基于三维花状五氧化二铌及活性炭的锂离子混合电容器

引用本文: 贾朝阳, 刘美男, 赵新洛, 王贤树, 潘争辉, 张跃钢. 基于三维花状五氧化二铌及活性炭的锂离子混合电容器[J]. 物理化学学报, 2017, 33(12): 2510-2516. doi: 10.3866/PKU.WHXB201705311 shu

Citation: JIA Zhao-Yang, LIU Mei-Nan, ZHAO Xin-Luo, WANG Xian-Shu, PAN Zheng-Hui, ZHANG Yue-Gang. Lithium Ion Hybrid Supercapacitor Based on Three-Dimensional Flower-Like Nb₂O₅ and Activated Carbon Electrode Materials[J]. Acta Physico-Chimica Sinica, 2017, 33(12): 2510-2516. doi: 10.3866/PKU.WHXB201705311 shu

基于三维花状五氧化二铌及活性炭的锂离子混合电容器

1.
上海大学化学系, 上海 200444;
2.
中国科学院苏州纳米技术与纳米仿生研究所, 江苏苏州 215123;
3.
上海大学物理系, 上海 200444;
4.
清华大学物理系, 北京 100084
基金项目:
国家自然科学基金（51402345）资助项目

摘要: 锂离子混合电容器由于兼备锂离子电池和超级电容器的优势，即较高的能量密度和功率密度，而成为当前能量存储体系的研究热点。本工作合成了具有三维花状微纳结构的正交相五氧化二铌（T-Nb₂O₅），并将其与活性炭（AC）相匹配，设计出一种新型的T-Nb₂O₅/AC锂离子混合电容器。循环伏安和恒电流充放电的测试结果表明该锂离子混合电容器具有较好的电化学性能，如在碳酸酯类的有机电解液中，工作电压可达到3.0 V；在100 mA·g^-1的电流密度下，电容器的比能量和比功率密度可达到53.79 Wh·kg^-1和294 W·kg^-1；在200 mA·g^-1的电流密度下，经过1000次充放电循环后，该电容器的比能量保持率为73%。由此可见，本工作开发的T-Nb₂O₅/AC锂离子混合电容器将在高功率的储能设备中有很好地应用前景。

关键词:

English

Lithium Ion Hybrid Supercapacitor Based on Three-Dimensional Flower-Like Nb₂O₅ and Activated Carbon Electrode Materials

1.
Department of Chemistry, Shanghai University, Shanghai 200444, P. R. China;
2.
Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215123, Jiangsu Province, P. R. China;
3.
Department of Physics, Shanghai University, Shanghai 200444, P. R. China;
4.
Department of Physics, Tsinghua University, Beijing 100084, P. R. China
Received Date: 08 May 2017
Revised Date: 25 May 2017
Fund Project:
The project was supported by the National Natural Science Foundation of China (51402345).

Abstract: A lithium ion hybrid supercapacitor system with battery and supercapacitor characteristics has the potential to meet the increasing demand for an energy storage device with both high energy and power densities. In this work, orthorhombic Nb₂O₅ (T-Nb₂O₅) with three-dimensional (3D) flower-like structures was synthesized by a facile hydrothermal reaction and an annealing process. A lithium ion hybrid supercapacitor was constructed by using T-Nb₂O₅ as an anode and commercial activated carbon (AC) as a cathode. The electrochemical performance of these T-Nb₂O₅/AC hybrid capacitors was measured by cyclic voltammetry and galvanostatic charge/discharge tests. The results showed that the working voltage of the hybrid supercapacitor could reach 3.0 V in the organic carbonate electrolyte system. The as-assembled device showed impressive power density of 294 W·kg^-1 and energy density of 53.79 W·h·kg^-1 at a current density of 100 mA·g^-1 with a voltage range of 0.5-3.5 V. Moreover, it also showed excellent cycling stability with a retention of 73% after 1000 cycles at 200 mA·g^-1. These results demonstrate that this novel lithium ion hybrid supercapacitor based on T-Nb₂O₅ with 3D flower-like structures and AC is a promising candidate for high power density energy storage applications.

Key words:

Lithium ion hybrid supercapacitor
/ Three-dimensional flower-like structure
/ Orthorhombic Nb₂O₅
/ Organic electrolyte
/ Activate carbon

1. [1]
  (1) Winter, M.; Brodd, R. J. Chem. Rev. 2004, 104, 4245. doi: 10.1021/cr020730k
2. [2]
  (2) Zheng, Z. M.; Zhang, P.; Yan, X. B. Chin. Sci. Bull. 2013, 58, 3115. [郑宗敏, 张鹏, 阎兴斌. 科学通报, 2013, 58, 3115.]doi: 10.1360/972013-760
3. [3]
  (3) An, B. K. H.; Kim, W. S.; Park, Y. S.; Moon, J. M.; Bea, D. J.; Lim, S. C.; Lee, Y. S.; Lee, Y. H. Adv. Funct. Mater. 2001, 11, 387. doi: 10.1002/1616-3028(200110)11:53.3.CO;2-7
4. [4]
  (4) Yoshino, A. Angew. Chem. Int. Ed. 2012, 51, 5798. doi: 10.1002/anie.201105006
5. [5]
  (5) Simon, P.; Gogotsi, Y. Nat. Mater. 2008, 7, 845. doi: 10.1038/nmat2297
6. [6]
  (6) Miller J R, Simon P. Science. 2008, 321, 651. doi: 10.1126/science.1158736
7. [7]
  (7) Su, Y. F.; Wu, F.; Bao, L. Y.; Xu, B.; Chen, S. Acta Chim. Sin. 2008, 66, 591 [苏岳峰, 吴锋, 包丽颖, 徐斌, 陈实. 化学学报, 2008, 66, 591. ]
8. [8]
  (8) Jiang, J. M.; Nie, P.; Dong, S. P; Wu, Y. T; Zhang, X. G. Acta Phys. -Chim. Sin. 2017, 33, 780. [将江民, 聂平, 董升阳, 吴宇婷, 张校刚. 物理化学学报, 2017, 33, 780.]. doi: 10.3866/PKU.WHXB201612291
9. [9]
  (9) Naoi, K.; Naoi, W.; Aoyagi, S.; Miyamoto, J. I.; Kamino, T. Acc. Chem. Res. 2012, 46, 1075. doi: 10.1021/ar200308h
10. [10]
  (10) Liu, H. J.; Xia, Y. Y. Prog. Chem. 2011, 23, 595. [刘海晶, 夏永姚. 化学进展, 2011, 23, 595. ]
11. [11]
  (11) Naoi, K.; Ishimoto, S.; Miyamoto, J. I.; Naoi, W. Energy Environ. Sci. 2012, 5, 9363. doi: 10.1039/C2ee21675b
12. [12]
  (12) Cheng, L.; Liu, H. J.; Zhang, J. J.; Xiong, H. M.; Xia, Y.Y. J. Electrochem. Soc. 2006, 153, A1472. doi: 10.1149/1.2204872
13. [13]
  (13) Naoi, K. Fuel. Cells. 2010, 10, 825. doi: 10.1002/fuce.201000041
14. [14]
  (14) Chen, Z.; Augustyn, V.; Wen, J.; Zhang, Y. W.; Shen, M. Q.; Dunn, B.; Lu, Y. F. Adv. Mater. 2011, 23, 791. doi: 10.1002/adma.201003658
15. [15]
  (15) Aravindan, V.; Sundaramurthy, J.; Jain, A.; Kumar, S.; Ling, W.C.; Ramarkrishna, S.; Srinivasan, M. P.; Madhavi, S. ChemSusChem. 2014, 7, 1858. doi: 10.1002/cssc.201400157
16. [16]
  (16) Augustyn, V.; Come, J.; Lowe, M. A.; Kim, J. W.; Taberna, P. L.; Tolbert, S. H.; Abrüna, H. D.; Simon, P.; Dunn, B. Nat. Mater. 2013, 12, 518. doi: 10.1038/NMAT3601
17. [17]
  (17) Viet, A. L.; Reddy, M. V.; Jose, R.; Chowdari, B. V. R.; Ramakrishna, S. J. Phys. Chem. C. 2014, 114, 664. doi: 10.1021/jp9088589
18. [18]
  (18) Liu, M. N.; Yan, C.; Zhang, Y. G. Sci. Rep. 2015, 5, 8326. doi: 10.1038/srep08326
19. [19]
  (19) Come, J.; Augustyn, V.; Kim, J. W.; Rozier, P.; Taberna, P. L.; Gogotsi, P.; Log, J. W; Dunn, B.; Simon, P. J. Electrochem. Soc. 2014, 161, A718. doi: 10.1149/2.040405jes
20. [20]
  (20) Li, G. Z.; Qiu, Y. C.; Hou, Y.; Li, H. F.; Zhou, L. S.; Deng, H.; Zhang, Y.G. J. Mater. Chem. A. 2015, 3, 1103. doi: 10.1039/c4ta04864d
21. [21]
  (21) Kim, S. I.; Lee, J. S.; Ahn, H. J.; Song, H. K.; Jang, J. H. ACS Appl. Mat. Interfaces 2013, 5, 1596. doi: 10.1021/am3021894
22. [22]
  (22) Tang, Y. X.; Rui, X. H.; Zhang, Y. Y.; Lim, T. M.; Dong, Z. L.; Hng, H. H.; Chen, X. D.; Yan, Q. Y.; Chen, Z. J. Mater. Chem. A. 2013, 1, 82. doi: 10.1039/c2ta00351a
23. [23]
  (23) Griffith, K. J.; Forse, A. C.; Griffin, J. M.; Grey, C. P. J. Am. Chem. Soc. 2016, 138, 8888. doi: 10.1021/jacs.6b04345
24. [24]
  (24) Arunkumar, P.; Ashish, A. G.; Babu, B.; Sarang, S.; Suresh, A.; Sharma, C. H.; Thalakulam, M.; Shaijumon, M. M. RSC Adv. 2015, 5, 59997. doi: 10.1039/c5ra07895d.
25. [25]
  (25) Xie, S. B.; Iglesia, E.; Bell, A. T. J. Phys. Chem. B. 2001, 105, 5144. doi: 10.1021/jp004434s
26. [26]
  (26) Wang, X. L.; Li, G.; Chen, Z.; Augustyn, V.; Ma, X.M.; Wang, G.; Dunn, B.; Lu, Y. F. Adv. Energy Mater. 2011, 1, 1089. doi: 10.1002/aenm.201100332
27. [27]
  (27) Tang, C. H.; Tang, Z.; Gong, H. J. Electrochem. Soc. 2012, 159, A651. doi: 10.1149/2.074205jes
28. [28]
  (28) Deng, L. J.; Zhu, G.; Wang, J. F.; Kang, L. P.; Liu, Z. H.; Yang, Z.P.; Wang, Z. L. J. Power Sources .2011, 196, 10782. doi: 10.1016/j.jpowsour.2011.09.005
29. [29]
  (29) Aravindan, V.; Shubha, N.; Ling, W. C.; Madhavi, S. J. Mater. Chem. A. 2013, 1, 6145. doi: 10.1039/C3TA11103B
30. [30]
  (30) Chen, Z.; Augustyn, V.; Wen, J.; Zhang, Y. W.; Shen, M. Q.; Dunn, B.; Lu, Y. F. Adv. Energy Mater. 2011, 23, 791. doi: 10.1002/adma.201003658

扫一扫看文章

计量

PDF下载量: 6
文章访问数: 1047
HTML全文浏览量: 132

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

基于三维花状五氧化二铌及活性炭的锂离子混合电容器

English

Lithium Ion Hybrid Supercapacitor Based on Three-Dimensional Flower-Like Nb₂O₅ and Activated Carbon Electrode Materials

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

基于三维花状五氧化二铌及活性炭的锂离子混合电容器

English

Lithium Ion Hybrid Supercapacitor Based on Three-Dimensional Flower-Like Nb2O5 and Activated Carbon Electrode Materials

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Lithium Ion Hybrid Supercapacitor Based on Three-Dimensional Flower-Like Nb₂O₅ and Activated Carbon Electrode Materials

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs