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肉桂酸及其衍生物的Eu(Ⅲ)配合物的合成、结构及荧光性质研究

周贤菊 ,  周凯宁 ,  王志亮 ,  肖腾蛟 ,  赵小奇 ,  李清旭

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引用本文: 周贤菊, 周凯宁, 王志亮, 肖腾蛟, 赵小奇, 李清旭. 肉桂酸及其衍生物的Eu(Ⅲ)配合物的合成、结构及荧光性质研究[J]. 无机化学学报, 2013, 29(9): 1870-1876. doi: 10.3969/j.issn.1001-4861.2013.00.288 shu
Citation:  ZHOU Xian-Ju, ZHOU Kai-Ning, WANG Zhi-Liang, XIAO Teng-Jiao, ZHAO Xiao-Qi, LI Qing-Xu. Synthesis, Structure and Fluorescent Properties of Europium Complexes with Cinnamic Acid and Its Derivates[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(9): 1870-1876. doi: 10.3969/j.issn.1001-4861.2013.00.288 shu

肉桂酸及其衍生物的Eu(Ⅲ)配合物的合成、结构及荧光性质研究

  • 基金项目:

    国家自然科学基金(No.20903123) (No.20903123)

    教育部重点项目(No.211154) (No.211154)

    重庆市自然科学基金(No.KJ110532,CSTC2011jjA1425) (No.KJ110532,CSTC2011jjA1425)

    重庆邮电大学研 究生优质课程建设及本科生创新计划资助项目。 

摘要: 以肉桂酸C9H8O2(HL)及其衍生物对位取代肉桂酸R-L(R=CH3,Cl,NO2,OCH3,OH)为配体,分别与Eu3+配位,得到系列Eu3+配合物。X-射线单晶解析结果表明:对甲基肉桂酸铕(1)和对氯肉桂酸铕(2)为一维高分子链,对硝基肉桂酸铕(3)为双核结构。通过FT-IR和UV-Vis光谱分析了配体在配位前后的变化。记录和解析了各配合物的荧光光谱,研究了对位取代基吸电子性和配位小分子对配合物发光性能的影响。

English

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  • 收稿日期:  2012-09-25
  • 网络出版日期:  2013-05-13
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