注册 English

从SiCl4合成多孔硅/碳复合材料及储锂性能研究

冯雪娇 ,  杨军 ,  努丽燕娜 ,  王久林

downloadPDF
引用本文: 冯雪娇, 杨军, 努丽燕娜, 王久林. 从SiCl4合成多孔硅/碳复合材料及储锂性能研究[J]. 无机化学学报, 2013, 29(11): 2289-2296. doi: 10.3969/j.issn.1001-4861.2013.00.367 shu
Citation:  FENG Xue-Jiao, YANG Jun, NULI Yan-Na, WANG Jiu-Lin. Synthesis and Lithium Storage Performance of Porous Silicon/Carbon Composite Material from SiCl4[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(11): 2289-2296. doi: 10.3969/j.issn.1001-4861.2013.00.367 shu

从SiCl4合成多孔硅/碳复合材料及储锂性能研究

摘要: 以Li13Si4和SiCl4为原料,通过简单的机械球磨法合成多孔硅/碳复合材料,通过控制Li13Si4颗粒的尺寸可以有效调节产物的比表面积。分别研究了包覆碳含量、多孔硅/SuperP(导电碳)比表面积以及极片活性物质负载量对多孔硅/碳复合材料电化学性能的影响。结果表明:多孔硅/SuperP比表面积为100.9m2·g-1,化学气相沉积(CVD)包覆碳含量为25.3wt%(约6nm厚)的复合材料具有最高的电化学活性,在300mA·g-1的电流密度下,循环可逆比容量达到1900mAh·g-1,50次循环后容量仅衰减7.6%。

English

  • 

    1. [1] Cho J. J. Mater. Chem., 2010,20:4009-4010[1] Cho J. J. Mater. Chem., 2010,20:4009-4010

    2. [2] FU Ping-Ping(付萍萍), SONG Ying-Jie(宋英杰), ZHANG Hong-Fang(张宏芳), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2006,22(10):1823-1827[2] FU Ping-Ping(付萍萍), SONG Ying-Jie(宋英杰), ZHANG Hong-Fang(张宏芳), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2006,22(10):1823-1827

    3. [3] YANG Xue-Lin(杨学林), WEN Zhao-Yin(温兆银), ZHANG Lu-Lu(张露露), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2007,23(12):2054-2058[3] YANG Xue-Lin(杨学林), WEN Zhao-Yin(温兆银), ZHANG Lu-Lu(张露露), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2007,23(12):2054-2058

    4. [4] Teki R, Datta M K, Krishnan R, et al. Small, 2009,5(20): 2236-2242[4] Teki R, Datta M K, Krishnan R, et al. Small, 2009,5(20): 2236-2242

    5. [5] SU Ming-Ru(苏明如), WANG Zhi-Xing(王志兴), GUO Hua-Jun(郭华军), et al. Chinese J. Nonfer. Metal.(Zhongguo Youse Jinshu Xuebao), 2013,23(4):1059-1064[5] SU Ming-Ru(苏明如), WANG Zhi-Xing(王志兴), GUO Hua-Jun(郭华军), et al. Chinese J. Nonfer. Metal.(Zhongguo Youse Jinshu Xuebao), 2013,23(4):1059-1064

    6. [6] LI Cun-Pu(李存璞), WANG Yao-Wu(王要武), XIE Xiao-Feng(谢晓峰), et al. CIESC Journal(Huagong Xuebao), 2011,62(S1): 13-18[6] LI Cun-Pu(李存璞), WANG Yao-Wu(王要武), XIE Xiao-Feng(谢晓峰), et al. CIESC Journal(Huagong Xuebao), 2011,62(S1): 13-18

    7. [7] Gao P, Nuli Y, He Y S, et al. Chem. Commun., 2010,46(48): 9149-9151[7] Gao P, Nuli Y, He Y S, et al. Chem. Commun., 2010,46(48): 9149-9151

    8. [8] Chan C K, Peng H, Liu G, et al. Nat. Nanotechnol., 2007,3 (1):31-35[8] Chan C K, Peng H, Liu G, et al. Nat. Nanotechnol., 2007,3 (1):31-35

    9. [9] Chan C K, Patel R N, Cui Y, et al. ACS Nano, 2010,4(3): 1443-1450[9] Chan C K, Patel R N, Cui Y, et al. ACS Nano, 2010,4(3): 1443-1450

    10. [10]Kim H, Han B, Choo J, et al. Angew. Chem. Int. Ed., 2008, 47(52):10151-10154[10]Kim H, Han B, Choo J, et al. Angew. Chem. Int. Ed., 2008, 47(52):10151-10154

    11. [11]Li H, Zhou H. Chem. Commun., 2012,48(9):1201-1217[11]Li H, Zhou H. Chem. Commun., 2012,48(9):1201-1217

    12. [12]DU Li-Li(杜莉莉), ZHUANG Quan-Chao(庄全超), WEI Tao (巍涛), et al. Acta Chim. Sin. (Huaxue Xuebao), 2011,69(2): 2641-2647[12]DU Li-Li(杜莉莉), ZHUANG Quan-Chao(庄全超), WEI Tao (巍涛), et al. Acta Chim. Sin. (Huaxue Xuebao), 2011,69(2): 2641-2647

    13. [13]ZHENG Ying(郑颖), YANG Jun(杨军), TAO Liang(陶亮), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2007, 23(11):1882-1886[13]ZHENG Ying(郑颖), YANG Jun(杨军), TAO Liang(陶亮), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2007, 23(11):1882-1886

    14. [14]Wang W, Kumta N P. ACS Nano, 2010,4(4):2233-2241[14]Wang W, Kumta N P. ACS Nano, 2010,4(4):2233-2241

    15. [15]Chen S, Gordin M L, Yi R, et al. Phys. Chem. Chem. Phys., 2012,14:12741-12745[15]Chen S, Gordin M L, Yi R, et al. Phys. Chem. Chem. Phys., 2012,14:12741-12745

    16. [16]Zhou X, Yin Y X, Wan L J, et al. Chem. Commun., 2012,48 (16):2198-2200[16]Zhou X, Yin Y X, Wan L J, et al. Chem. Commun., 2012,48 (16):2198-2200

    17. [17]Gao P, Fu J, Yang J, et al. Phys. Chem. Chem. Phys., 2009, 11(47):11101-11105[17]Gao P, Fu J, Yang J, et al. Phys. Chem. Chem. Phys., 2009, 11(47):11101-11105

    18. [18]Xu Y, Yin G, Ma Y, et al. J. Mater. Chem., 2010,20(16): 3216-3220[18]Xu Y, Yin G, Ma Y, et al. J. Mater. Chem., 2010,20(16): 3216-3220

    19. [19]Magasinski A, Dixon P, Hertzberg B, et al. Nat. Mater., 2010,9:353-358[19]Magasinski A, Dixon P, Hertzberg B, et al. Nat. Mater., 2010,9:353-358

    20. [20]Guo S, Dong S. Chem. Soc. Rev., 2011,40(5):2644-2672[20]Guo S, Dong S. Chem. Soc. Rev., 2011,40(5):2644-2672

    21. [21]Feng X, Yang J, Gao P, et al. RSC Adv., 2012,2(13):5701-5706[21]Feng X, Yang J, Gao P, et al. RSC Adv., 2012,2(13):5701-5706

    22. [22]Liu N, Hu L, McDowell M T, et al. ACS Nano, 2011,5: 6487-6493[22]Liu N, Hu L, McDowell M T, et al. ACS Nano, 2011,5: 6487-6493

    23. [23]Cho Y D, Fey G T K, Kao H M. J. Power Sources, 2009,189 (1):256-262[23]Cho Y D, Fey G T K, Kao H M. J. Power Sources, 2009,189 (1):256-262

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  0
  • 文章访问数:  281
  • HTML全文浏览量:  41
文章相关
  • 收稿日期:  2013-04-22
  • 网络出版日期:  2013-06-17
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net