English

Designing Electrolytes for Aqueous Electrocatalytic CO₂ Reduction

• Youwen Rong ^{1, 2,} ,
• Jiaqi Sang ^{2, 3,} ,
• Li Che ^{1, ,} ,
• Dunfeng Gao ^{2, ,} ,
• Guoxiong Wang ^2,

• 1.

  School of Science, Dalian Maritime University, Dalian 116026, Liaoning Province, China

• 2.

  State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning Province, China

• 3.

  University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Li Che, liche@dlmu.edu.cn Dunfeng Gao, dfgao@dicp.ac.cn

• Received Date: 16 December 2022
  Accepted Date: 02 January 2023
  Revised Date: 02 January 2023
  Available Online: 15 May 2023
• Fund Project:

Abstract: As an emerging technology for achieving carbon neutrality, the electrocatalytic CO₂ reduction reaction (CO₂RR) converts CO₂ and water to valuable fuels and chemicals with power supply from renewable energy. Currently, the practical application of the CO₂RR suffers from insufficient electrocatalytic performance in terms of selectivity, reaction rate, energy efficiency, and long-term stability. Electrolytes are considered as equally critical as catalysts for enhancing the CO₂RR performance. From a catalysis perspective, electrolytes significantly affect the reaction microenvironments around catalytically active sites. From an electrochemical perspective, electrolytes determine the electric double layer structure. The electrocatalytic electrode/electrolyte interface where the CO₂RR takes place is strongly influenced by electrolyte composition and identity. Thus, beyond catalyst design, rational electrolyte design is an alternative strategy for advancing the CO₂RR towards industrial applications. This review presents important electrolyte effects in the aqueous CO₂RR using the most recent studies, with an emphasis on those conducted under industrially-relevant reaction conditions. The effects of (local) pH, cations, and anions in aqueous inorganic electrolytes and their coupled effects with solid polymer electrolytes on tuning the activity and selectivity of the CO₂RR are summarized. Although their influences on CO₂RR performance are interconnected, pH effects, cation effects, and anion effects as well as electrolyte effects in membrane electrode assembly (MEA) electrolyzers are discussed separately considering the leading role of each factor. The experimentally observed performance dependence on the electrolyte composition and identity as well as the underlying reaction mechanism are discussed. The unique role of vibrational spectroscopies, such as surface-enhanced infrared absorption and Raman, in the characterization of electrode/electrolyte interfaces and the elucidation of electrolyte effects is highlighted. An innovative experimental strategy that involves the validation of specific adsorption of alkali-metal cations on the surface of an electrode by precisely monitoring the vibrational spectroscopic characteristics of probe molecules is highly recommended. The review focuses on the pH-dependent electrocatalytic performance and reaction pathways, the uncertain mechanisms of cation effects, and the roles of typical anions, such as bicarbonate and halides. Particularly, emphasis is given to the transport of key species, such as anions, cations, water, and products in ion exchange membranes, as well as their dynamic behaviors at the electrode/electrolyte interface in MEA CO₂ electrolyzers. Although it has some drawbacks, anion exchange membranes are currently the most promising polymer electrolytes for practical application of the CO₂RR. However, some emerging strategies based on cation exchange and bipolar membranes as well as tandem electrolysis processes are in progress. In all cases, a detailed understanding of electrolyte effects in the complex environments of MEA electrolyzers is indispensable for achieving performance enhancement. In conclusion, the remaining challenges and research opportunities in terms of the experimental and theoretical investigation of the electrolyte effects in the CO₂RR process are proposed. This review provides novel insights into rational electrolyte design and useful guidelines for researchers in the field.

Key words:
• Electrocatalytic CO₂ electroreduction
•  /  Electrolyte effect
•  /  Electric double layer
•  /  pH effect
•  /  Cation effect
•  /  Anion effect
•  /  Solid polymer electrolyte
•  /  Membrane electrode assembly

• 1. [1]

     Artz, J.; Muller, T. E.; Thenert, K.; Kleinekorte, J.; Meys, R.; Sternberg, A.; Bardow, A.; Leitner, W. Chem. Rev. 2018, 118, 434. doi: 10.1021/acs.chemrev.7b00435

  2. [2]

     Burkart, M. D.; Hazari, N.; Tway, C. L.; Zeitler, E. L. ACS Catal. 2019, 9, 7937. doi: 10.1021/acscatal.9b02113

  3. [3]

     Gao, D.; Li, W.; Wang, H.; Wang, G.; Cai, R. Trans. Tianjin Univ. 2022, 28, 245. doi: 10.1007/s12209-022-00326-x

  4. [4]

     Chen, C.; Kotyk, J. F. K.; Sheehan, S. W. Chem 2018, 4, 2571. doi: 10.1016/j.chempr.2018.08.019

  5. [5]

     Sanchez, O. G.; Birdja, Y. Y.; Bulut, M.; Vaes, J.; Breugelmans, T.; Pant, D. Curr. Opin. Green Sustain. Chem. 2019, 16, 47. doi: 10.1016/j.cogsc.2019.01.005

  6. [6]

     Tang, C.; Zheng, Y.; Jaroniec, M.; Qiao, S. Z. Angew. Chem. Int. Ed. 2021, 60, 19572. doi: 10.1002/anie.202101522

  7. [7]

     Wen, G; Ren, B.; Wang, X.; Luo, D.; Dou, H.; Zheng, Y.; Gao, R.; Gostick, J.; Yu, A.; Chen, Z. Nat. Energy 2022, 7, 978. doi: 10.1038/s41560-022-01130-6

  8. [8]

     Zhou, Y. S.; Martin, A. J.; Dattila, F.; Xi, S. B.; Lopez, N.; Perez-Ramirez, J.; Yeo, B. S. Nat. Catal. 2022, 5, 545. doi: 10.1038/s41929-022-00803-5

  9. [9]

     Zang, Y.; Wei, P.; Li, H.; Gao, D.; Wang, G. Electrochem. Energy Rev. 2022, 5, 29. doi: 10.1007/s41918-022-00140-y

  10. [10]

      Zhang, G.; Wang, T.; Zhang, M.; Li, L.; Cheng, D.; Zhen, S.; Wang, Y.; Qin, J.; Zhao, Z.-J.; Gong, J. Nat. Commun. 2022, 13, 7768. doi: 10.1038/s41467-022-35450-8

  11. [11]

      Shin, H.; Hansen, K. U.; Jiao, F. Nat. Sustain. 2021, 4, 911. doi: 10.1038/s41893-021-00739-x

  12. [12]

      Masel, R. I.; Liu, Z. C.; Yang, H. Z.; Kaczur, J. J.; Carrillo, D.; Ren, S. X.; Salvatore, D.; Berlinguette, C. P. Nat. Nanotechnol. 2021, 16, 118. doi: 10.1038/s41565-020-00823-x

  13. [13]

      Wakerley, D.; Lamaison, S.; Wicks, J.; Clemens, A.; Feaster, J.; Corral, D.; Jaffer, S. A.; Sarkar, A.; Fontecave, M.; Duoss, E. B.; et al. Nat. Energy 2022, 7, 130. doi: 10.1038/s41560-021-00973-9

  14. [14]

      Gao, D.; Cai, F.; Wang, G.; Bao, X. Curr. Opin. Green Sustain. Chem. 2017, 3, 39. doi: 10.1016/j.cogsc.2016.10.004

  15. [15]

      Gao, D.; Aran-Ais, R. M.; Jeon, H. S.; Roldan Cuenya, B. Nat. Catal. 2019, 2, 198. doi: 10.1038/s41929-019-0235-5

  16. [16]

      Zhu, Y.; Cui, X.; Liu, H.; Guo, Z.; Dang, Y.; Fan, Z.; Zhang, Z.; Hu, W. Nano Res. 2021, 14, 4471. doi: 10.1007/s12274-021-3448-2

  17. [17]

      Gao, D.; Liu, T.; Wang, G.; Bao, X. ACS Energy Lett. 2021, 6, 713. doi: 10.1021/acsenergylett.0c02665

  18. [18]

      Zhai, Y.; Han, P.; Yun, Q.; Ge, Y.; Zhang, X.; Chen, Y.; Zhang, H. eScience 2022, 2, 467. doi: 10.1016/j.esci.2022.09.002

  19. [19]

      郝磊端, 孙振宇. 物理化学学报, 2021, 37, 2009033 doi: 10.3866/PKU.WHXB202009033Hao, L.; Sun, Z. Acta Phys. -Chim. Sin. 2021, 37, 2009033. doi: 10.3866/PKU.WHXB202009033

  20. [20]

      孟怡辰, 况思宇, 刘海, 范群, 马新宾, 张生. 物理化学学报, 2021, 37, 2006034. doi: 10.3866/PKU.WHXB202006034Meng, Y.; Kuang, S.; Liu, H.; Fan, Q.; Ma, X.; Zhang, S. Acta Phys. -Chim. Sin. 2021, 37, 2006034. doi: 10.3866/PKU.WHXB202006034

  21. [21]

      Burdyny, T.; Smith, W. A. Energy Environ. Sci. 2019, 12, 1442. doi: 10.1039/C8EE03134G

  22. [22]

      Higgins, D.; Hahn, C.; Xiang, C. X.; Jaramillo, T. F.; Weber, A. Z. ACS Energy Lett. 2019, 4, 317. doi: 10.1021/acsenergylett.8b02035

  23. [23]

      Sa, Y. J.; Lee, C. W.; Lee, S. Y.; Na, J.; Lee, U.; Hwang, Y. J. Chem. Soc. Rev. 2020, 49, 6632. doi: 10.1039/D0CS00030B

  24. [24]

      高敦峰, 魏鹏飞, 李合肥, 林龙, 汪国雄, 包信和. 物理化学学报, 2021, 37, 200921. doi: 10.3866/PKU.WHXB202009021Gao, D.; Wei, P.; Li, H.; Lin, L.; Wang, G.; Bao, X. Acta Phys. -Chim. Sin. 2021, 37, 2009021. doi: 10.3866/PKU.WHXB202009021

  25. [25]

      Lees, E. W.; Mowbray, B. A. W.; Parlane, F. G. L.; Berlinguette, C. P. Nat. Rev. Mater. 2022, 7, 55. doi: 10.1038/s41578-021-00356-2

  26. [26]

      Dickinson, E. J. F.; Limon-Petersen, J. G.; Rees, N. V.; Compton, R. G. J. Phys. Chem. C 2009, 113, 11157. doi: 10.1021/jp901628h

  27. [27]

      Strmcnik, D.; Kodama, K.; van der Vliet, D.; Greeley, J.; Stamenkovic, V. R.; Markovic, N. M. Nat. Chem. 2009, 1, 466. doi: 10.1038/nchem.330

  28. [28]

      Ledezma-Yanez, I.; Wallace, W. D. Z.; Sebastian-Pascual, P.; Climent, V.; Feliu, J. M.; Koper, M. T. M. Nat. Energy 2017, 2, 17031. doi: 10.1038/nenergy.2017.31

  29. [29]

      Aran-Ais, R. M.; Gao, D.; Roldan Cuenya, B. Acc. Chem. Res. 2018, 51, 2906. doi: 10.1021/acs.accounts.8b00360

  30. [30]

      Konig, M.; Vaes, J.; Klemm, E.; Pant, D. iScience 2019, 19, 135. doi: 10.1016/j.isci.2019.07.014

  31. [31]

      Pupo, M. M. D.; Kortlever, R. ChemPhysChem. 2019, 20, 2926. doi: 10.1002/cphc.201900680

  32. [32]

      Sebastian-Pascual, P.; Mezzavilla, S.; Stephens, I. E. L.; Escudero-Escribano, M. ChemCatChem 2019, 11, 3624. doi: 10.1002/cctc.201900552

  33. [33]

      Marcandalli, G.; Monteiro, M. C. O.; Goyal, A.; Koper, M. T. M. Acc. Chem. Res. 2022, 55, 1900. doi: 10.1021/acs.accounts.2c00080

  34. [34]

      Xu, A. N.; Govindarajan, N.; Kastlunger, G.; Vijay, S.; Chan, K. R. Acc. Chem. Res. 2022, 55, 495. doi: 10.1021/acs.accounts.1c00679

  35. [35]

      Deng, B.; Huang, M.; Zhao, X.; Mou, S.; Dong, F. ACS Catal. 2022, 12, 331. doi: 10.1021/acscatal.1c03501

  36. [36]

      Gill, T. M.; Furst, A. L. Curr. Opin. Electrochem. 2022, 35, 101061. doi: 10.1016/j.coelec.2022.101061

  37. [37]

      Bui, J. C.; Kim, C.; King, A. J.; Romiluyi, O.; Kusoglu, A.; Weber, A. Z.; Bell, A. T. Acc. Chem. Res. 2022, 55, 484. doi: 10.1021/acs.accounts.1c00650

  38. [38]

      Wagner, A.; Sahm, C. D.; Reisner, E. Nat. Catal. 2020, 3, 775. doi: 10.1038/s41929-020-00512-x

  39. [39]

      Lv, J.; Yin, R.; Zhou, L.; Li, J.; Kikas, R.; Xu, T.; Wang, Z.; Jin, H.; Wang, X.; Wang, S. Angew. Chem. Int. Ed. 2022, 61, e202207252. doi: 10.1002/anie.202207252

  40. [40]

      Shin, S. J.; Kim, D. H.; Bae, G.; Ringe, S.; Choi, H.; Lim, H. K.; Choi, C. H.; Kim, H. Nat. Commun. 2022, 13, 174. doi: 10.1038/s41467-021-27909-x

  41. [41]

      Sebastian-Pascual, P.; Shao-Horn, Y.; Escudero-Escribano, M. Curr. Opin. Electrochem. 2022, 32, 10918. doi: 10.1016/j.coelec.2021.100918

  42. [42]

      Bohra, D.; Chaudhry, J. H.; Burdyny, T.; Pidko, E. A.; Smith, W. A. Energy Environ. Sci. 2019, 12, 3380. doi: 10.1039/C9EE02485A

  43. [43]

      Waegele, M. M.; Gunathunge, C. M.; Li, J. Y.; Li, X. J. Chem. Phys. 2019, 151, 160902. doi: 10.1063/1.5124878

  44. [44]

      Ringe, S.; Morales-Guio, C. G.; Chen, L. D.; Fields, M.; Jaramillo, T. F.; Hahn, C.; Chan, K. Nat. Commun. 2020, 11, 33. doi: 10.1038/s41467-019-13777-z

  45. [45]

      许义飞, 杨瀚文, 常晓侠, 徐冰君. 物理化学学报, 2023, 39, 2210025. doi: 10.3866/PKU.WHXB202210025Xu, Y.; Yang, H.; Chang, X.; Xu, B. Acta Phys. -Chim. Sin. 2023, 39, 2210025. doi: 10.3866/PKU.WHXB202210025

  46. [46]

      Banerjee, S.; Gerke, C. S.; Thoi, V. S. Acc. Chem. Res. 2022, 55, 504. doi: 10.1021/acs.accounts.1c00680

  47. [47]

      Tan, X.; Sun, X.; Han, B. Natl. Sci. Rev. 2022, 9, nwab022. doi: 10.1093/nsr/nwab022

  48. [48]

      Berto, T. C.; Zhang, L. H.; Hamers, R. J.; Berry, J. F. ACS Catal. 2015, 5, 703. doi: 10.1021/cs501641z

  49. [49]

      Weng, L. C.; Bell, A. T.; Weber, A. Z. Energy Environ. Sci. 2019, 12, 1950. doi: 10.1039/C9EE00909D

  50. [50]

      Singh, M. R.; Clark, E. L.; Bell, A. T. Phys. Chem. Chem. Phys. 2015, 17, 18924. doi: 10.1039/C5CP03283K

  51. [51]

      Ovalle, V. J.; Waegele, M. M. J. Phys. Chem. C 2021, 125, 18567. doi: 10.1021/acs.jpcc.1c05921

  52. [52]

      Chen, W.; Zhang, M.; Liu, B.; Cai, J.; Chen, Y. Curr. Opin. Electrochem. 2022, 34, 101003. doi: 10.1016/j.coelec.2022.101003

  53. [53]

      Xie, Y.; Ou, P. F.; Wang, X.; Xu, Z. Y.; Li, Y. C.; Wang, Z. Y.; Huang, J. E.; Wicks, J.; McCallum, C.; Wang, N.; et al. Nat. Catal. 2022, 5, 564. doi: 10.1038/s41929-022-00788-1

  54. [54]

      Gupta, N.; Gattrell, M.; MacDougall, B. J. Appl. Electrochem. 2006, 36, 161. doi: 10.1007/s10800-005-9058-y

  55. [55]

      Weng, L. C.; Bell, A. T.; Weber, A. Z. Phys. Chem. Chem. Phys. 2018, 20, 16973. doi: 10.1039/C8CP01319E

  56. [56]

      Bui, J. C.; Kim, C.; Weber, A. Z.; Bell, A. T. ACS Energy Lett. 2021, 6, 1181. doi: 10.1021/acsenergylett.1c00364

  57. [57]

      Welch, A. J.; Fenwick, A. Q.; Bohme, A.; Chen, H. Y.; Sullivan, I.; Li, X. Q.; DuChene, J. S.; Xiang, C. X.; Atwater, H. A. J. Phys. Chem. C 2021, 125, 20896. doi: 10.1021/acs.jpcc.1c06265

  58. [58]

      Monteiro, M. C. O.; Koper, M. T. M. Curr. Opin. Electrochem. 2021, 25, 100649. doi: 10.1016/j.coelec.2020.100649

  59. [59]

      Schatz, M.; Jovanovic, S.; Eichel, R. A.; Granwehr, J. Sci. Rep. 2022, 12, 8274. doi: 10.1038/s41598-022-12264-8

  60. [60]

      Zhang, G.; Cui, Y.; Kucernak, A. ACS Catal. 2022, 12, 6180. doi: 10.1021/acscatal.2c00609

  61. [61]

      Govindarajan, N.; Xu, A. N.; Chan, K. Science 2022, 375, 379. doi: 10.1126/science.abj2421

  62. [62]

      Kim, B.; Ma, S.; Jhong, H. R. M.; Kenis, P. J. A. Electrochim. Acta 2015, 166, 271. doi: 10.1016/j.electacta.2015.03.064

  63. [63]

      Gao, D.; Wang, J.; Wu, H.; Jiang, X.; Miao, S.; Wang, G.; Bao, X. Electrochem. Commun. 2015, 55, 1. doi: 10.1016/j.elecom.2015.03.008

  64. [64]

      Wuttig, A.; Yaguchi, M.; Motobayashi, K.; Osawa, M.; Surendranath, Y. Proc. Natl Acad. Sci. USA 2016, 113, E4585. doi: 10.1073/pnas.1602984113

  65. [65]

      Jiang, X.; Li, H.; Yang, Y.; Gao, D. J. Mater. Sci. 2020, 55, 13916. doi: 10.1007/s10853-020-04983-y

  66. [66]

      Kim, B.; Seong, H.; Song, J. T.; Kwak, K.; Song, H.; Tan, Y. C.; Park, G.; Lee, D.; Oh, J. ACS Energy Lett. 2020, 5, 749. doi: 10.1021/acsenergylett.9b02511

  67. [67]

      Goyal, A.; Marcandalli, G.; Mints, V. A.; Koper, M. T. M. J. Am. Chem. Soc. 2020, 142, 4154. doi: 10.1021/jacs.9b10061

  68. [68]

      Marcandalli, G.; Goyal, A.; Koper, M. T. M. ACS Catal. 2021, 11, 4936. doi: 10.1021/acscatal.1c00272

  69. [69]

      Varela, A. S.; Kroschel, M.; Leonard, N. D.; Ju, W.; Steinberg, J.; Bagger, A.; Rossmeisl, J.; Strasser, P. ACS Energy Lett. 2018, 3, 812. doi: 10.1021/acsenergylett.8b00273

  70. [70]

      Seifitokaldani, A.; Gabardo, C. M.; Burdyny, T.; Dinh, C. T.; Edwards, J. P.; Kibria, M. G.; Bushuyev, O. S.; Kelley, S. O.; Sinton, D.; Sargent, E. H. J. Am. Chem. Soc. 2018, 140, 3833. doi: 10.1021/jacs.7b13542

  71. [71]

      Whipple, D. T.; Finke, E. C.; Kenis, P. J. A. Electrochem. Solid-Sate Lett. 2010, 13, B109. doi: 10.1149/1.3456590

  72. [72]

      Lu, Q.; Rosen, J.; Zhou, Y.; Hutchings, G. S.; Kimmel, Y. C.; Chen, J. G.; Jiao, F. Nat. Commun. 2014, 5, 3242. doi: 10.1038/ncomms4242

  73. [73]

      Hall, A. S.; Yoon, Y.; Wuttig, A.; Surendranath, Y. J. Am. Chem. Soc. 2015, 137, 14834. doi: 10.1021/jacs.5b08259

  74. [74]

      Jiang, X.; Cai, F.; Gao, D.; Dong, J.; Miao, S.; Wang, G.; Bao, X. Electrochem. Commun. 2016, 68, 67. doi: 10.1016/j.elecom.2016.05.003

  75. [75]

      Zhang, B. A.; Ozel, T.; Elias, J. S.; Costentin, C.; Nocera, D. G. ACS Cent. Sci. 2019, 5, 1097. doi: 10.1021/acscentsci.9b00302

  76. [76]

      Raciti, D.; Mao, M.; Park, J. H.; Wang, C. J. Electrochem. Soc. 2018, 165, F799. doi: 10.1149/2.0521810jes

  77. [77]

      Moradzaman, M.; Mul, G. J. Phys. Chem. C 2021, 125, 6546. doi: 10.1021/acs.jpcc.0c10792

  78. [78]

      Nitopi, S.; Bertheussen, E.; Scott, S. B.; Liu, X. Y.; Engstfeld, A. K.; Horch, S.; Seger, B.; Stephens, I. E. L.; Chan, K.; Hahn, C.; et al. Chem. Rev. 2019, 119, 7610. doi: 10.1021/acs.chemrev.8b00705

  79. [79]

      Hori, Y.; Takahashi, R.; Yoshinami, Y.; Murata, A. J. Phys. Chem. B 1997, 101, 7075. doi: 10.1021/jp970284i

  80. [80]

      Schouten, K. J. P.; Gallent, E. P.; Koper, M. T. M. J. Electroanal. Chem. 2014, 716, 53. doi: 10.1016/j.jelechem.2013.08.033

  81. [81]

      Wang, L.; Nitopi, S. A.; Bertheussen, E.; Orazov, M.; Morales-Guio, C. G.; Liu, X. Y.; Higgins, D. C.; Chan, K. R.; Norskov, J. K.; Hahn, C.; et al. ACS Catal. 2018, 8, 7445. doi: 10.1021/acscatal.8b01200

  82. [82]

      Kastlunger, G.; Wang, L.; Govindarajan, N.; Heenen, H. H.; Ringe, S.; Jaramillo, T.; Hahn, C.; Chan, K. R. ACS Catal. 2022, 12, 4344. doi: 10.1021/acscatal.1c05520

  83. [83]

      Liu, X. Y.; Schlexer, P.; Xiao, J. P.; Ji, Y. F.; Wang, L.; Sandberg, R. B.; Tang, M.; Brown, K. S.; Peng, H. J.; Ringe, S.; et al. Nat. Commun. 2019, 10, 2515. doi: 10.1038/s41467-018-07970-9

  84. [84]

      Schreier, M.; Yoon, Y.; Jackson, M. N.; Surendranath, Y. Angew. Chem. Int. Ed. 2018, 57, 10221. doi: 10.1002/anie.201806051

  85. [85]

      Li, J.; Chang, X. X.; Zhang, H. C.; Malkani, A. S.; Cheng, M. J.; Xu, B. J.; Lu, Q. Nat. Commun. 2021, 12, 3264. doi: 10.1038/s41467-021-23582-2

  86. [86]

      Chang, X. X.; Li, J.; Xiong, H. C.; Zhang, H. C.; Xu, Y. F.; Xiao, H.; Lu, Q.; Xu, B. J. Angew. Chem. Int. Ed. 2022, 134, e202111167. doi: 10.1002/ange.202111167

  87. [87]

      Lin, L.; Liu, T.; Xiao, J.; Li, H.; Wei, P.; Gao, D.; Nan, B.; Si, R.; Wang, G.; Bao, X. Angew. Chem. Int. Ed. 2020, 59, 22408. doi: 10.1002/anie.202009191

  88. [88]

      Resasco, J.; Lum, Y.; Clark, E.; Zeledon, J. Z.; Bell, A. T. ChemElectroChem 2018, 5, 1064. doi: 10.1002/celc.201701316

  89. [89]

      Gunathunge, C. M.; Ovalle, V. J.; Li, Y. W.; Janik, M. J.; Waegele, M. M. ACS Catal. 2018, 8, 7507. doi: 10.1021/acscatal.8b01552

  90. [90]

      Chou, T. C.; Chang, C. C.; Yu, H. L.; Yu, W. Y.; Dong, C. L.; Velasco-Velez, J. J.; Chuang, C. H.; Chen, L. C.; Lee, J. F.; Chen, J. M.; et al. J. Am. Chem. Soc. 2020, 142, 2857. doi: 10.1021/jacs.9b11126

  91. [91]

      Chang, X.; Zhao, Y.; Xu, B. ACS Catal. 2020, 10, 13737. doi: 10.1021/acscatal.0c03108

  92. [92]

      Dinh, C. T.; Burdyny, T.; Kibria, M. G.; Seifitokaldani, A.; Gabardo, C. M.; de Arquer, F. P. G.; Kiani, A.; Edwards, J. P.; De Luna, P.; Bushuyev, O. S.; et al. Science 2018, 360, 783. doi: 10.1126/science.aas9100

  93. [93]

      Ma, W.; Xie, S.; Liu, T.; Fan, Q.; Ye, J.; Sun, F.; Jiang, Z.; Zhang, Q.; Cheng, J.; Wang, Y. Nat. Catal. 2020, 3, 478. doi: 10.1038/s41929-020-0450-0

  94. [94]

      Li, H.; Liu, T.; Wei, P.; Lin, L.; Gao, D.; Wang, G.; Bao, X. Angew. Chem. Int. Ed. 2021, 133, 14450. doi: 10.1002/ange.202102657

  95. [95]

      Lu, X.; Zhu, C.; Wu, Z.; Xuan, J.; Francisco, J. S.; Wang, H. J. Am. Chem. Soc. 2020, 142, 15438. doi: 10.1021/jacs.0c06779

  96. [96]

      Henckel, D. A.; Counihan, M. J.; Holmes, H. E.; Chen, X. Y.; Nwabara, U. O.; Verma, S.; Rodriguez-Lopez, J.; Kenis, P. J. A.; Gewirth, A. A. ACS Catal. 2021, 11, 255. doi: 10.1021/acscatal.0c04297

  97. [97]

      Jiang, S.; D'Amario, L.; Dau, H. ChemSusChem 2022, 15, e202102506. doi: 10.1002/cssc.202102506

  98. [98]

      de Ruiter, J.; An, H. Y.; Wu, L. F.; Gijsberg, Z.; Yang, S.; Hartman, T.; Weckhuysen, B. M.; Stam, W. V. J. Am. Chem. Soc. 2022, 144, 15047. doi: 10.1021/jacs.2c03172

  99. [99]

      Luc, W.; Fu, X. B.; Shi, J. J.; Lv, J. J.; Jouny, M.; Ko, B. H.; Xu, Y. B.; Tu, Q.; Hu, X. B.; Wu, J. S.; et al. Nat. Catal. 2019, 2, 423. doi: 10.1038/s41929-019-0269-8

  100. [100]

       Heenen, H. H.; Shin, H.; Kastlunger, G.; Overa, S.; Gauthier, J. A.; Jiao, F.; Chan, K. Energy Environ. Sci. 2022, 15, 3978. doi: 10.1039/D2EE01485H

  101. [101]

       Kim, C.; Weng, L. C.; Bell, A. T. ACS Catal. 2020, 10, 12403. doi: 10.1021/acscatal.0c02915

  102. [102]

       Aran-Ais, R. M.; Scholten, F.; Kunze, S.; Rizo, R.; Roldan Cuenya, B. Nat. Energy 2020, 5, 317. doi: 10.1038/s41560-020-0594-9

  103. [103]

       Jeon, H. S.; Timoshenko, J.; Rettenmaier, C.; Herzog, A.; Yoon, A.; Chee, S. W.; Oener, S.; Hejral, U.; Haase, F. T.; Roldan Cuenya, B. J. Am. Chem. Soc. 2021, 143, 7578. doi: 10.1021/jacs.1c03443

  104. [104]

       Murata, A.; Hori, Y. Bull. Chem. Soc. Jpn. 1991, 64, 123. doi: 10.1246/bcsj.64.123

  105. [105]

       Singh, M. R.; Kwon, Y.; Lum, Y.; Ager, J. W.; Bell, A. T. J. Am. Chem. Soc. 2016, 138, 13006. doi: 10.1021/jacs.6b07612

  106. [106]

       Resasco, J.; Chen, L. D.; Clark, E.; Tsai, C.; Hahn, C.; Jaramillo, T. F.; Chan, K.; Bell, A. T. J. Am. Chem. Soc. 2017, 139, 11277. doi: 10.1021/jacs.7b06765

  107. [107]

       Gao, D.; McCrum, I. T.; Deo, S.; Choi, Y. W.; Scholten, F.; Wan, W.; Chen, J. G.; Janik, M. J.; Roldan Cuenya, B. ACS Catal. 2018, 8, 10012. doi: 10.1021/acscatal.8b02587

  108. [108]

       Malkani, A. S.; Li, J.; Oliveira, N. J.; He, M.; Chang, X.; Xu, B.; Lu, Q. Sci. Adv. 2020, 6, eabd2569. doi: 10.1126/sciadv.abd2569

  109. [109]

       Monteiro, M. C. O.; Dattila, F.; Hagedoorn, B.; Garcia-Muelas, R.; Lopez, N.; Koper, M. T. M. Nat. Catal. 2021, 4, 654. doi: 10.1038/s41929-021-00655-5

  110. [110]

       Rebstock, J. A.; Zhu, Q. S.; Baker, L. R. Chem. Sci. 2022, 13, 7634. doi: 10.1039/D2SC01878K

  111. [111]

       Pan, B.; Wang, Y.; Li, Y. Chem. Catal. 2022, 2, 1267. doi: 10.1016/j.checat.2022.03.012

  112. [112]

       Yu, Y.; Yin, J.; Li, R.; Ma, Y. B.; Fan, Z. Chem. Catal. 2022, 2, 2229. doi: 10.1016/j.checat.2022.07.024

  113. [113]

       Akhade, S. A.; McCrum, I. T.; Janik, M. J. J. Electrochem. Soc. 2016, 163, F477. doi: 10.1149/2.0581606jes

  114. [114]

       Ringe, S.; Clark, E. L.; Resasco, J.; Walton, A.; Seger, B.; Bell, A. T.; Chan, K. Energy Environ. Sci. 2019, 12, 3001. doi: 10.1039/C9EE01341E

  115. [115]

       Wallentine, S.; Bandaranayake, S.; Biswas, S.; Baker, L. R. J. Phys. Chem. Lett. 2020, 11, 8307. doi: 10.1021/acs.jpclett.0c02628

  116. [116]

       Hussain, G.; Perez-Martinez, L.; Le, J. B.; Papasizza, M.; Cabello, G.; Cheng, J.; Cuesta, A. Electrochim. Acta 2019, 327, 135055. doi: 10.1016/j.electacta.2019.135055

  117. [117]

       Chen, L. D.; Urushihara, M.; Chan, K. R.; Norskov, J. K. ACS Catal. 2016, 6, 7133. doi: 10.1021/acscatal.6b02299

  118. [118]

       Ayemoba, O.; Cuesta, A. ACS Appl. Mater. Interfaces 2017, 9, 27377. doi: 10.1021/acsami.7b07351

  119. [119]

       Zhang, F.; Co, A. C. Angew. Chem. Int. Ed. 2020, 59, 1674. doi: 10.1002/anie.201912637

  120. [120]

       Li, J. Y.; Li, X.; Gunathunge, C. M.; Waegele, M. M. Proc. Natl. Acad. Sci. USA 2019, 116, 9220. doi: 10.1073/pnas.1900761116

  121. [121]

       Bagger, A.; Arnarson, L.; Hansen, M. H.; Spohr, E.; Rossmeisl, J. J. Am. Chem. Soc. 2019, 141, 1506. doi: 10.1021/jacs.8b08839

  122. [122]

       Yin, Z.; Peng, H.; Wei, X.; Zhou, H.; Gong, J.; Huai, M.; Xiao, L.; Wang, G.; Lu, J.; Zhuang, L. Energy Environ. Sci. 2019, 12, 2455. doi: 10.1039/C9EE01204D

  123. [123]

       Li, W.; Yin, Z.; Gao, Z.; Wang, G.; Li, Z.; Wei, F.; Wei, X.; Peng, H.; Hu, X.; Xiao, L.; et al. Nat. Energy 2022, 7, 835. doi: 10.1038/s41560-022-01092-9

  124. [124]

       Xu, Y.; Miao, R. K.; Edwards, J. P.; Liu, S. J.; O'Brien, C. P.; Gabardo, C. M.; Fan, M. Y.; Huang, J. E.; Robb, A.; Sargent, E. H.; et al. Joule 2022, 6, 1333. doi: 10.1016/j.joule.2022.04.023

  125. [125]

       Neyrizi, S.; Kiewiet, J.; Hempenius, M. A.; Mul, G. ACS Energy Lett. 2022, 7, 3439. doi: 10.1021/acsenergylett.2c01372

  126. [126]

       Liu, M.; Pang, Y. J.; Zhang, B.; De Luna, P.; Voznyy, O.; Xu, J. X.; Zheng, X. L.; Dinh, C. T.; Fan, F. J.; Cao, C. H.; et al. Nature 2016, 537, 382. doi: 10.1038/nature19060

  127. [127]

       Le, D.; Rahman, T. S. Nat. Catal. 2022, 5, 977. doi: 10.1038/s41929-022-00876-2

  128. [128]

       Dattila, F.; Monteiro, M. C. O.; Koper, M. T. M.; Lopez, N. Nat. Catal. 2022, 5, 979. doi: 10.1038/s41929-022-00877-1

  129. [129]

       Liu, H.; Liu, J.; Yang, B. ACS Catal. 2021, 11, 12336. doi: 10.1021/acscatal.1c01072

  130. [130]

       Shin, S. J.; Choi, H.; Ringe, S.; Won, D. H.; Oh, H. S.; Kim, D. H.; Lee, T.; Nam, D. H.; Kim, H.; Choi, C. H. Nat. Commun. 2022, 13, 5482. doi: 10.1038/s41467-022-33199-8

  131. [131]

       Ren, W.; Xu, A.; Chan, K. R.; Hu, X. Angew. Chem. Int. Ed. 2022, 61, e202214173. doi: 10.1002/anie.202214173

  132. [132]

       Chandrashekar, S.; van Montfort, H. P. I.; Bohra, D.; Filonenko, G.; Geerlings, H.; Burdyny, T.; Smith, W. A. Nanoscale 2022, 14, 14185. doi: 10.1039/D2NR03438G

  133. [133]

       Bhargava, S. S.; Cofell, E. R.; Chumble, P.; Azmoodeh, D.; Someshwar, S.; Kenis, P. J. A. Electrochim. Acta 2021, 394, 139055. doi: 10.1016/j.electacta.2021.139055

  134. [134]

       Huang, J. E.; Li, F. W.; Ozden, A.; Rasouli, A. S.; de Arquer, F. P. G.; Liu, S. J.; Zhang, S. Z.; Luo, M. C.; Wang, X.; Lum, Y. W.; et al. Science 2021, 372, 1074. doi: 10.1126/science.abg6582

  135. [135]

       Monteiro, M. C. O.; Philips, M. F.; Schouten, K. J. P.; Koper, M. T. M. Nat. Commun. 2021, 12, 4943. doi: 10.1038/s41467-021-24936-6

  136. [136]

       Gu, J.; Liu, S.; Ni, W.; Ren, W.; Haussener, S.; Hu, X. Nat. Catal. 2022, 5, 268. doi: 10.1038/s41929-022-00761-y

  137. [137]

       Qiao, Y.; Lai, W.; Huang, K.; Yu, T.; Wang, Q.; Gao, L.; Yang, Z.; Ma, Z.; Sun, T.; Liu, M.; et al. ACS Catal. 2022, 12, 2357. doi: 10.1021/acscatal.1c05135

  138. [138]

       Sheng, X.; Ge, W.; Jiang, H.; Li, C. Adv. Mater. 2022, 34, 2201295. doi: 10.1002/adma.202201295

  139. [139]

       Liu, Z.; Yan, T.; Shi, H.; Pan, H.; Cheng, Y.; Kang, P. ACS Appl. Mater. Interfaces 2022, 14, 7900. doi: 10.1021/acsami.1c21242

  140. [140]

       Jiang, Z.; Zhang, Z.; Li, H.; Tang, Y.; Yuan, Y.; Zao, J.; Zheng, H.; Liang, Y. Adv. Energy Mater. 2023, doi: 10.1002/aenm.202203603

  141. [141]

       Qin, H.; Li, F.; Du, Y.; Yang, L.; Wang, H.; Bai, Y.; Lin, M.; Gu, J. ACS Catal. 2023, 13, 916. doi: 10.1021/acscatal.2c04875

  142. [142]

       Schizodimou, A.; Kyriacou, G. Electrochim. Acta 2012, 78, 171. doi: 10.1016/j.electacta.2012.05.118

  143. [143]

       Monteiro, M. C. O.; Dattila, F.; Lopez, N.; Koper, M. T. M. J. Am. Chem. Soc. 2022, 144, 1589. doi: 10.1021/jacs.1c10171

  144. [144]

       Wang, Y.; Dan, X.; Wang, X.; Yi, Z.; Fu, J.; Feng, Y.; Hu, J.; Wang, D.; Wan, L. J. Am. Chem. Soc. 2022, 144, 20126. doi: 10.1021/jacs.2c09862

  145. [145]

       Ovalle, V. J.; Hsu, Y. S.; Agrawal, N.; Janik, M. J.; Waegele, M. M. Nat. Catal. 2022, 5, 624. doi: 10.1038/s41929-022-00816-0

  146. [146]

       Li, J.; Wu, D. H.; Malkani, A. S.; Chang, X. X.; Cheng, M. J.; Xu, B. J.; Lu, Q. Angew. Chem. Int. Ed. 2020, 59, 4464. doi: 10.1002/anie.201912412

  147. [147]

       Hori, Y.; Murata, A.; Takahashi, R. J. Chem. Soc., Faraday Trans. 1 1989, 85, 2309. doi: 10.1039/F19898502309

  148. [148]

       Sun, M.; Staykov, A.; Yamauchi, M. ACS Catal. 2022, 12, 14856. doi: 10.1021/acscatal.2c03650

  149. [149]

       Sebastian-Pascual, P.; Petersen, A. S.; Bagger, A.; Rossmeisl, J.; Escudero-Escribano, M. ACS Catal. 2021, 11, 1128. doi: 10.1021/acscatal.0c03998

  150. [150]

       Varela, A. S.; Kroschel, M.; Reier, T.; Strasser, P. Catal. Today 2016, 260, 8. doi: 10.1016/j.cattod.2015.06.009

  151. [151]

       Dunwell, M.; Lu, Q.; Heyes, J. M.; Rosen, J.; Chen, J. G. G.; Yan, Y. S.; Jiao, F.; Xu, B. J. J. Am. Chem. Soc. 2017, 139, 3774. doi: 10.1021/jacs.7b10462

  152. [152]

       Zhu, S. Q.; Jiang, B.; Cai, W. B.; Shao, M. H. J. Am. Chem. Soc. 2017, 139, 15664. doi: 10.1021/jacs.7b10462

  153. [153]

       Wuttig, A.; Yoon, Y.; Ryu, J.; Surendranath, Y. J. Am. Chem. Soc. 2017, 139, 17109. doi: 10.1021/jacs.7b08345

  154. [154]

       Li, T.; Yang, C.; Luo, J.; Zheng, G. ACS Catal. 2019, 9, 10440. doi: 10.1021/acscatal.9b02443

  155. [155]

       Shan, W.; Liu, R.; Zhao, H.; Liu, J. J. Phys. Chem. Lett. 2022, 13, 7296. doi: 10.1021/acs.jpclett.2c01372

  156. [156]

       McCrum, I. T.; Akhade, S. A.; Janik, M. J. Electrochim. Acta 2015, 173, 302. doi: 10.1016/j.electacta.2015.05.036

  157. [157]

       Ovalle, V. J.; Waegele, M. M. J. Phys. Chem. C 2020, 124, 14713. doi: 10.1021/acs.jpcc.0c04037

  158. [158]

       Yuan, T.; Wang, T.; Zhang, G.; Deng, W.; Cheng, D.; Gao, H.; Zhao, J.; Yu, J.; Zhang, P.; Gong, J. Chem. Sci. 2022, 13, 8117. doi: 10.1039/D2SC02689A

  159. [159]

       Garg, S.; Li, M. R.; Wu, Y. M.; Idros, M. N.; Wang, H. M.; Yago, A. J.; Ge, L.; Wang, G. X.; Rufford, T. E. ChemSusChem 2021, 14, 2601. doi: 10.1002/cssc.202100848

  160. [160]

       Verma, S.; Lu, X.; Ma, S. C.; Masel, R. I.; Kenis, P. J. A. Phys. Chem. Chem. Phys. 2016, 18, 7075. doi: 10.1039/C5CP05665A

  161. [161]

       Hsieh, Y. C.; Betancourt, L. E.; Senanayake, S. D.; Hu, E. Y.; Zhang, Y.; Xu, W. Q.; Polyansky, D. E. ACS Appl. Energy Mater. 2019, 2, 102. doi: 10.1021/acsaem.8b01692

  162. [162]

       Li, S.; Dong, X.; Zhao, Y.; Mao, J.; Chen, W.; Chen, A.; Song, Y.; Li, G.; Jiang, Z.; Wei, W.; et al. Angew. Chem. Int. Ed. 2022, 61, e202210432. doi: 10.1002/anie.202210432

  163. [163]

       Varela, A. S.; Ju, W.; Reier, T.; Strasser, P. ACS Catal. 2016, 6, 2136. doi: 10.1021/acscatal.5b02550

  164. [164]

       Gao, D.; Scholten, F.; Roldan Cuenya, B. ACS Catal. 2017, 7, 5112. doi: 10.1021/acscatal.7b01416

  165. [165]

       Huang, Y.; Ong, C. W.; Yeo, B. S. ChemSusChem 2018, 11, 3299. doi: 10.1002/cssc.201801078

  166. [166]

       Yang, Y.; Li, K. J.; Ajmal, S.; Feng, Y. Q.; Bacha, A. U. R.; Nabi, L.; Zhang, L. W. Sustain. Energy Fuels 2020, 4, 2284. doi: 10.1039/C9SE01318K

  167. [167]

       Masana, J. J.; Peng, B. W.; Shuai, Z. Y.; Qiu, M.; Yu, Y. J. Mater. Chem. A 2022, 10, 1086. doi: 10.1039/D1TA09125E

  168. [168]

       Gao, D.; Li, H.; Wei, P.; Wang, Y.; Wang, G.; Bao, X. Chin. J. Catal. 2022, 43, 1001. doi: 10.1016/S1872-2067(21)63940-2

  169. [169]

       Gao, D.; Sinev, I.; Scholten, F.; Aran-Ais, R. M.; Divins, N. J.; Kvashnina, K.; Timoshenko, J.; Roldan Cuenya, B. Angew. Chem. Int. Ed. 2019, 58, 17047. doi: 10.1002/anie.201910155

  170. [170]

       Gao, D.; Zegkinoglou, I.; Divins, N. J.; Scholten, F.; Sinev, I.; Grosse, P.; Roldan Cuenya, B. ACS Nano 2017, 11, 4825. doi: 10.1021/acsnano.7b01257

  171. [171]

       Grosse, P.; Gao, D.; Scholten, F.; Sinev, I.; Mistry, H.; Roldan Cuenya, B. Angew. Chem. Int. Ed. 2018, 57, 6192. doi: 10.1002/anie.201802083

  172. [172]

       Lee, S. Y.; Jung, H.; Kim, N. K.; Oh, H. S.; Min, B. K.; Hwang, Y. J. J. Am. Chem. Soc. 2018, 140, 8681. doi: 10.1021/jacs.8b02173

  173. [173]

       Wang, H.; Matios, E.; Wang, C.; Luo, J.; Lu, X.; Hu, X.; Li, W. Nano Lett. 2019, 19, 3925. doi: 10.1021/acs.nanolett.9b01197

  174. [174]

       Aran-Ais, R. M.; Rizo, R.; Grosse, P.; Algara-Siller, G.; Dembel, K.; Plodinec, M.; Lunkenbein, T.; Chee, S. W.; Roldan Cuenya, B. Nat. Commun. 2020, 11, 3489. doi: 10.1038/s41467-020-17220-6

  175. [175]

       Grosse, P.; Yoon, A.; Rettenmaier, C.; Herzog, A.; Chee, S. W.; Roldan Cuenya, B. Nat. Commun. 2021, 12, 6736. doi: 10.1038/s41467-021-26743-5

  176. [176]

       Zhao, Z.; Zhang, J.; Lei, M.; Lum, Y. Nano Res. Energy 2023, doi: 10.26599/NRE.2023.9120044

  177. [177]

       Overa, S.; Feric, T. G.; Park, A. H. A.; Jiao, F. Joule 2021, 5, 8. doi: 10.1016/j.joule.2020.12.004

  178. [178]

       Gao, D.; Cai, F.; Xu, Q.; Wang, G.; Pan, X.; Bao, X. J. Energy Chem. 2014, 23, 694. doi: 10.1016/S2095-4956(14)60201-1

  179. [179]

       Wei, P.; Li, H.; Lin, L.; Gao, D.; Zhang, X.; Gong, H.; Qing, G.; Cai, R.; Wang, G.; Bao, X. Sci. China Chem. 2020, 63, 1711. doi: 10.1007/s11426-020-9825-9

  180. [180]

       Endrodi, B.; Kecsenovity, E.; Samu, A.; Halmagyi, T.; Rojas-Carbonell, S.; Wang, L.; Yan, Y.; Janaky, C. Energy Environ. Sci. 2020, 13, 4098. doi: 10.1039/D0EE02589E

  181. [181]

       Oener, S. Z.; Twight, L. P.; Lindquist, G. A.; Boettcher, S. W. ACS Energy Lett. 2021, 6, 1. doi: 10.1021/acsenergylett.0c02078

  182. [182]

       Ge, L.; Rabiee, H.; Li, M. R.; Subramanian, S.; Zheng, Y.; Lee, J. H.; Burdyny, T.; Wang, H. Chem 2022, 8, 663. doi: 10.1016/j.chempr.2021.12.002

  183. [183]

       Xie, K.; Miao, R. K.; Ozden, A.; Liu, S. J.; Chen, Z.; Dinh, C. T.; Huang, J. E.; Xu, Q. C.; Gabardo, C. M.; Lee, G.; et al. Nat. Commun. 2022, 13, 3609. doi: 10.1038/s41467-022-31295-3

  184. [184]

       Garg, S.; Rodriguez, C. A. G.; Rufford, T. E.; Varcoe, J. R.; Seger, B. Energy Environ. Sci. 2022, 15, 4440. doi: 10.1039/D2EE01818G

  185. [185]

       Sang, J.; Wei, P.; Liu, T.; Lv, H.; Ni, X.; Gao, D.; Zhang, J.; Li, H.; Zang, Y.; Yang, F.; et al. Angew. Chem. Int. Ed. 2022, 61, e202114238. doi: 10.1002/anie.202114238

  186. [186]

       Kowalski, A.; Faber, G.; Cave, E. Curr. Opin. Green Sustain. Chem. 2023, 39, 100702. doi: 10.1016/j.cogsc.2022.100702

  187. [187]

       Park, J.; Ko, Y.-J.; Lim, C.; Kim, H.; Min, B. K.; Lee, K.-Y.; Koh, J. H.; Oh, H.-S.; Lee, W. H. Chem. Eng. J. 2023, 453, 139826. doi: 10.1016/j.cej.2022.139826

  188. [188]

       Jiang, X.; Lin, L.; Rong, Y.; Li, R.; Jiang, Q.; Yang, Y.; Gao, D. Nano Res. 2023, doi: 10.1007/s12274-022-5073-0

  189. [189]

       Wei, P.; Gao, D.; Liu, T.; Li, H.; Sang, J.; Wang, C.; Cai, R.; Wang, G.; Bao, X. Nat. Nanotechnol. 2023, doi: 10.1038/s41565-022-01286-y

  190. [190]

       Ma, M.; Clark, E. L.; Therkildsen, K. T.; Dalsgaard, S.; Chorkendorff, I.; Seger, B. Energy Environ. Sci. 2020, 13, 977. doi: 10.1039/D0EE00047G

  191. [191]

       McCallum, C.; Gabardo, C. M.; O'Brien, C. P.; Edwards, J. P.; Wicks, J.; Xu, Y.; Sargent, E. H.; Sinton, D. Cell Rep. Phys. Sci. 2021, 2, 100522. doi: 10.1016/j.xcrp.2021.100522

  192. [192]

       Rabinowitz, J. A.; Kanan, M. W. Nat. Commun. 2020, 11, 5231. doi: 10.1038/s41467-020-19135-8

  193. [193]

       Jouny, M.; Luc, W.; Jiao, F. Nat. Catal. 2018, 1, 748. doi: 10.1038/s41929-018-0133-2

  194. [194]

       Kim, J. Y.; Zhu, P.; Chen, F. Y.; Wu, Z. Y.; Cullen, D. A.; Wang, H. T. Nat. Catal. 2022, 5, 288. doi: 10.1038/s41929-022-00763-w

  195. [195]

       Zheng, Y. W.; Omasta, T. J.; Peng, X.; Wang, L. Q.; Varcoe, J. R.; Pivovar, B. S.; Mustain, W. E. Energy Environ. Sci. 2019, 12, 2806. doi: 10.1039/C9EE01334B

  196. [196]

       Endrodi, B.; Samu, A.; Kecsenovity, E.; Halmagyi, T.; Sebok, D.; Janaky, C. Nat. Energy 2021, 6, 439. doi: 10.1038/s41560-021-00813-w

  197. [197]

       Romiluyi, O.; Danilovic, N.; Bell, A. T.; Weber, A. Z. Electrochem. Sci. Adv. 2022, e2100186. doi: 10.1002/elsa.202100186

  198. [198]

       Li, M. R.; Idros, M. N.; Wu, Y. M.; Burdyny, T.; Garg, S.; Zhao, X. S.; Wang, G.; Rufford, T. E. J. Mater. Chem. A 2021, 9, 19369. doi: 10.1039/D1TA03636J

  199. [199]

       Wheeler, D. G.; Mowbray, B. A. W.; Reyes, A.; Habibzadeh, F.; He, J. F.; Berlinguette, C. P. Energy Environ. Sci. 2020, 13, 5126. doi: 10.1039/D0EE02219E

  200. [200]

       Choi, W.; Park, S.; Jung, W.; Won, D. H.; Na, J.; Hwang, Y. J. ACS Energy Lett. 2022, 7, 939. doi: 10.1021/acsenergylett.1c02658

  201. [201]

       Gabardo, C. M.; O'Brien, C. P.; Edwards, J. P.; McCallum, C.; Xu, Y.; Dinh, C. T.; Li, J.; Sargent, E. H.; Sinton, D. Joule 2019, 3, 2777. doi: 10.1016/j.joule.2019.07.021

  202. [202]

       Zhang, J.; Luo, W.; Zuttel, A. J. Catal. 2020, 385, 140. doi: 10.1016/j.jcat.2020.03.013

  203. [203]

       Miao, R. K.; Xu, Y.; Ozden, A.; Robb, A.; O'Brien, C. P.; Gabardo, C. M.; Lee, G.; Edwards, J. P.; Huang, J. E.; Fan, M. Y.; et al. Joule 2021, 5, 2742. doi: 10.1016/j.joule.2021.08.013

  204. [204]

       Yang, K.; Li, M.; Subramanian, S.; Blommaert, M. A.; Smith, W. A.; Burdyny, T. ACS Energy Lett. 2021, 6, 4291. doi: 10.1021/acsenergylett.1c02058

  205. [205]

       Siritanaratkul, B.; Forster, M.; Greenwell, F.; Sharma, P. K.; Yu, E. H.; Cowan, A. J. J. Am. Chem. Soc. 2022, 144, 7551. doi: 10.1021/jacs.1c13024

  206. [206]

       Pan, B.; Fan, J.; Zhang, J.; Luo, Y.; Shen, C.; Wang, C.; Wang, Y.; Li, Y. ACS Energy Lett. 2022, 7, 4224. doi: 10.1021/acsenergylett.2c02292

  207. [207]

       Fan, L.; Xia, C.; Zhu, P.; Lu, Y.; Wang, H. Nat. Commun. 2021, 11, 3633. doi: 10.1038/s41467-020-17403-1

  208. [208]

       Xia, C.; Zhu, P.; Jiang, Q.; Pan, Y.; Liang, W.; Stavitski, E.; Alshareef, H. N.; Wang, H. Nat. Energy 2019, 4, 776. doi: 10.1038/s41560-019-0451-x

  209. [209]

       Wang, Z.; Zhou, Y.; Liu, D.; Qi, R.; Xia, C.; Li, M.; You, B.; Xia, B. Angew. Chem. Int. Ed. 2022, 61, e202200552. doi: 10.1002/anie.202200552

  210. [210]

       Ji, Y.; Chen, Z.; Wei, R.; Yang, C.; Wang, Y.; Xu, J.; Zhang, H.; Guan, A.; Chen, J.; Sham, T.-K.; et al. Nat. Catal. 2022, 5, 251. doi: 10.1038/s41929-022-00757-8

  211. [211]

       Sisler, J.; Khan, S.; Ip, A. H.; Schreiber, M. W.; Jaffer, S. A.; Bobicki, E. R.; Dinh, C.-T.; Sargent, E. H. ACS Energy Lett. 2021, 6, 997. doi: 10.1021/acsenergylett.0c02633

  212. [212]

       Ozden, A.; Wang, Y.; Li, F.; Luo, M.; Sisler, J.; Thevenon, A.; Rosas-Hernández, A.; Burdyny, T.; Lum, Y.; Yadegari, H.; et al. Joule 2021, 5, 706. doi: 10.1016/j.joule.2021.01.007

  213. [213]

       Chen, C.; Yu, S.; Yang, Y.; Louisia, S.; Roh, I.; Jin, J.; Chen, S.; Chen, P.-C.; Shan, Y.; Yang, P. Nat. Catal. 2022, 5, 878. doi: 10.1038/s41929-022-00844-w

  214. [214]

       Ren, H.; Kovalev, M.; Weng, Z.; Muhamad, M. Z.; Ma, H.; Sheng, Y.; Sun, L.; Wang, J.; Rihm, S.; Yang, W.; et al. Nat. Catal. 2022, 5, 1169. doi: 10.1038/s41929-022-00891-3

  215. [215]

       Heidary, N.; Ly, K. H.; Kornienko, N. Nano Lett. 2019, 19, 4817. doi: 10.1021/acs.nanolett.9b01582

  216. [216]

       Huang-fu, Z. C.; Song, Q. T.; He, Y. H.; Wang, J. J.; Ye, J. Y.; Zhou, Z. Y.; Sun, S. G.; Wang, Z. H. Phys. Chem. Chem. Phys. 2019, 21, 25047. doi: 10.1039/C9CP04346B

  217. [217]

       Li, H.; Jiang, K.; Zou, S. Z.; Cai, W. B. Chin. J. Catal. 2022, 43, 2772. doi: 10.1016/S1872-2067(22)64095-6

  218. [218]

       Li, H.; Wei, P.; Gao, D.; Wang, G. Curr. Opin. Green Sustain. Chem. 2022, 34, 100589. doi: 10.1016/j.cogsc.2022.100589

  219. [219]

       Liu, S.; D'Amario, l.; Jiang, S.; Dau, H. Curr. Opin. Electrochem. 2022, 35, 101042. doi: 10.1016/j.coelec.2022.101042

  220. [220]

       Wei, Z. Y.; Sautet, P. Angew. Chem. Int. Ed. 2022, 61, e202210060. doi: 10.1002/anie.202210060

  221. [221]

       Dattila, F.; Seemakurthi, R. R.; Zhou, Y. C.; Lopez, N. Chem. Rev. 2022, 122, 11085. doi: 10.1021/acs.chemrev.1c00690

  222. [222]

       Weng, L. C.; Bell, A. T.; Weber, A. Z. Energy Environ. Sci. 2020, 13, 3592. doi: 10.1039/D0EE01604G

  223. [223]

       Lees, E. W.; Bui, J. C.; Song, D. T.; Weber, A. Z.; Berlinguette, C. P. ACS Energy Lett. 2022, 7, 834. doi: 10.1021/acsenergylett.1c02522

  224. [224]

       Li, H.; Jiao, Y., Davey, K.; Qiao, S. Angew. Chem. Int. Ed. 2023, 62, e202216383. doi: 10.1002/anie.202216383

  225. [225]

       Gomes, R. J.; Birch, C.; Cencer, M. M.; Li, C. Y.; Son, S. B.; Bloom, I. D.; Assary, R. S.; Amanchukwu, C. V. J. Phys. Chem. C 2022, 126, 13595. doi: 10.1021/acs.jpcc.2c03321

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