含磷钼酸及2,2’-联吡啶-3,3’-二羧酸配体的铜配位聚合物的合成、晶体结构与电化学性质

王志花 王鑫鹏 赵胜能 王琴 孟祥高 靳素荣

引用本文: 王志花, 王鑫鹏, 赵胜能, 王琴, 孟祥高, 靳素荣. 含磷钼酸及2,2’-联吡啶-3,3’-二羧酸配体的铜配位聚合物的合成、晶体结构与电化学性质[J]. 无机化学学报, 2013, 29(9): 1877-1881. doi: 10.3969/j.issn.1001-4861.2013.00.271 shu
Citation:  WANG Zhi-Hua, WANG Xin-Peng, ZHAO Sheng-Neng, WANG Qin, MENG Xiang-Gao, JIN Su-Rong. Synthesis, Crystal Structure and Electrochemical Property of a Copper Coordination Polymer Containing Molybdophosphate and 2,2’-Bipyridine-3,3’-dicarboxylic Acid Ligands[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(9): 1877-1881. doi: 10.3969/j.issn.1001-4861.2013.00.271 shu

含磷钼酸及2,2’-联吡啶-3,3’-二羧酸配体的铜配位聚合物的合成、晶体结构与电化学性质

  • 基金项目:

    中央高校基本科研业务费专项资金(批准号:2012-Ia-042)资助项目。 (批准号:2012-Ia-042)

摘要: 在水热条件下合成了一个新的化合物{[Cu4(PMo12O40)(H2O)5(H2bpdc)(Hbpdc)(bpdc)2]·6H2O}n(H2bpdc=2,2'-联吡啶-3,3'-二羧酸),并用元素分析、IR、TG和X-射线衍射等手段进行了表征。结果表明本化合物的晶体结构中,最小不对称单元包含1个[Cu4(H2O)5(H2bpdc)(Hbpdc)(bpdc)2]3+阳离子,1个[PMo12O40]3-阴离子和6个结晶水分子。Cu(Ⅱ)与相邻[PMo12O40]3-的桥氧原子配位,形成一维链状结构。电化学研究表明,化合物存在三步氧化还原过程。

English

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  • 收稿日期:  2012-07-21
  • 网络出版日期:  2013-05-04
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