固溶体光催化材料的研究进展

引用本文: 荆涛, 戴瑛. 固溶体光催化材料的研究进展[J]. 物理化学学报, 2017, 33(2): 295-304. doi: 10.3866/PKU.WHXB201610172 shu

Citation: JING Tao, DAI Ying. Development of Solid Solution Photocatalytic Materials[J]. Acta Physico-Chimica Sinica, 2017, 33(2): 295-304. doi: 10.3866/PKU.WHXB201610172 shu

固溶体光催化材料的研究进展

荆涛 ,
戴瑛

山东大学物理学院, 山东大学晶体材料国家重点实验室, 济南 250100

作者简介: 荆涛,1981年生。2010年毕业于贵州大学理学院,获得硕士学位。2012年至今就读于山东大学物理学院,攻读博士学位。主要从事光催化材料电子结构及其相关性质的研究;戴瑛,1962年生。1998年博士毕业于山东大学。现任山东大学物理学院教授,博士生导师。2015年被评为泰山学者特聘专家。主要从事半导体材料纳米光电性质和光催化性质及其应用的研究。;

基金项目:
国家重点基础研究发展规划（973）（2013CB632401），国家自然科学基金（21333006，11374190）和山东省泰山学者计划资助项目

摘要: 掺杂能够实现传统宽带隙半导体光催化材料的可见光响应，但引入的局域杂质能级易成为载流子的复合中心，降低材料的光催化活性。固溶体方法可以实现带隙和带边位置的精确调控，使材料的光吸收和氧化还原电位达到最佳平衡，是改善其光催化性能的有效方法。本文结合我们课题组近些年来的研究，从固溶体方法对半导体光催化材料带隙和带边位置的调控以及对载流子分离和迁移等性质的影响出发，概述了近年来该领域的最新研究进展，总结了固溶体方法在发展中所面临的主要问题，并对其发展趋势进行展望。

关键词:

English

Development of Solid Solution Photocatalytic Materials

JING Tao ,
DAI Ying

School of Physics, State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, P. R. China
Received Date: 09 August 2016
Revised Date: 17 October 2016
Fund Project:
The project was supported by the National Key Basic Research Program of China (973) (2013CB632401), National Natural Science Foundation of China (21333006, 11374190), and Taishan Scholar Program of Shandong Province, China.

Abstract: Traditional semiconductor photocatalysts with a wide band gap can achieve visible light responses through element doping. However, the localized levels introduced by impurities may act as recombination centers of charge carriers, which may lower the photocatalytic activity of the doped materials. The solid solution method can realize precise regulation of the band gap and band edge positions of materials to obtain an optimal balance between their optical absorption and redox potentials. The solid solution method is therefore an effective approach to improve the photocatalytic performance of semiconductor materials. In the present review, considering our recent research, we briefly discuss the latest progress of the solid solution method to tune the band gap and band edge positions of photocatalytic materials as well as examining its influence on carrier separation and migration properties. Finally, challenges and prospects for further development of this method are presented.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

固溶体光催化材料的研究进展

English

Development of Solid Solution Photocatalytic Materials

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

固溶体光催化材料的研究进展

English

Development of Solid Solution Photocatalytic Materials

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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