistic effects of CDs, Ag, and BIT enable the design of a photocatalytic application with a remarkably improved efficiency and operational stability.

Key words:

1. [1] Y. Jin, S. Wu, Z. Zeng, Z. Fu, Environ. Pollut., 2017, 222, 1-9.
2. [2] A. J. Cramer, J. M. Cole, J. Mater. Chem. A, 2017, 5, 10746-10771.
3. [3] Y. P. Wang, Q. Fu, C. Li, H. H. Li, H. Tang, ACS Sustainable Chem. Eng., 2018, 6, 15083-15091.
4. [4] X. Meng, L. Liu, S. Ouyang, H. Xu, D. Wang, N. Zhao, J. Ye, Adv. Mater., 2016, 28, 6781-6803.
5. [5] X. Zhang, X. Li, D. Zhang, N.Q. Su, W. Yang, H.O. Everitt, J. Liu, Nat. Commun., 2017, 8, 14542.
6. [6] H. Yu, W. Liu, X. Wang, F. Wang, Appl. Catal. B, 2018, 225, 415-423.
7. [7] K. M. Cho, K. H. Kim, K. Park, C. Kim, S. Kim, A. Alsaggaf, I. Gereige, H. T. Jung, ACS Catal., 2017, 10, 7064-7069.
8. [8] K. J. Yun, I. Y. Kim, J. M. Lee, S. Nahm, J. W. Choi, S. J. Hwang, Mater. Lett., 2014, 114, 152-155.
9. [9] F. Qiu, Z. Han, J. J. Peterson, M. Y. Odoi, K. L. Sowers, T. D. Krauss, Nano Lett., 2016, 16, 5347-5352.
10. [10] D. Hou, W. Luo, Y. Huang, J. C. Yu, X. Hu, Nanoscale, 2013, 5, 2028-2035.
11. [11] Z. Chen, H. Jiang, W. Jin, C. Shi, Appl. Catal. B, 2016, 180, 698-706.
12. [12] W. F. Yao, X. H. Xu, H. Wang, J. T. Zhou, X. N. Yang, Y. Zhang, S. X. Shang, B. B. Huang, Appl. Catal. B, 2004, 52, 109-116.
13. [13] S. Murugesan, M. N. Huda, Y. Yan, M. M. Al-Jassim, V. Subramanian, J. Phys. Chem. C, 2010, 114, 10598-10605.
14. [14] C. Lertvachirapaiboon, A. Baba, S. Ekgasit, K. Shinbo, K. Kato, F. Kaneko, Sensor. Actuat. B, 2017, 249, 39-43.
15. [15] K. M. See, F. C. Lin, J. S. Huang, Nanoscale, 2017, 9, 10811-10819.
16. [16] X. Yi, W. Chen, G. Bertoni, I. Kriegel, X. Mo, N. Li, M. Prato, A. Riedinger, A. Sathya, L. Manna, Chem. Mater., 2011, 29, 1716-1723.
17. [17] G. M. Faccin, M. A. San-Miguel, J. Andres, E. Longo, E. Z. da Silva, J. Phys. Chem. C, 2017, 121, 7030-7036.
18. [18] Y. Sun, T. Xiong, Z. Ni, J. Liu, F. Dong, W. Zhang, W. K. Ho, Appl. Surf. Sci., 2015, 358, 356-362.
19. [19] B. Shi, H. Yin, J. Gong, Q. Nie, Appl. Surf. Sci., 2017, 419, 614-623.
20. [20] Y. Li, Z. Liu, Y. Wu, J. Chen, J. Zhao, F. Jin, P. Na, Appl. Catal. B, 2018, 224, 508-517.
21. [21] Q. Wang, J. Huang, H. Sun, K. Q. Zhang, Y. Lai, Nanoscale, 2017, 9, 16046-16058.
22. [22] J. Wang, L. Tang, G. Zeng, Y. Deng, H. Dong, Y. Liu, L. Wang, B. Peng, C. Zhang, F. Chen, Appl. Catal. B, 2018, 222, 115-123.
23. [23] C. Zhu, C. Liu, Y. Zhou, Y. Fu, S. Guo, H. Li, S. Zhao, H. Huang, Y. Liu, Z. Kang, Appl. Catal. B, 2017, 216, 114-121.
24. [24] X. Xu, Z. Bao, W. Tang, H. Wu, J. Pan, J. Hu, H. Zeng, Carbon, 2017, 121, 201-208.
25. [25] Y. Liu, G. Zhu, J.Z. Gao, M. Hojamberdiev, H. Luo, R. Zhu, X. Wei, P. Liu, J. Alloys Compd., 2016, 688, 487-496.
26. [26] T. Wang, X. Liu, C. Ma, Z. Zhu, Y. Liu, Z. Liu, M. Wei, X. Zhao, H. Dong, P. Huo, C. Li, Y. Yan, J. Alloys Compd., 2018, 752, 106-114.
27. [27] O. Moradlou, Z. Rabiei, A. Banazadeh, J. Warzywoda, M. Zirak, Appl. Catal. B, 2018, 227, 178-189.
28. [28] J. Jin, S. Zhu, Y. Song, H. Zhao, Z. Zhang, Y. Guo, J. Li, W. Song, B. Yang, B. Zhao, ACS Appl. Mater. Interfaces, 2016, 8, 27956-27965.
29. [29] D. Xu, Y. Hai, X. Zhang, S. Zhang, R. He, Appl. Surf. Sci., 2016, 400, 530-536.
30. [30] E. I. Vovk, A. V. Kalinkin, M. Y. Smirnov, I. O. Klembovskii, V. I. Bukhtiyarov, J. Phys. Chem. C, 2017, 121, 17297-17304.
31. [31] H. Li, X. He, Z. Kang, H. Huang, Y. Liu, J. Liu, S. Lian, C. H. A. Tsang, X. Yang, S. T. Lee, Angew. Chem. Int. Ed., 2010, 49, 4430-4434.
32. [32] X. F. Meng, Y. Zhuang, H. Tang, C. H. Lu, J. Alloys Compd., 2018, 761, 15-23.
33. [33] H. Yu, Y. Zhao, C. Zhou, L. Shang, Y. Peng, Y. Cao, L. Z. Wu, C. H. Tung, T. Zhang, J. Mater. Chem. A, 2014, 2, 3344-3351.
34. [34] C. Hu, Y. Liu, J. Qin, G. Nie, B. Lei, Y. Xiao, M. Zheng, J. Rong, ACS Appl. Mater. Interfaces, 2013, 5, 4760-4768.
35. [35] X. Wang, L. Cao, F. Lu, M. J. Meziani, H. Li, G. Qi, B. Zhou, B. A. Harruff, F. Kermarrec, Y. P. Sun, Chem. Commun., 2009, 3774-3776.
36. [36] Q. Q. Liu, J. Y. Shen, X. F. Yang, T. R. Zhang, H. Tang, Appl. Catal. B, 2018, 232, 562-573.
37. [37] G. A. M. Hutton, B. C. M. Martindale, E. Reisner, Chem. Soc. Rev., 2017, 46, 6111-6123.
38. [38] X. Liu, X. Wei, Y. Xu, H. Li, K. Lu, K. Wang, Y. Yan, Nano, 2017, 12, 1750024.
39. [39] Z. Chen, X. Jiang, C. Zhu, C. Shi, Appl. Catal. B, 2016, 199, 241-251.
40. [40] J. Wang, D. Song, L. Wang, H. Zhang, H. Zhang, Y. Sun, Sensor. Actuat. B, 2011, 157, 547-553.
41. [41] Y. Liu, G. Zhu, J. Gao, M. Hojamberdiev, R. Zhu, X. Wei, Q. Guo, P. Liu, Appl. Catal. B, 2017, 200, 72-82.
42. [42] J. Yu, M. Jaroniec, Appl. Surf. Sci., 2017, 391, 71-71.
43. [43] F. Petronella, A. Truppi, C. Ingrosso, T. Placido, M. Striccoli, M. L. Curri, A. Agostiano, R. Comparelli, Catal. Today, 2017, 281, 85-100.
44. [44] W. Liu, J. Shen, Q. Liu, X. Yang, H. Tang, Appl. Surf. Sci., 2018, 462, 822-830.
45. [45] T. Weller, L. Specht, R. Marschall, Nano Energy, 2017, 31, 551-559.
46. [46] Y. Zhang, L. L. Han, C. Wang, W. H. Wang, T. Ling, J. Yang, C. Dong, F. Lin, X. W. Du, ACS Catal., 2017, 7, 1470-1477.
47. [47] D. Gu, Y. Qin, Y. Wen, T. Li, L. Qin, H. J. Seo, J. Alloys Compd., 2016, 695, 2224-2231.
48. [48] D. G. Li, S. H. Chen, S. Y. Zhao, X. M. Hou, H. Y. Ma, X. G. Yang, Appl. Surf. Sci., 2002, 200, 62-67.
49. [49] W. Liu, J. Shen, X. Yang, Q. Liu, H. Tang, Appl. Surf. Sci., 2018, 456, 369-378.
50. [50] X. Wang, R. Yu, K. Wang, G. Yang, H. Yu, Chin. J. Catal., 2015, 36, 1211-2218.
51. [51] F. Chen, H. Yang, W. Luo, P. Wang, H. Yu, Chin. J. Catal., 2017, 38, 1990-1998.
52. [52] T. Leshuk, R. Parviz, P. Everett, H. Krishnakumar, R. A. Varin, F. Gu, ACS Appl. Mater. Interfaces, 2013, 5, 1892-1895.
53. [53] C. S. Hong, Y. Wang, B. Bush, Chemosphere, 1998, 36, 1653-1667.
54. [54] Z. Zhu, P. Huo, Z. Lu, Y. Yan, Z. Liu, W. Shi, C. Li, H. Dong, Chem. Eng. J., 2018, 331, 615-625.
55. [55] Z. Zhu, Y. Yu, H. Dong, Z. Liu, C. Li, P. Huo, Y. Yan, ACS Sustainable Chem. Eng., 2017, 5, 10614-10623.
56. [56] J. Qin, H. Zeng, Appl. Catal. B, 2017, 209, 161-173.
57. [57] Y. Guo, J. Zhang, D. Zhou, S. Dong, J. Mol. Liq., 2018, 262, 194-203.
58. [58] Z. Zhang, S. Lin, W. Cui, X. Li, H. Li, Mater. Lett., 2019, 234, 264-268.

扫一扫看文章

计量

PDF下载量: 1
文章访问数: 2034
HTML全文浏览量: 117

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

等离子共振效应的Ag纳米颗粒修饰生物炭点/Bi₄Ti₃O₁₂纳米片复合材料的制备及其光催化性能

English

Surface plasmon resonance effect of Ag nanoparticles for improving the photocatalytic performance of biochar quantum-dot/Bi₄Ti₃O₁₂ nanosheets

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处