固相聚合合成聚噻吩衍生物及烷基链对固相聚合的影响

引用本文: 裴童, 彭凯, 蔡心怡, 袁良杰, 夏江滨. 固相聚合合成聚噻吩衍生物及烷基链对固相聚合的影响[J]. 物理化学学报, 2017, 33(12): 2550-2558. doi: 10.3866/PKU.WHXB201706071 shu

Citation: PEI Tong, PENG Kai, CAI Xin-Yi, YUAN Liang-Jie, XIA Jiang-Bin. Synthesis of Poly(bis-3,4-ethylenedioxythiophene methine)s with Side-Chain Comprising Electro-Optical Moieties and Alkyl Chain Effect in Solid State Polymerization[J]. Acta Physico-Chimica Sinica, 2017, 33(12): 2550-2558. doi: 10.3866/PKU.WHXB201706071 shu

固相聚合合成聚噻吩衍生物及烷基链对固相聚合的影响

武汉大学化学与分子科学学院, 武汉 430072
基金项目:
国家自然科学基金（21371138），湖北省创新团队科研基金（2014CFA007）及中央高校基本科研业务费专项资金（2042015kf0180）资助项目

摘要: 本文以EDOT-CH（R）-EDOT为基本模型，向侧链引入噻吩、咔唑、芴等几种典型的光电基团，并通过固相/熔融聚合得到相应的聚合物。详细探讨了聚合物的相关性质和几种典型单体的晶体结构，同时发现烷基链的引入降低了分子间的作用力，使得单体的初始聚合温度（T_onset）降低。

关键词:

English

Synthesis of Poly(bis-3,4-ethylenedioxythiophene methine)s with Side-Chain Comprising Electro-Optical Moieties and Alkyl Chain Effect in Solid State Polymerization

College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072, P. R. China
Received Date: 08 May 2017
Revised Date: 06 June 2017
Fund Project:
The project was supported by the National Natural Science Foundation of China (21371138), the Funds for Creative Research Groups of Hubei Province, China (2014CFA007) and the Fundamental Research Funds for the Central Universities, China (2042015kf0180).

Abstract: New poly(bis-3,4-ethylenedioxythiophene methine)s derivatives with typical electro-optical moieties of thiophene, carbazole and fluorene as the side chains are obtained by facile solid state polymerization (SSP) or melt state polymerization (MSP). Detail characterizations of these polymers are carried out and some key monomers' crystals are obtained for structures analysis. It is found that existence of alkyl chains decrease monomers onset temperatures for SSP (T_onset) due to the weakening of the intermolecular interaction in crystals.

Key words:

Poly (bis-3,4-ethylenedioxythiophene methine) s derivatives
/ Solid and melt state polymerization
/ Alkyl chain effect

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沈阳化工大学材料科学与工程学院沈阳 110142

固相聚合合成聚噻吩衍生物及烷基链对固相聚合的影响

English

Synthesis of Poly(bis-3,4-ethylenedioxythiophene methine)s with Side-Chain Comprising Electro-Optical Moieties and Alkyl Chain Effect in Solid State Polymerization

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

固相聚合合成聚噻吩衍生物及烷基链对固相聚合的影响

English

Synthesis of Poly(bis-3,4-ethylenedioxythiophene methine)s with Side-Chain Comprising Electro-Optical Moieties and Alkyl Chain Effect in Solid State Polymerization

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

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