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2-噻吩咪唑[4,5-f][1,10]菲啰啉及其衍生物的顺式镉(Ⅱ)、锰(Ⅱ)和镍(Ⅱ)配合物的结构和波谱研究

王银歌 ,  刘前前 ,  翟立新 ,  钱惠芬 ,  黄伟

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引用本文: 王银歌, 刘前前, 翟立新, 钱惠芬, 黄伟. 2-噻吩咪唑[4,5-f][1,10]菲啰啉及其衍生物的顺式镉(Ⅱ)、锰(Ⅱ)和镍(Ⅱ)配合物的结构和波谱研究[J]. 无机化学学报, 2013, 29(8): 1687-1695. doi: 10.3969/j.issn.1001-4861.2013.00.294 shu
Citation:  WANG Yin-Ge, LIU Qian-Qian, ZHAI Li-Xin, QIAN Hui-Fen, HUANG Wei. Structural and Spectral Studies of Cis Cadmium(Ⅱ), Manganese(Ⅱ) and Nickel(Ⅱ) Complexes Having 2-Thiophenimidazo[4,5-f][1,10]phenanthroline and 2-(5-Bromothiophen)imidazo[4,5-f][1,10]phenanthroline Ligands[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(8): 1687-1695. doi: 10.3969/j.issn.1001-4861.2013.00.294 shu

2-噻吩咪唑[4,5-f][1,10]菲啰啉及其衍生物的顺式镉(Ⅱ)、锰(Ⅱ)和镍(Ⅱ)配合物的结构和波谱研究

  • 基金项目:

    国家自然科学基金(No.21171088) (No.21171088)

    “青蓝工程”资助项目。 

摘要: 本文报道了3个基于2-噻吩咪唑[4,5-f][1,10]菲啰啉(TIP)和2-(5-溴-2-噻吩)咪唑[4,5-f][1,10]菲啰啉(5-Br-TIP)的镉(Ⅱ)配合物1 [cis-Cd(TIP)2(NO3)2]、锰(Ⅱ)配合物2 [cis-Mn(5-Br-TIP)2Cl2]和镍(Ⅱ)配合物3 [cis-Ni(TIP)2Cl(CH3OH)]Cl·CH3OH的合成、波谱和晶体结构表征。它们均为顺式1:2单核配合物,其中1为8配位,2和3为6配位,TIP和5-Br-TIP配体在不同配合物中噻吩和邻菲啰啉并咪唑环之间的二面角有所不同,但都不大,在3.9(1)°~9.2(1)°范围。

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  • 收稿日期:  2013-02-16
  • 网络出版日期:  2013-05-28
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