English

Single-Crystal Nickel-Rich Cathode Materials: Challenges and Strategies

• Chenyue Huang ,
• Hongfei Zheng ,
• Ning Qin ,
• Canpei Wang ,
• Liguang Wang ^, ,
• Jun Lu ^,

• College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China

Corresponding author: Email: wanglg@zju.edu.cn (L.W.); Email: junzoelu@zju.edu.cn (J.L.)

• Received Date: 31 August 2023
  Accepted Date: 09 October 2023
  Revised Date: 05 October 2023
  Available Online: 15 September 2024
• Fund Project:

  the National Natural Science Foundation of China 

Abstract: Over the past three decades, significant advancements in lithium-ion battery technology have greatly improved human convenience, particularly in today's thriving electric vehicle industry. Further enhancements in the energy density, cycle life, and safety of lithium-ion batteries are crucial for the widespread adoption of electric vehicles. In recent years, transition metal layered oxides have garnered significant attention in the industrial power battery sector due to their advantages, including high specific capacity, commendable low-temperature performance, and cost-effectiveness. Increasing the nickel content and adjusting the charging cut-off voltage are recognized as effective means to enhance the energy density of transition metal layered oxides. However, these strategies tend to degrade cycling stability and thermal safety in conventional polycrystalline layered cathode materials. Benefiting from the mechanical stability of intact primary particles, the single-crystal structure of layered cathode materials can effectively mitigate intergranular cracking issues associated with high charging voltages. Nevertheless, due to the intrinsic structural properties of layered materials, single-crystal structures still face challenges related to sluggish Li⁺ transport kinetics, heterogeneous state of charge, anisotropic changes in lattice parameters, cation mixing, and chemo-mechanical degradation. The temporal and spatial evolution of the physicochemical properties within the internal microstructure of materials still requires comprehensive analysis using advanced operando characterization techniques. Currently, there is limited understanding of the intricate interplay between thermodynamics and kinetics in the synthesis process of single-crystal cathode materials. A more profound exploration of the structural degradation and synthesis mechanisms of single-crystal materials will serve as a fundamental basis for targeted modification strategies. Regrettably, existing single-crystal synthesis processes and modification approaches still fall short of market expectations. This shortfall is especially noticeable in future applications in solid-state batteries, where interface issues related to solid-state-electrolyte and cathode material are serious. Addressing these challenges necessitates the precise regulation of the microstructure of composite cathodes. Therefore, this review systematically analyzes and summarizes common issues related to the failure of both polycrystal and single-crystal structures, taking into account the intrinsic structural evolution at various temporal and spatial scales. We also outline strategies for regulating the synthesis process, element doping, and surface-interface modification of single-crystal nickel-rich layered cathode materials from the perspective of coherent structural design. We also intent to elucidate the essential connection between structural design and electrochemical performance. The microstructural design of single-crystal nickel-rich cathode materials should emphasize the alignment of lattice parameters between heterostructures and layered oxides, as well as the modulation of their spatial distribution, thereby ensuring the long-term efficacy of element doping and surface-interface modification. Finally, we offer a perspective on the future development of single-crystal nickel-rich cathode materials, highlighting their potential success in the realm of power batteries.

Key words:
• Lithium-ion battery
•  /  Layered cathode material
•  /  Nickel-rich
•  /  Single-crystal structure
•  /  Failure mechanism
•  /  Structural evolution
•  /  Modification strategy

• 1. [1]

     Frith, J. T.; Lacey, M. J.; Ulissi, U. Nat. Commun. 2023, 14 (1), 420. doi: 10.1038/s41467-023-35933-2

  2. [2]

     Manthiram, A.; Knight, J. C.; Myung, S.-T.; Oh, S.-M.; Sun, Y.-K. Adv. Energy Mater. 2016, 6 (1), 201501010. doi: 10.1002/aenm.201501010

  3. [3]

     Choi, N. S.; Chen, Z.; Freunberger, S. A.; Ji, X.; Sun, Y. K.; Amine, K.; Yushin, G.; Nazar, L. F.; Cho, J.; Bruce, P. G. Angew. Chem. Int. Ed. 2012, 51 (40), 9994. doi: 10.1002/anie.201201429

  4. [4]

     Liang, L.; Li, X.; Su, M.; Wang, L.; Sun, J.; Liu, Y.; Hou, L.; Yuan, C. Angew. Chem. Int. Ed. 2023, 62 (11), e202216155. doi: 10.1002/anie.202216155

  5. [5]

     Xue, W.; Huang, M.; Li, Y.; Zhu, Y. G.; Gao, R.; Xiao, X.; Zhang, W.; Li, S.; Xu, G.; Yu, Y.; et al. Nat. Energy 2021, 6 (5), 495. doi: 10.1038/s41560-021-00792-y

  6. [6]

     张继斌, 滑纬博, 郑卓, 刘文元, 郭孝东, 钟本和. 物理化学学报, 2015, 31 (5), 905. doi: 10.3866/PKU.WHXB201503091Zhang, J. B.; Hua, W. B.; Zheng, Z.; Liu, W. Y.; Guo, X. D.; Zhong, B. H. Acta Phys. -Chim. Sin. 2015, 31 (5), 905. doi: 10.3866/PKU.WHXB201503091

  7. [7]

     Nomura, Y.; Yamamoto, K.; Yamagishi, Y.; Igaki, E. ACS Nano 2021, 15 (12), 19806. doi: 10.1021/acsnano.1c07252

  8. [8]

     Lou, S.; Liu, Q.; Zhang, F.; Liu, Q.; Yu, Z.; Mu, T.; Zhao, Y.; Borovilas, J.; Chen, Y.; Ge, M.; et al. Nat. Commun. 2020, 11 (1), 5700. doi: 10.1038/s41467-020-19528-9

  9. [9]

     Xu, X.; Huo, H.; Jian, J.; Wang, L.; Zhu, H.; Xu, S.; He, X.; Yin, G.; Du, C.; Sun, X. Adv. Energy Mater. 2019, 9 (15), 201803963. doi: 10.1002/aenm.201803963

  10. [10]

      Yang, Y.; Xu, R.; Zhang, K.; Lee, S. J.; Mu, L.; Liu, P.; Waters, C. K.; Spence, S.; Xu, Z.; Wei, C.; et al. Adv. Energy Mater. 2019, 9 (25), 201900674. doi: 10.1002/aenm.201900674

  11. [11]

      Kim, U. H.; Ryu, H. H.; Kim, J. H.; Mücke, R.; Kaghazchi, P.; Yoon, C. S.; Sun, Y. K. Adv. Energy Mater. 2019, 9 (15), 201803902. doi: 10.1002/aenm.201803902

  12. [12]

      Besli, M. M.; Xia, S.; Kuppan, S.; Huang, Y.; Metzger, M.; Shukla, A. K.; Schneider, G.; Hellstrom, S.; Christensen, J.; Doeff, M. M.; et al. Chem. Mater. 2018, 31 (2), 491. doi: 10.1021/acs.chemmater.8b04418

  13. [13]

      Sun, Y.-K. ACS Energy Lett. 2019, 4 (5), 1042. doi: 10.1021/acsenergylett.9b00652

  14. [14]

      You, B.; Wang, Z.; Shen, F.; Chang, Y.; Peng, W.; Li, X.; Guo, H.; Hu, Q.; Deng, C.; Yang, S.; Yan, G.; Wang, J. Small Methods 2021, 5 (8), e2100234. doi: 10.1002/smtd.202100234

  15. [15]

      Zhu, H.; Tang, Y.; Wiaderek, K. M.; Borkiewicz, O. J.; Ren, Y.; Zhang, J.; Ren, J.; Fan, L.; Li, C. C.; Li, D.; et al. Nano Lett. 2021, 21 (23), 9997. doi: 10.1021/acs.nanolett.1c03613

  16. [16]

      Fan, X. M.; Huang, Y. D.; Wei, H. X.; Tang, L. B.; He, Z. J.; Yan, C.; Mao, J.; Dai, K. H.; Zheng, J. C. Adv. Funct. Mater. 2021, 32 (6), 202109421. doi: 10.1002/adfm.202109421

  17. [17]

      Yang, S.-Q.; Wang, P.-B.; Wei, H.-X.; Tang, L.-B.; Zhang, X.-H.; He, Z.-J.; Li, Y.-J.; Tong, H.; Zheng, J.-C. Nano Energy 2019, 63, 103889. doi: 10.1016/j.nanoen.2019.103889

  18. [18]

      Song, Y.; Cui, Y.; Li, B.; Geng, L.; Yan, J.; Zhu, D.; Zhou, P.; Zhou, J.; Yan, Z.; Xue, Q.; Tang, Y.; Xing, W. Nano Energy 2023, 116, 108846. doi: 10.1016/j.nanoen.2023.108846

  19. [19]

      Kong, X.; Zhang, Y.; Li, J.; Yang, H.; Dai, P.; Zeng, J.; Zhao, J. Chem. Eng. J. 2022, 434, 134638. doi: 10.1016/j.cej.2022.134638

  20. [20]

      Wang, L.; Wang, R.; Zhong, C.; Lu, L.; Gong, D.; Shi, Q.; Fan, Y.; Wang, X.; Zhan, C.; Liu, G. J. Energy Chem. 2022, 72, 265. doi: 10.1016/j.jechem.2022.04.006

  21. [21]

      Xu, Z.; Jiang, Z.; Kuai, C.; Xu, R.; Qin, C.; Zhang, Y.; Rahman, M. M.; Wei, C.; Nordlund, D.; Sun, C. J.; et al. Nat. Commun. 2020, 11 (1), 83. doi: 10.1038/s41467-019-13884-x

  22. [22]

      Zhang, F.; Lou, S.; Li, S.; Yu, Z.; Liu, Q.; Dai, A.; Cao, C.; Toney, M. F.; Ge, M.; Xiao, X.; et al. Nat. Commun. 2020, 11 (1), 3050. doi: 10.1038/s41467-020-16824-2

  23. [23]

      Ulvestad, A.; Singer, A.; Clark, J. N.; Cho, H. M.; Kim, J. W.; Harder, R.; Maser, J.; Meng, Y. S.; Shpyrko, O. G. Science 2015, 348 (6241), 1344. doi: 10.1126/science.aaa1313

  24. [24]

      Robinson, I.; Harder, R. Nat. Mater. 2009, 8 (4), 291. doi: 10.1038/nmat2400

  25. [25]

      Li, H.; Li, J.; Zaker, N.; Zhang, N.; Botton, G. A.; Dahn, J. R. J. Electrochem. Soc. 2019, 166 (10), A1956. doi: 10.1149/2.0681910jes

  26. [26]

      Gao, H.; Wu, Q.; Hu, Y.; Zheng, J. P.; Amine, K.; Chen, Z. J. Phys. Chem. Lett. 2018, 9 (17), 5100. doi: 10.1021/acs.jpclett.8b02229

  27. [27]

      Zhou, H.; Xin, F.; Pei, B.; Whittingham, M. S. ACS Energy Lett. 2019, 4 (8), 1902. doi: 10.1021/acsenergylett.9b01236

  28. [28]

      Kang, S.-H.; Yoon, W.-S.; Nam, K.-W.; Yang, X.-Q.; Abraham, D. P. J. Mater. Sci. 2008, 43 (14), 4701. doi: 10.1007/s10853-007-2355-6

  29. [29]

      Ryu, H.-H.; Namkoong, B.; Kim, J.-H.; Belharouak, I.; Yoon, C. S.; Sun, Y.-K. ACS Energy Lett. 2021, 6 (8), 2726. doi: 10.1021/acsenergylett.1c01089

  30. [30]

      Hu, Q.; Wu, Y.; Ren, D.; Liao, J.; Song, Y.; Liang, H.; Wang, A.; He, Y.; Wang, L.; Chen, Z.; He, X. Energy Storage Mater. 2022, 50, 373. doi: 10.1016/j.ensm.2022.05.038

  31. [31]

      Trevisanello, E.; Ruess, R.; Conforto, G.; Richter, F. H.; Janek, J. Adv. Energy Mater. 2021, 11 (18), 202003400. doi: 10.1002/aenm.202003400

  32. [32]

      Ge, M.; Wi, S.; Liu, X.; Bai, J.; Ehrlich, S.; Lu, D.; Lee, W. K.; Chen, Z.; Wang, F. Angew. Chem. Int. Ed. 2021, 60 (32), 17350. doi: 10.1002/anie.202012773

  33. [33]

      Deng, X.; Zhang, R.; Zhou, K.; Gao, Z.; He, W.; Zhang, L.; Han, C.; Kang, F.; Li, B. Energy Environm. Mater. 2022, 6, e12331. doi: 10.1002/eem2.12331

  34. [34]

      Han, G.-M.; Kim, Y.-S.; Ryu, H.-H.; Sun, Y.-K.; Yoon, C. S. ACS Energy Lett. 2022, 7 (9), 2919. doi: 10.1021/acsenergylett.2c01521

  35. [35]

      Zhong, Z.; Chen, L.; Huang, S.; Shang, W.; Kong, L.; Sun, M.; Chen, L.; Ren, W. J. Mater. Sci. 2019, 55 (7), 2913. doi: 10.1007/s10853-019-04133-z

  36. [36]

      Li, S.; Tian, G.; Xiong, R.; He, R.; Chen, S.; Zhou, H.; Wu, Y.; Han, Z.; Yu, C.; Cheng, S.; Xie, J. Energy Storage Mater. 2022, 46, 443. doi: 10.1016/j.ensm.2022.01.035

  37. [37]

      Lin, F.; Zhao, K.; Liu, Y. ACS Energy Lett. 2021, 6 (11), 4065. doi: 10.1021/acsenergylett.1c02135

  38. [38]

      Tian, C.; Xu, Y.; Nordlund, D.; Lin, F.; Liu, J.; Sun, Z.; Liu, Y.; Doeff, M. Joule 2018, 2 (3), 464. doi: 10.1016/j.joule.2017.12.008

  39. [39]

      Park, K.-Y.; Park, J.-W.; Seong, W. M.; Yoon, K.; Hwang, T.-H.; Ko, K.-H.; Han, J.-H.; Jaedong, Y.; Kang, K. J. Power Sources 2020, 468, 228369. doi: 10.1016/j.jpowsour.2020.228369

  40. [40]

      Merryweather, A. J.; Schnedermann, C.; Jacquet, Q.; Grey, C. P.; Rao, A. Nature 2021, 594 (7864), 522. doi: 10.1038/s41586-021-03584-2

  41. [41]

      Xu, C.; Merryweather, A. J.; Pandurangi, S. S.; Lun, Z.; Hall, D. S.; Deshpande, V. S.; Fleck, N. A.; Schnedermann, C.; Rao, A.; Grey, C. P. Joule 2022, 6 (11), 2535. doi: 10.1016/j.joule.2022.09.008

  42. [42]

      Kuppan, S.; Xu, Y.; Liu, Y.; Chen, G. Nat. Commun. 2017, 8, 14309. doi: 10.1038/ncomms14309

  43. [43]

      Wang, L.; Liu, T.; Dai, A.; De Andrade, V.; Ren, Y.; Xu, W.; Lee, S.; Zhang, Q.; Gu, L.; Wang, S.; et al. Nat. Commun. 2021, 12 (1), 5370. doi: 10.1038/s41467-021-25686-1

  44. [44]

      Liu, T.; Liu, J.; Li, L.; Yu, L.; Diao, J.; Zhou, T.; Li, S.; Dai, A.; Zhao, W.; Xu, S.; et al. Nature 2022, 606 (7913), 305. doi: 10.1038/s41586-022-04689-y

  45. [45]

      Ulvestad, A.; Singer, A.; Cho, H. M.; Clark, J. N.; Harder, R.; Maser, J.; Meng, Y. S.; Shpyrko, O. G. Nano Lett. 2014, 14 (9), 5123. doi: 10.1021/nl501858u

  46. [46]

      Radin, M. D.; Alvarado, J.; Meng, Y. S.; Van der Ven, A. Nano Lett. 2017, 17 (12), 7789. doi: 10.1021/acs.nanolett.7b03989

  47. [47]

      Wang, L.; Liu, T.; Wu, T.; Lu, J. Nature 2022, 611 (7934), 61. doi: 10.1038/s41586-022-05238-3

  48. [48]

      Stallard, J. C.; Wheatcroft, L.; Booth, S. G.; Boston, R.; Corr, S. A.; De Volder, M. F. L.; Inkson, B. J.; Fleck, N. A. Joule 2022, 6 (5), 984. doi: 10.1016/j.joule.2022.04.001

  49. [49]

      Liang, C.; Jiang, L.; Wei, Z.; Zhang, W.; Wang, Q.; Sun, J. J. Energy Chem. 2022, 65, 424. doi: 10.1016/j.jechem.2021.06.010

  50. [50]

      Yu, H.; Cao, Y.; Chen, L.; Hu, Y.; Duan, X.; Dai, S.; Li, C.; Jiang, H. Nat. Commun. 2021, 12 (1), 4564. doi: 10.1038/s41467-021-24893-0

  51. [51]

      Xu, J.; Hu, E.; Nordlund, D.; Mehta, A.; Ehrlich, S. N.; Yang, X. Q.; Tong, W. ACS Appl. Mater. 2016, 8 (46), 31677. doi: 10.1021/acsami.6b11111

  52. [52]

      Zhang, S. S. J. Energy Chem. 2020, 41, 135. doi: 10.1016/j.jechem.2019.05.013

  53. [53]

      Xu, C.; Reeves, P. J.; Jacquet, Q.; Grey, C. P. Adv. Energy Mater. 2020, 11 (7), 202003404. doi: 10.1002/aenm.202003404

  54. [54]

      Ryu, H.-H.; Park, K.-J.; Yoon, C. S.; Sun, Y.-K. Chem. Mater. 2018, 30 (3), 1155. doi: 10.1021/acs.chemmater.7b05269

  55. [55]

      Li, J.; Li, W.; You, Y.; Manthiram, A. Adv. Energy Mater. 2018, 8 (29), 201801957. doi: 10.1002/aenm.201801957

  56. [56]

      Xu, Y.; Hu, E.; Zhang, K.; Wang, X.; Borzenets, V.; Sun, Z.; Pianetta, P.; Yu, X.; Liu, Y.; Yang, X.-Q.; et al. ACS Energy Lett. 2017, 2 (5), 1240. doi: 10.1021/acsenergylett.7b00263

  57. [57]

      Bak, S.-M.; Shadike, Z.; Lin, R.; Yu, X.; Yang, X.-Q. NPG Asia Mater. 2018, 10 (7), 563. doi: 10.1038/s41427-018-0056-z

  58. [58]

      Zhu, J.; Sharifi-Asl, S.; Garcia, J. C.; Iddir, H. H.; Croy, J. R.; Shahbazian-Yassar, R.; Chen, G. ACS Appl. Energ. Mater. 2020, 3 (5), 4799. doi: 10.1021/acsaem.0c00411

  59. [59]

      Tang, Z.; Wang, S.; Liao, J.; Wang, S.; He, X.; Pan, B.; He, H.; Chen, C. Research 2019, 2019, 2198906. doi: 10.34133/2019/2198906

  60. [60]

      Luo, Y.-H.; Pan, Q.-L.; Wei, H.-X.; Huang, Y.-D.; Tang, L.-B.; Wang, Z.-Y.; He, Z.-J.; Yan, C.; Mao, J.; Dai, K.-H.; et al. Nano Energy 2022, 102, 107626. doi: 10.1016/j.nanoen.2022.107626

  61. [61]

      Wei, W.; Ding, Z.; Chen, C.; Yang, C.; Han, B.; Xiao, L.; Liang, C.; Gao, P.; Cho, K. Acta Materialia 2021, 212, 116914. doi: 10.1016/j.actamat.2021.116914

  62. [62]

      Sun, H.-H.; Manthiram, A. Chem. Mater. 2017, 29 (19), 8486. doi: 10.1021/acs.chemmater.7b03268

  63. [63]

      Zou, L.; Zhao, W.; Jia, H.; Zheng, J.; Li, L.; Abraham, D. P.; Chen, G.; Croy, J. R.; Zhang, J.-G.; Wang, C. Chem. Mater. 2020, 32 (7), 2884. doi: 10.1021/acs.chemmater.9b04938

  64. [64]

      Ku, K.; Kim, B.; Jung, S.-K.; Gong, Y.; Eum, D.; Yoon, G.; Park, K.-Y.; Hong, J.; Cho, S.-P.; Kim, D.-H.; et al. Energy Environm. Sci. 2020, 13 (4), 1269. doi: 10.1039/c9ee04123k

  65. [65]

      Kim, U.-H.; Park, G.-T.; Conlin, P.; Ashburn, N.; Cho, K.; Yu, Y.-S.; Shapiro, D. A.; Maglia, F.; Kim, S.-J.; Lamp, P.; et al. Energy Environm. Sci. 2021, 14 (3), 1573. doi: 10.1039/d0ee03774e

  66. [66]

      Li, M.; Lu, J. Science 2020, 367 (6481), 979. doi: 10.1126/science.aba9168

  67. [67]

      Zheng, J.; Teng, G.; Xin, C.; Zhuo, Z.; Liu, J.; Li, Q.; Hu, Z.; Xu, M.; Yan, S.; Yang, W.; Pan, F. J. Phys. Chem. Lett. 2017, 8 (22), 5537. doi: 10.1021/acs.jpclett.7b02498

  68. [68]

      Liu, W.; Oh, P.; Liu, X.; Lee, M. J.; Cho, W.; Chae, S.; Kim, Y.; Cho, J. Angew. Chem. Int. Ed. 2015, 54 (15), 4440. doi: 10.1002/anie.201409262

  69. [69]

      Myung, S.-T.; Maglia, F.; Park, K.-J.; Yoon, C. S.; Lamp, P.; Kim, S.-J.; Sun, Y.-K. ACS Energy Lett. 2016, 2 (1), 196. doi: 10.1021/acsenergylett.6b00594

  70. [70]

      Chu, B.; Guo, Y.-J.; Shi, J.-L.; Yin, Y.-X.; Huang, T.; Su, H.; Yu, A.; Guo, Y.-G.; Li, Y. J. Power Sources 2022, 544, 231873. doi: 10.1016/j.jpowsour.2022.231873

  71. [71]

      Hwang, S.; Chang, W.; Kim, S. M.; Su, D.; Kim, D. H.; Lee, J. Y.; Chung, K. Y.; Stach, E. A. Chem. Mater. 2014, 26 (2), 1084. doi: 10.1021/cm403332s

  72. [72]

      Kondrakov, A. O.; Geßwein, H.; Galdina, K.; de Biasi, L.; Meded, V.; Filatova, E. O.; Schumacher, G.; Wenzel, W.; Hartmann, P.; Brezesinski, T.; et al. J. Phys. Chem. C 2017, 121 (44), 24381. doi: 10.1021/acs.jpcc.7b06598

  73. [73]

      de Biasi, L.; Schwarz, B.; Brezesinski, T.; Hartmann, P.; Janek, J.; Ehrenberg, H. Adv. Mater. 2019, 31 (26), e1900985. doi: 10.1002/adma.201900985

  74. [74]

      Xu, C.; Marker, K.; Lee, J.; Mahadevegowda, A.; Reeves, P. J.; Day, S. J.; Groh, M. F.; Emge, S. P.; Ducati, C.; Mehdi, B. L.; et al. Nat. Mater. 2021, 20 (1), 84. doi: 10.1038/s41563-020-0767-8

  75. [75]

      Park, K.-J.; Jung, H.-G.; Kuo, L.-Y.; Kaghazchi, P.; Yoon, C. S.; Sun, Y.-K. Adv. Energy Mater. 2018, 8 (25), 201801202. doi: 10.1002/aenm.201801202

  76. [76]

      Bi, Y.; Tao, J.; Wu, Y.; Li, L.; Xu, Y.; Hu, E.; Wu, B.; Hu, J.; Wang, C.; Zhang, J. G.; Qi, Y.; Xiao, J. Science 2020, 370 (6522), 1313. doi: 10.1126/science.abc3167

  77. [77]

      Meng, X. H.; Lin, T.; Mao, H.; Shi, J. L.; Sheng, H.; Zou, Y. G.; Fan, M.; Jiang, K.; Xiao, R. J.; Xiao, D.; et al. J. Am. Chem. Soc. 2022, 144 (25), 11338. doi: 10.1021/jacs.2c03549

  78. [78]

      Yan, P.; Zheng, J.; Gu, M.; Xiao, J.; Zhang, J. G.; Wang, C. M. Nat. Commun. 2017, 8, 14101. doi: 10.1038/ncomms14101

  79. [79]

      Shadow Huang, H.-Y.; Wang, Y.-X. J. Electrochem. Soc. 2012, 159 (6), A815. doi: 10.1149/2.090206jes

  80. [80]

      Li, W.; Kim, U. H.; Dolocan, A.; Sun, Y. K.; Manthiram, A. ACS Nano 2017, 11 (6), 5853. doi: 10.1021/acsnano.7b01494

  81. [81]

      Yoon, C. S.; Park, K.-J.; Kim, U.-H.; Kang, K. H.; Ryu, H.-H.; Sun, Y.-K. Chem. Mater. 2017, 29 (24), 10436. doi: 10.1021/acs.chemmater.7b04047

  82. [82]

      Kim, H.; Kim, M. G.; Jeong, H. Y.; Nam, H.; Cho, J. Nano Lett. 2015, 15 (3), 2111. doi: 10.1021/acs.nanolett.5b00045

  83. [83]

      Goodenough, J. B.; Park, K. S. J. Am. Chem. Soc. 2013, 135 (4), 1167. doi: 10.1021/ja3091438

  84. [84]

      Liu, H.; Harris, K. J.; Jiang, M.; Wu, Y.; Goward, G. R.; Botton, G. A. ACS Nano 2018, 12 (3), 2708. doi: 10.1021/acsnano.7b08945

  85. [85]

      Steiner, J. D.; Mu, L.; Walsh, J.; Rahman, M. M.; Zydlewski, B.; Michel, F. M.; Xin, H. L.; Nordlund, D.; Lin, F. ACS Appl. Mater. 2018, 10 (28), 23842. doi: 10.1021/acsami.8b06399

  86. [86]

      Eum, D.; Kim, B.; Kim, S. J.; Park, H.; Wu, J.; Cho, S. P.; Yoon, G.; Lee, M. H.; Jung, S. K.; Yang, W.; et al. Nat. Mater. 2020, 19 (4), 419. doi: 10.1038/s41563-019-0572-4

  87. [87]

      House, R. A.; Rees, G. J.; Pérez-Osorio, M. A.; Marie, J.-J.; Boivin, E.; Robertson, A. W.; Nag, A.; Garcia-Fernandez, M.; Zhou, K.-J.; Bruce, P. G. Nat. Energy 2020, 5 (10), 777. doi: 10.1038/s41560-020-00697-2

  88. [88]

      Csernica, P. M.; Kalirai, S. S.; Gent, W. E.; Lim, K.; Yu, Y.-S.; Liu, Y.; Ahn, S.-J.; Kaeli, E.; Xu, X.; Stone, K. H.; et al. Nat. Energy 2021, 6 (6), 642. doi: 10.1038/s41560-021-00832-7

  89. [89]

      Hou, X.-Y.; Kimura, Y.; Tamenori, Y.; Nitta, K.; Yamagishi, H.; Amezawa, K.; Nakamura, T. ACS Energy Lett. 2022, 7 (5), 1687. doi: 10.1021/acsenergylett.2c00353

  90. [90]

      Shi, C. G.; Peng, X.; Dai, P.; Xiao, P.; Zheng, W. C.; Li, H. Y.; Li, H.; Indris, S.; Mangold, S.; Hong, Y. H.; et al. Adv. Energy Mater. 2022, 12 (20), 202200569. doi: 10.1002/aenm.202200569

  91. [91]

      Wandt, J.; Freiberg, A. T. S.; Ogrodnik, A.; Gasteiger, H. A. Mater. Today 2018, 21 (8), 825. doi: 10.1016/j.mattod.2018.03.037

  92. [92]

      Wan, G.; Dou, W.; Zhu, H.; Zhang, W.; Liu, T.; Wang, L.; Lu, J. Interdisciplinary Mater. 2023, 2 (3), 416. doi: 10.1002/idm2.12091

  93. [93]

      Sharifi-Asl, S.; Lu, J.; Amine, K.; Shahbazian-Yassar, R. Adv. Energy Mater. 2019, 9 (22), 201900551. doi: 10.1002/aenm.201900551

  94. [94]

      Wang, K.; Wan, J.; Xiang, Y.; Zhu, J.; Leng, Q.; Wang, M.; Xu, L.; Yang, Y. J. Power Sources 2020, 460, 228062. doi: 10.1016/j.jpowsour.2020.228062

  95. [95]

      Li, F.; Kong, L.; Sun, Y.; Jin, Y.; Hou, P. J. Mater. Chem. A 2018, 6 (26), 12344. doi: 10.1039/c8ta03363c

  96. [96]

      Jiao, J.; Lai, G.; Qin, S.; Fang, C.; Xu, X.; Jiang, Y.; Ouyang, C.; Zheng, J. Acta Mater. 2022, 238, 118229. doi: 10.1016/j.actamat.2022.118229

  97. [97]

      Ni, L.; Guo, R.; Deng, W.; Wang, B.; Chen, J.; Mei, Y.; Gao, J.; Gao, X.; Yin, S.; Liu, H.; et al. Chem. Eng. J. 2022, 431, 133731. doi: 10.1016/j.cej.2021.133731

  98. [98]

      Wang, J.; Lu, X.; Zhang, Y.; Zhou, J.; Wang, J.; Xu, S. J. Energy Chem. 2022, 65, 681. doi: 10.1016/j.jechem.2021.06.017

  99. [99]

      Shi, J. L.; Sheng, H.; Meng, X. H.; Zhang, X. D.; Lei, D.; Sun, X.; Pan, H.; Wang, J.; Yu, X.; Wang, C.; et al. Natl Sci Rev 2023, 10 (2), nwac226. doi: 10.1093/nsr/nwac226

  100. [100]

       Kim, Y. ACS Appl. Mater. 2012, 4 (5), 2329. doi: 10.1021/am300386j

  101. [101]

       Liang, C.; Longo, R. C.; Kong, F.; Zhang, C.; Nie, Y.; Zheng, Y.; Cho, K. ACS Appl. Mater. 2018, 10 (7), 6673. doi: 10.1021/acsami.7b17424

  102. [102]

       Zhu, J.; Chen, G. J. Mater. Chem. A 2019, 7 (10), 5463. doi: 10.1039/c8ta10329a

  103. [103]

       Lu, Y.; Zhu, T.; McShane, E.; McCloskey, B. D.; Chen, G. Small 2022, 18 (12), e2105833. doi: 10.1002/smll.202105833

  104. [104]

       Zhang, H.; Omenya, F.; Yan, P.; Luo, L.; Whittingham, M. S.; Wang, C.; Zhou, G. ACS Energy Lett. 2017, 2 (11), 2607. doi: 10.1021/acsenergylett.7b00907

  105. [105]

       Garcia, J. C.; Bareño, J.; Yan, J.; Chen, G.; Hauser, A.; Croy, J. R.; Iddir, H. J. Phys. Chem. C 2017, 121 (15), 8290. doi: 10.1021/acs.jpcc.7b00896

  106. [106]

       Ryu, H.-H.; Lee, S.-B.; Yoon, C. S.; Sun, Y.-K. ACS Energy Lett. 2022, 7 (9), 3072. doi: 10.1021/acsenergylett.2c01670

  107. [107]

       Liu, J.; Yuan, Y.; Zheng, J.; Wang, L.; Ji, J.; Zhang, Q.; Yang, L.; Bai, Z.; Lu, J. Angew. Chem. Int. Ed. 2023, 62 (20), e202302547. doi: 10.1002/anie.202302547

  108. [108]

       Kimijima, T.; Zettsu, N.; Teshima, K. Crystal Growth Des. 2016, 16 (5), 2618. doi: 10.1021/acs.cgd.5b01723

  109. [109]

       Jeon, H.; Kwon, D.-H.; Kim, H.; Lee, J.-H.; Jun, Y.; Son, J.-W.; Park, S. Chem. Eng. J. 2022, 445. doi: 10.1016/j.cej.2022.136828

  110. [110]

       Huang, H.; Zhang, L.; Tian, H.; Yan, J.; Tong, J.; Liu, X.; Zhang, H.; Huang, H.; Hao, S. M.; Gao, J.; et al. Adv. Energy Mater. 2022, 13 (3), 202203188. doi: 10.1002/aenm.202203188

  111. [111]

       Yoon, M.; Dong, Y.; Huang, Y.; Wang, B.; Kim, J.; Park, J.-S.; Hwang, J.; Park, J.; Kang, S. J.; Cho, J.; et al. Nat. Energy 2023, 8 (5), 482. doi: 10.1038/s41560-023-01233-8

  112. [112]

       Yin, S.; Deng, W.; Chen, J.; Gao, X.; Zou, G.; Hou, H.; Ji, X. Nano Energy 2021, 83, 105854. doi: 10.1016/j.nanoen.2021.105854

  113. [113]

       Oh, P.; Yun, J.; Park, S.; Nam, G.; Liu, M.; Cho, J. Adv. Energy Mater. 2020, 11 (15), 202003197. doi: 10.1002/aenm.202003197

  114. [114]

       Ko, G.; Jeong, S.; Park, S.; Lee, J.; Kim, S.; Shin, Y.; Kim, W.; Kwon, K. Energy Storage Mater. 2023, 60, 102840. doi: 10.1016/j.ensm.2023.102840

  115. [115]

       Kim, U.-H.; Kuo, L.-Y.; Kaghazchi, P.; Yoon, C. S.; Sun, Y.-K. ACS Energy Lett. 2019, 4 (2), 576. doi: 10.1021/acsenergylett.8b02499

  116. [116]

       Li, C.; Kan, W. H.; Xie, H.; Jiang, Y.; Zhao, Z.; Zhu, C.; Xia, Y.; Zhang, J.; Xu, K.; Mu, D.; Wu, F. Adv. Sci. 2019, 6 (4), 1801406. doi: 10.1002/advs.201801406

  117. [117]

       李节宾, 徐友龙, 杜显锋, 孙孝飞, 熊礼龙. 物理化学学报, 2012, 28 (8), 1899. doi: 10.3866/PKU.WHXB201205152Jie-Bin, L. I.; You-Long, X. U.; Xian-Feng, D. U.; Xiao-Fei, S. U. N.; Li-Long, X. Acta Phys. -Chim. Sin. 2012, 28 (8), 1899. doi: 10.3866/PKU.WHXB201205152

  118. [118]

       Mu, L.; Kan, W. H.; Kuai, C.; Yang, Z.; Li, L.; Sun, C. J.; Sainio, S.; Avdeev, M.; Nordlund, D.; Lin, F. ACS Appl. Mater. 2020, 12 (11), 12874. doi: 10.1021/acsami.0c00111

  119. [119]

       Zheng, H.; Zhang, C.; Zhang, Y.; Lin, L.; Liu, P.; Wang, L.; Wei, Q.; Lin, J.; Sa, B.; Xie, Q.; et al. Adv. Funct. Mater. 2021, 31 (30), 202100783. doi: 10.1002/adfm.202100783

  120. [120]

       Liu, Q.; Xie, T.; Xie, Q.; He, W.; Zhang, Y.; Zheng, H.; Lu, X.; Wei, W.; Sa, B.; Wang, L.; et al. ACS Appl. Mater. 2021, 13 (7), 8239. doi: 10.1021/acsami.0c19040

  121. [121]

       Yao, W.; Liu, Y.; Li, D.; Zhang, Q.; Zhong, S.; Cheng, H.; Yan, Z. J. Phys. Chem. C 2020, 124 (4), 2346. doi: 10.1021/acs.jpcc.9b10526

  122. [122]

       Li, Y.; Wang, X.; Zhang, W.; He, Y.; Ma, Z. Chin. J. Process Eng. 2018, 18 (2), 422. doi: 10.12034/j.issn.1009-606X.217296

  123. [123]

       Ding, X.; Li, Y.-X.; Deng, M.-M.; Wang, S.; Aqsa, Y.; Hu, Q.; Chen, C.-H. J. Alloy. Compd. 2019, 791, 100. doi: 10.1016/j.jallcom.2019.03.297

  124. [124]

       Weigel, T.; Schipper, F.; Erickson, E. M.; Susai, F. A.; Markovsky, B.; Aurbach, D. ACS Energy Lett. 2019, 4 (2), 508. doi: 10.1021/acsenergylett.8b02302

  125. [125]

       Rajkamal, A.; Kim, H. ACS Appl. Energ. Mater. 2021, 4 (12), 14068. doi: 10.1021/acsaem.1c02837

  126. [126]

       杨祖光, 滑纬博, 张军, 陈九华, 何凤荣, 钟本和, 郭孝东. 物理化学学报, 2016, 32 (5), 1056. doi: 10.3866/PKU.WHXBb201603092Yang, Z.-G.; Hua, W.-B.; Zhang, J.; Chen, J.-H.; He, F.-R.; Zhong, B.-H.; Guo, X.-D. Acta Phys. -Chim. Sin. 2016, 32 (5), 1056. doi: 10.3866/PKU.WHXBb201603092

  127. [127]

       Gao, S.; Cheng, Y. T.; Shirpour, M. ACS Appl. Mater. 2019, 11 (1), 982. doi: 10.1021/acsami.8b19349

  128. [128]

       Qian, G.; Huang, H.; Hou, F.; Wang, W.; Wang, Y.; Lin, J.; Lee, S.-J.; Yan, H.; Chu, Y. S.; Pianetta, P.; et al. Nano Energy 2021, 84, 105926. doi: 10.1016/j.nanoen.2021.105926

  129. [129]

       Kam, D.; Choi, M.; Park, D.; Choi, W. Chem. Eng. J. 2023, 472, 144885. doi: 10.1016/j.cej.2023.144885

  130. [130]

       Zou, Y. G.; Mao, H.; Meng, X. H.; Du, Y. H.; Sheng, H.; Yu, X.; Shi, J. L.; Guo, Y. G. Angew. Chem. Int. Ed. 2021, 60 (51), 26535. doi: 10.1002/anie.202111954

  131. [131]

       Jamil, S.; Fasehullah, M.; Jabar, B.; Liu, P.; Aslam, M. K.; Zhang, Y.; Bao, S.; Xu, M. Nano Energy 2022, 94, 106961. doi: 10.1016/j.nanoen.2022.106961

  132. [132]

       Ou, X.; Liu, T.; Zhong, W.; Fan, X.; Guo, X.; Huang, X.; Cao, L.; Hu, J.; Zhang, B.; Chu, Y. S.; et al. Nat. Commun. 2022, 13 (1), 2319. doi: 10.1038/s41467-022-30020-4

  133. [133]

       Zhang, Q.; Deng, Q.; Zhong, W.; Li, J.; Wang, Z.; Dong, P.; Huang, K.; Yang, C. Adv. Funct. Mater. 2023, 33 (27), 202301336. doi: 10.1002/adfm.202301336

  134. [134]

       Guo, Y. J.; Zhang, C. H.; Xin, S.; Shi, J. L.; Wang, W. P.; Fan, M.; Chang, Y. X.; He, W. H.; Wang, E.; Zou, Y. G.; et al. Angew. Chem. Int. Ed. 2022, 61 (21), e202116865. doi: 10.1002/anie.202116865

  135. [135]

       Ni, L.; Chen, H.; Deng, W.; Wang, B.; Chen, J.; Mei, Y.; Zou, G.; Hou, H.; Guo, R.; Xie, J.; Ji, X. Adv. Energy Mater. 2022, 12 (11), 202103757. doi: 10.1002/aenm.202103757

  136. [136]

       Li, H.; Zhou, P.; Liu, F.; Li, H.; Cheng, F.; Chen, J. Chem. Sci. 2019, 10 (5), 1374. doi: 10.1039/c8sc03385d

  137. [137]

       Wu, F.; Liu, N.; Chen, L.; Li, N.; Lu, Y.; Cao, D.; Xu, M.; Wang, Z.; Su, Y. ACS Appl. Mater. 2021, 13 (21), 24925. doi: 10.1021/acsami.1c05486

  138. [138]

       Zhang, M. J.; Teng, G.; Chen-Wiegart, Y. K.; Duan, Y.; Ko, J. Y. P.; Zheng, J.; Thieme, J.; Dooryhee, E.; Chen, Z.; Bai, J.; et al. J. Am. Chem. Soc. 2018, 140 (39), 12484. doi: 10.1021/jacs.8b06150

  139. [139]

       Duan, Y.; Yang, L.; Zhang, M.-J.; Chen, Z.; Bai, J.; Amine, K.; Pan, F.; Wang, F. J. Mater. Chem. A 2019, 7 (2), 513. doi: 10.1039/c8ta10553g

  140. [140]

       Meng, X. H.; Zhang, X. D.; Sheng, H.; Fan, M.; Lin, T.; Xiao, D.; Tian, J.; Wen, R.; Liu, W. Z.; Shi, J. L.; et al. Angew. Chem. Int. Ed. 2023, 62 (22), e202302170. doi: 10.1002/anie.202302170

  141. [141]

       苏岳锋, 张其雨, 陈来, 包丽颖, 卢赟, 陈实, 吴锋. 物理化学学报, 2021, 37 (3), 2005062. doi: 10.3866/PKU.WHXB202005062Su, Y.; Zhang, Q.; Chen, L.; Bao, L.; Lu, Y.; Chen, S.; Wu, F. Acta Phys. -Chim. Sin. 2020, 37 (3), 2005062. doi: 10.3866/PKU.WHXB202005062

  142. [142]

       Liu, Q.; Liu, Y. T.; Zhao, C.; Weng, Q. S.; Deng, J.; Hwang, I.; Jiang, Y.; Sun, C.; Li, T.; Xu, W.; et al. ACS Nano 2022, 16 (9), 14527. doi: 10.1021/acsnano.2c04959

  143. [143]

       Guo, H. J.; Sun, Y.; Zhao, Y.; Liu, G. X.; Song, Y. X.; Wan, J.; Jiang, K. C.; Guo, Y. G.; Sun, X.; Wen, R. Angew. Chem. Int. Ed. 2022, 61 (48), e202211626. doi: 10.1002/anie.202211626

  144. [144]

       Li, Y.; Wan, C.; Tian, Y.; Li, J.; Yang, C.; Zhang, W.; Zhang, X.; Hao, Z.; Yang, Z.; Guo, P.; et al. Appl. Surf. Sci. 2023, 609, 155162. doi: 10.1016/j.apsusc.2022.155162

  145. [145]

       Fan, X.; Ou, X.; Zhao, W.; Liu, Y.; Zhang, B.; Zhang, J.; Zou, L.; Seidl, L.; Li, Y.; Hu, G.; Battaglia, C.; Yang, Y. Nat. Commun. 2021, 12 (1), 5320. doi: 10.1038/s41467-021-25611-6

  146. [146]

       Bai, H.; Yuan, K.; Zhang, C.; Zhang, W.; Tang, X.; Jiang, S.; Jin, T.; Ma, Y.; Kou, L.; Shen, C.; Xie, K. Energy Storage Mater. 2023, 61, 102879. doi: 10.1016/j.ensm.2023.102879

  147. [147]

       Jiang, W.; Zhu, X.; Huang, R.; Zhao, S.; Fan, X.; Ling, M.; Liang, C.; Wang, L. Adv. Energy Mater. 2022, 12 (13), 202103473. doi: 10.1002/aenm.202103473

  148. [148]

       Kim, S. Y.; Cha, H.; Kostecki, R.; Chen, G. ACS Energy Lett. 2022, 8 (1), 521. doi: 10.1021/acsenergylett.2c02414

  149. [149]

       Han, Y.; Jung, S. H.; Kwak, H.; Jun, S.; Kwak, H. H.; Lee, J. H.; Hong, S. T.; Jung, Y. S. Adv. Energy Mater. 2021, 11 (21), 202100126. doi: 10.1002/aenm.202100126

  150. [150]

       Minnmann, P.; Strauss, F.; Bielefeld, A.; Ruess, R.; Adelhelm, P.; Burkhardt, S.; Dreyer, S. L.; Trevisanello, E.; Ehrenberg, H.; Brezesinski, T.; et al. Adv. Energy Mater. 2022, 12 (35), 202201425. doi: 10.1002/aenm.202201425

  151. [151]

       赵永智, 陈晨阳, 刘文燚, 胡伟飞, 刘金平. 物理化学学报, 2023, 39 (8), 2211017. doi: 10.3866/PKU.WHXB202211017Zhao, Y.; Chen, C.; Liu, W.; Hu, W.; Liu, J. Acta Phys. -Chim. Sin. 2023, 39 (8), 2211017. doi: 10.3866/PKU.WHXB202211017

  152. [152]

       Yi, M.; Li, J.; Wang, M.; Fan, X.; Hong, B.; Zhang, Z.; Zhang, Z.; Jiang, H.; Wang, A.; Lai, Y. Energy Storage Mater. 2023, 54, 579. doi: 10.1016/j.ensm.2022.11.007

  153. [153]

       Su, Y.; Liu, X.; Yan, H.; Zhao, J.; Cheng, Y.; Luo, Y.; Gu, J.; Zhong, H.; Fu, A.; Wang, K.; et al. Nano Energy 2023, 113, 108572. doi: 10.1016/j.nanoen.2023.108572

  154. [154]

       Tian, R.; Wang, Z.; Liao, J.; Zhang, H.; Song, D.; Zhu, L.; Zhang, L. Adv. Energy Mater. 2023, 13 (26), 202300850. doi: 10.1002/aenm.202300850

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