钙钛矿铁电纳米片诱导的P(VDF-TrFE)取向生长

引用本文: 刘金, 麦江泉, 李诗, 任召辉, 李铭, 武梦娇, 吴勇军, 路新慧, 李翔, 田鹤, 王宗荣, 韩高荣. 钙钛矿铁电纳米片诱导的P(VDF-TrFE)取向生长[J]. 物理化学学报, 2017, 33(6): 1261-1266. doi: 10.3866/PKU.WHXB201702281 shu

Citation: LIU Jin, MAI Jiang-Quan, LI Shi, REN Zhao-Hui, LI Ming, WU Meng-Jiao, WU Yong-Jun, LU Xin-Hui, LI Xiang, TIAN He, WANG Zong-Rong, HAN Gao-Rong. Perovskite Ferroelectric Nanoplates Induced a Highly Oriented Growth of P(VDF-TrFE) Films[J]. Acta Physico-Chimica Sinica, 2017, 33(6): 1261-1266. doi: 10.3866/PKU.WHXB201702281 shu

钙钛矿铁电纳米片诱导的P(VDF-TrFE)取向生长

刘金 ^1, ,
麦江泉 ^2, ,
李诗 ^1, ,
任召辉 ^1, ,
李铭 ^1, ,
武梦娇 ^1, ,
吴勇军 ^1, ,
路新慧 ^2, ,
李翔 ^1, ,
田鹤 ^3, ,
王宗荣 ^1, ,
韩高荣 ^1,

1.
浙江大学, 硅材料国家重点实验室, 唐仲英传感材料及应用研究中心, 材料科学与工程学院, 浙江杭州 310027;
2.
香港中文大学, 物理系, 香港新界 999077;
3.
浙江大学, 电子显微镜中心, 硅材料国家重点实验室, 材料科学与工程学院, 浙江杭州 310027
基金项目:
国家自然科学基金（51232006，51472218），国家973项目（2015CB654901），中央高校基本科研业务费专项资金（2016FZA4005），香港研究资助局科研基金（14303314），香港中文大学基金（4053128）资助项目

摘要: 半结晶的铁电聚合物在柔性电子器件中极具应用前景，控制晶相生长对其性能优化至关重要。本文通过引入少量（0.2%）单晶单畴的PbTiO₃纳米片对P（VDF-TrFE）（简称PVTF）铁电薄膜的生长进行有效调节，获得了高度取向的铁电薄膜且铁电性能得到了大幅提高。PbTiO₃纳米片铁电极化对PVTF极性分子的诱导作用可能是薄膜取向生长与性能提高的原因。

关键词:

English

Perovskite Ferroelectric Nanoplates Induced a Highly Oriented Growth of P(VDF-TrFE) Films

1.
State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Cyrus Tang Center for Sensor Materials and Application, Zhejiang University, Hangzhou 310027, P. R. China;
2.
Department of Physics, Chinese University of Hong Kong, New Territories, Hong Kong 999077, P. R. China;
3.
Center of Electron Microscope, State Key Laboratory of Silicon Material, School of Material Science & Engineering, Zhejiang University, Hangzhou 310027, P. R. China
Received Date: 15 February 2017
Revised Date: 27 February 2017
Available Online: 06 March 2017
Fund Project:
The project was supported by the National Natural Science Foundation of China (No.51232006, 51472218), the National 973 Program of China (2015CB654901), Fundamental Research Funds for the Central Universities (No. 2016FZA4005) and RGC of Hong Kong GRF (No. 14303314) and CUHK Direct Grant (No. 4053128).

Abstract: Ferroelectric polymers are particularly attractive for applications in flexible electronic devices, and controlling its crystalline phase growth is crucial for obtaining optimized ferroelectric properties. Herein we report that a very low introduction (0.2% (w)) of single-domain ferroelectric PbTiO₃ nanoplates can effectively mediate the nucleation and subsequent growth of a crystalline phase within P(VDF-TrFE) (denoted by PVTF), forming highly oriented films and significantly improving the ferroelectric properties due to an alignment of the polarization directions of the polymer and the nanoplates.

Key words:

1. [1]
  (1) Soin, N.; Boyer, D.; Prashanthi, K.; Sharma, S.; Narasimulu, A. A;Luo, J.; Shah, T. H.; Siores, E.; Thundat, T. Chem. Commun. 2015, 51, 8257. doi: 10.1039/c5cc01688f
2. [2]
  (2) Hu, Z.; Tian, M.; Nysten, B.; Jonas, A. M. Nat. Mater. 2009, 8, 62. doi: 10.1038/NMAT2339
3. [3]
  (3) Chen, X. Z.; Li, Q.; Chen, X.; Guo, X.; Ge, H. X.; Liu, Y.; Shen, Q.D. Adv. Funct. Mater. 2013, 23, 3124. doi: 10.1002/adfm.201203042
4. [4]
  (4) Wang, X.; Wang, P.; Wang, J.; Hu, W.; Zhou, X.; Guo, N.; Huang, H.; Sun, S.; Shen, H.; Lin, T.; Tang, M. Adv. Mater. 2015, 27, 6575. doi: 10.1002/adma.201503340
5. [5]
  (5) Lee, J. S.; Shin, K. Y.; Kim, C.; Jang, J. Chem. Commun. 2013, 49, 11047. doi: 10.1039/c3cc46807k
6. [6]
  (6) Ohigashi, H.; Omote, K.; Gomyo, M. C. Appl. Phys. Lett. 1995, 66, 3281. doi: 10.1063/1.113730
7. [7]
  (7) García-Gutiérrez, M. C.; Linares, A.; Hernández, J. J.; Rueda, D. R.; Ezquerra, T. A.; Poza, P.; Davies, R. J. Nano Lett. 2010, 10, 1472. doi: 10.1021/nl100429u
8. [8]
  (8) Wu, Y.; Li, X.; Jonas, A. M.; Hu, Z. Phys. Rev. Lett. 2015, 115, 267601. doi: 10.1103/PhysRevLett.115.267601
9. [9]
  (9) Shin, Y. J.; Kim, R. H.; Jung, H. J.; Kang, S. J.; Park, Y. J.; Bae, I.Park, C. ACS Appl. Mater. Interfaces 2011, 3, 4736. doi: 10.1021/am201202w
10. [10]
  (10) Cauda, V.; Torre, B.; Falqui, A.; Canavese, G.; Stassi, S.; Bein, T.; Pizzi, M. Chem. Mater. 2012, 24, 4215. doi: 10.1021/cm302594s
11. [11]
  (11) Kang, S. J.; Bae, I.; Shin, Y. J.; Park, Y. J.; Huh, J.; Park, S. M.; Kim, H. C.; Park, C. Nano Lett. 2010, 11, 138. doi: 10.1021/nl103094e
12. [12]
  (12) Park, Y. J.; Kang, S. J.; Park, C.; Lotz, B.; Thierry, A.; Kim, K. J.; Huh, J. Macromolecules 2008, 41, 109. doi: 10.1021/ma0718705
13. [13]
  (13) Kim, K. L.; Lee, W.; Hwang, S. K.; Joo, S. H.; Cho, S. M.; Song, G.; Cho, S. H.; Jeong, B.; Hwang, I.; Ahn, J. H.; Yu, Y. J. Nano Lett.2015, 16, 334. doi: 10.1021/acs.nanolett.5b03882
14. [14]
  (14) Bhavanasi, V.; Kusuma, D. Y.; Lee, P. S. Adv. Energy Mater. 2014, 4, 1400723. doi: 10.1002/aenm.201400723
15. [15]
  (15) Sun, X.; Ma, C.; Wang, Y.; Li, H. J. Cryst. Growth 2002, 234, 404. doi: 10.1016/S0022-0248(01)01695-5
16. [16]
  (16) Burbure, N. V.; Salvador, P. A.; Rohrer, G. S. Chem. Mater. 2010, 22, 5823. doi: 10.1021/cm1018025
17. [17]
  (17) Rosa, L. G.; Xiao, J.; Losovyj, Y. B.; Gao, Y.; Yakovkin, I. N.; Zeng, X. C.; Dowben, P. A. J. Am. Chem. Soc. 2005, 127, 17261. doi: 10.1021/ja054159t
18. [18]
  (18) Fong, D. D.; Kolpak, A. M.; Eastman, J. A.; Streiffer, S. K.; Fuoss, P. H.; Stephenson, G. B.; Thompson, C.; Kim, D. M.; Choi, K. J.; Eom, C. B.; Grinberg, I. Phys. Rev. Lett. 2006, 96, 127601. doi: 10.1103/PhysRevLett.96.127601
19. [19]
  (19) Chao, C.; Ren, Z.; Zhu, Y.; Xiao, Z.; Liu, Z.; Xu, G.; Mai, J.; Li, X.; Shen, G.; Han, G. Angew. Chem. Int. Ed. 2012, 51, 9283. doi: 10.1002/anie.201204792
20. [20]
  (20) Jia, C. L.; Nagarajan, V.; He, J. Q.; Houben, L.; Zhao, T.; Ramesh, R.; Urban, K.; Waser, R. Nat. Mater. 2007, 6, 64. doi: 10.1038/nmat1808
21. [21]
  (21) Fridkin, V. M. Ferroelectric Semiconductors, Consultants Bureau:New York, NY, USA 1980.
22. [22]
  (22) Wang, F.; Lack, A.; Xie, Z.; Frübing, P.; Taubert, A.; Gerhard, R.Appl. Phys. Lett. 2012, 100, 062903. doi: 10.1063/1.3683526
23. [23]
  (23) Salimi, A.; Yousefi, A. A. J. Polym. Sci. B: Polym. Phys. 2004, 42, 3487. doi: 10.1002/polb.20223
24. [24]
  (24) Han, X.; Kuang, Q.; Jin, M.; Xie Z.; Zheng, L. J. Am. Chem. Soc.2009, 131, 3152. doi: 10.1021/ja8092373
25. [25]
  (25) Park, Y. J.; Kang, S. J.; Lotz, B.; Brinkmann, M.; Thierry, A.; Kim, K. J.; Park, C. Macromolecules 2008, 41, 8648. doi: 10.1021/ma801495k
26. [26]
  (26) Guo, D.; Setter, N. Macromolecules 2013, 46, 1883. doi: 10.1021/ma302377q
27. [27]
  (27) Urayama, K.; Tsuji, M.; Neher, D. Macromolecules 2000, 33, 8269. doi: 10.1021/ma000855w
28. [28]
  (28) Prabu, A. A.; Lee, J. S.; Kim, K. J.; Lee, H. S. VibrationalSpectroscopy 2006, 41, 1-13. doi: 10.1016/j.vibspec.2005.11.005
29. [29]
  (29) Li, W.; Guo, S.; Tang, Y.; Zhao, X. J. Appl. Polym. Sci. 2004, 91, 2903. doi: 10.1002/app.13503
30. [30]
  (30) Shin, Y. J.; Kang, S. J.; Jung, H. J.; Park, Y. J.; Bae, I.; Choi, D. H.Park, C. ACS Appl. Mater. Interfaces 2011, 3, 582. doi: 10.1021/am1011657
31. [31]
  (31) Zhu, H.; Mitsuishi, M.; Miyashita, T. Macromolecules 2012, 45, 9076. doi: 10.1021/ma301711g
32. [32]
  (32) Guo, D.; Stolichnov, I.; Setter, N. J. Phys. Chem. B 2011, 115, 13455. doi: 10.1021/jp2061442

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沈阳化工大学材料科学与工程学院沈阳 110142

钙钛矿铁电纳米片诱导的P(VDF-TrFE)取向生长

English

Perovskite Ferroelectric Nanoplates Induced a Highly Oriented Growth of P(VDF-TrFE) Films

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中国化学会秘书处

钙钛矿铁电纳米片诱导的P(VDF-TrFE)取向生长

English

Perovskite Ferroelectric Nanoplates Induced a Highly Oriented Growth of P(VDF-TrFE) Films

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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