基于硝基修饰的锆基金属有机框架材料的分散固相萃取-高效液相色谱-串联质谱法测定食品中的米酵菌酸

方兰云 江艳华 李继革 邱巧丽 金米聪 张丹丹 张玉梅

引用本文: 方兰云, 江艳华, 李继革, 邱巧丽, 金米聪, 张丹丹, 张玉梅. 基于硝基修饰的锆基金属有机框架材料的分散固相萃取-高效液相色谱-串联质谱法测定食品中的米酵菌酸[J]. 分析化学, 2023, 51(6): 1024-1032. doi: 10.19756/j.issn.0253-3820.231040 shu
Citation:  FANG Lan-Yun,  JIANG Yan-Hua,  LI Ji-Ge,  QIU Qiao-Li,  JIN Mi-Cong,  ZHANG Dan-Dan,  ZHANG Yu-Mei. Determination of Bongkrekic Acid in Food by Dispersive Solid Phase Extraction-High Performance Liquid Chromatography-Tandem Mass Spectrometry Using Nitro Modified Zirconium Metal Organic Framework[J]. Chinese Journal of Analytical Chemistry, 2023, 51(6): 1024-1032. doi: 10.19756/j.issn.0253-3820.231040 shu

基于硝基修饰的锆基金属有机框架材料的分散固相萃取-高效液相色谱-串联质谱法测定食品中的米酵菌酸

    通讯作者: 张玉梅,E-mail:23858956@qq.com
  • 基金项目:

    浙江省基础公益研究计划项目(No.LGC22H260002)、宁波市公益重点项目(No.2022S091)和宁夏自然科学基金项目(No.2022AAC03208)资助。

摘要: 建立了基于硝基修饰的锆基金属有机框架材料(NO2-MOF)的分散固相萃取(DSPE)测定食品中米酵菌酸的方法。采用扫描电镜(SEM)、傅里叶变换红外光谱(FT-IR)、热重分析(TGA)、X射线衍射仪(XRD)、X射线光电子能谱(XPS)和氮气吸附实验等对合成的MOF材料进行了表征,结果表明制得了一种比表面积大、结构稳定的MOF材料。此材料与米酵菌酸分子之间存在静电作用、π-π堆积效应和氢键等分子间弱相互作用,基于此实现了对目标物米酵菌酸的选择性吸附。考察了此材料作为DSPE吸附剂吸附米酵菌酸的实验条件,包括溶液pH值、吸附剂分散方式、吸附剂用量、萃取时间以及解吸附溶剂类型等,结合高效液相色谱-串联质谱技术,建立了米酵菌酸的检测方法,方法的定量限为1.6 μg/kg,检出限为0.5 μg/kg。此方法前处理时间短、灵敏度高、对环境友好,木耳和米粉中米酵菌酸的加标回收率为75%~96%,准确度高,为相关食品中痕量米酵菌酸的测定提供了技术参考。

English


    1. [1]

      MOEBIUS N, ROSS C, SCHERLACH K, ROHM B, ROTH M, HERTWECK C. Chem. Biol., 2012, 19(9):1164-1174.MOEBIUS N, ROSS C, SCHERLACH K, ROHM B, ROTH M, HERTWECK C. Chem. Biol., 2012, 19(9):1164-1174.

    2. [2]

      MATSUMOTO K, SUYAMA M, FUJITA S, MORIWAKI T, SATO Y, ASO Y, MUROSHITA S, MATSUO H, MONDA K, OKUDA K, ABE M, FUKUNAGA H, KANO A, SHINDO M. Chem. Eur. J., 2015, 21(32):11590-11602.MATSUMOTO K, SUYAMA M, FUJITA S, MORIWAKI T, SATO Y, ASO Y, MUROSHITA S, MATSUO H, MONDA K, OKUDA K, ABE M, FUKUNAGA H, KANO A, SHINDO M. Chem. Eur. J., 2015, 21(32):11590-11602.

    3. [3]

      ZHOU Peng. Food Res. Develop., 2015, 36(22):123-126. 周鹏. 食品研究与开发, 2015, 36(22):123-126.

    4. [4]

      GB 5009.189-2016. Determination of Bongkrekic Acid in Foods. National Standards of the People's Republic of China. 食品中米酵菌酸的测定. 中华人民共和国食品安全国家标准. GB 5009.189-2016.

    5. [5]

      ZENG Xue-Fang, LIU Jia-Fei, WANG Li-Ya, QI Chun-Yan, YE Jing-Yi, LIANG Xu-Xia, LEI Yi. J. Food Safety Quality, 2019, 10(13):4074-4079. 曾雪芳, 刘嘉飞, 王立亚, 齐春艳, 叶靖怡, 梁旭霞, 雷毅. 食品安全检测学报, 2019, 10(13):4074-4079.

    6. [6]

      WEN Hai-Bin. Modern Food, 2020, (12):166-169. 温海滨. 现代食品, 2020, (12):166-169.

    7. [7]

      WANG Jun-Hu, CHEN Xiao-Peng, QIU Ya-Jing, ZHU Yuan. Chin. J. Pharm. Anal., 2020, 40(6):1025-1031. 王俊虎, 陈骁鹏, 仇雅静, 朱渊, 药物分析杂志, 2020, 40(6):1025-1031.

    8. [8]

      WANG Jun-Hu, QIAO Yong-Sheng, WANG Jian, ZHU Yuan. Chin. J. Chromatogr., 2019, 37(9):963-968. 王俊虎, 乔勇升, 王建, 朱渊, 色谱, 2019, 37(9):963-968.

    9. [9]

      FANG Li, QIU Feng-Mei. Chin. J. Anal. Chem., 2022, 50(4):634-642. 方力, 邱凤梅, 分析化学, 2022, 50(4):634-642.

    10. [10]

      MAYA F, CABELLO C P, FRIZZARIN R M, ESTELA J M, PALOMINO G T, CERDA V. TrAC, Trends Anal. Chem., 2017, 90:142-152.MAYA F, CABELLO C P, FRIZZARIN R M, ESTELA J M, PALOMINO G T, CERDA V. TrAC, Trends Anal. Chem., 2017, 90:142-152.

    11. [11]

      LIAN L, ZHANG X, HAO J, LV J, WANG X, ZHU B, LOU D J. J. Chromatogr. A, 2018, 1579:1-8.LIAN L, ZHANG X, HAO J, LV J, WANG X, ZHU B, LOU D J. J. Chromatogr. A, 2018, 1579:1-8.

    12. [12]

      RAHMAN M M, ABD EL-ATY A M, KIM S W, SHIN S C, SHIN H C, SHIM J H. J. Sep. Sci., 2017, 40(1):203-212.RAHMAN M M, ABD EL-ATY A M, KIM S W, SHIN S C, SHIN H C, SHIM J H. J. Sep. Sci., 2017, 40(1):203-212.

    13. [13]

      CASTILLO-GARCÍA M L, AGUILAR-CABALLOS M P, GOMEZ-HENS A. TrAC, Trends Anal. Chem., 2016, 82:385- 393.CASTILLO-GARCÍA M L, AGUILAR-CABALLOS M P, GOMEZ-HENS A. TrAC, Trends Anal. Chem., 2016, 82:385- 393.

    14. [14]

      KHEZELI T, DANESHFAR A. TrAC, Trends Anal. Chem., 2017, 89:99-118.KHEZELI T, DANESHFAR A. TrAC, Trends Anal. Chem., 2017, 89:99-118.

    15. [15]

      RÍOS A, ZOUGAGH M. TrAC, Trends Anal. Chem., 2016, 84:72-83.RÍOS A, ZOUGAGH M. TrAC, Trends Anal. Chem., 2016, 84:72-83.

    16. [16]

      SOCAS-RODRÍGUEZ B, HERRERA-HERRERA A V, ASENSIO-RAMOS M, HERNÁNDEZ-BORGES J. J. Chromatogr. A, 2014, 1357:110-146.SOCAS-RODRÍGUEZ B, HERRERA-HERRERA A V, ASENSIO-RAMOS M, HERNÁNDEZ-BORGES J. J. Chromatogr. A, 2014, 1357:110-146.

    17. [17]

      DE TOFFOLI A L, MACIEL E V S, FUMES B H, LANÇAS F M. J. Sep. Sci., 2018, 41(1):288-302.DE TOFFOLI A L, MACIEL E V S, FUMES B H, LANÇAS F M. J. Sep. Sci., 2018, 41(1):288-302.

    18. [18]

      RUIZ F J, RIPOLL L, HIDALGO M, CANALS A. Talanta, 2019, 191:162-170.RUIZ F J, RIPOLL L, HIDALGO M, CANALS A. Talanta, 2019, 191:162-170.

    19. [19]

      ZHANG H, XIONG P, LI G. TrAC, Trends Anal. Chem., 2020, 131:116015.ZHANG H, XIONG P, LI G. TrAC, Trends Anal. Chem., 2020, 131:116015.

    20. [20]

      ZENG Jin-Yue, WANG Xiao-Shuang, ZHANG Xian-Zheng, ZHUO Ren-Xi. Acta Chim. Sin., 2019, 77(11):1156-1163. 曾锦跃, 王小双, 张先正, 卓仁禧, 化学学报, 2019, 77(11):1156-1163.

    21. [21]

      DOU Y, GUO L, LI G, LV X, XIA L, YOU J. Microchem. J., 2019, 146:366-373.DOU Y, GUO L, LI G, LV X, XIA L, YOU J. Microchem. J., 2019, 146:366-373.

    22. [22]

      RADA Z H, ABID H R, SUN H, SHANG J, LI J, HE Y, LIU S, WANG S. Prog. Nat. Sci.:Mater. Int., 2018, 28(2):160- 167.RADA Z H, ABID H R, SUN H, SHANG J, LI J, HE Y, LIU S, WANG S. Prog. Nat. Sci.:Mater. Int., 2018, 28(2):160- 167.

    23. [23]

      HIRA S A, NAGAPPAN S, ANNAS D, KUMAR Y A, PARK K H. Electrochem. Commun., 2021, 125:107012.HIRA S A, NAGAPPAN S, ANNAS D, KUMAR Y A, PARK K H. Electrochem. Commun., 2021, 125:107012.

    24. [24]

      GARIBAY S J, COHEN S M. Chem. Commun., 2010, 46(41):7700-7702.GARIBAY S J, COHEN S M. Chem. Commun., 2010, 46(41):7700-7702.

    25. [25]

      LU D, LIU C, QIN M, DENG J, SHI G, ZHOU T. Anal. Chim. Acta, 2020, 1133:88-98.LU D, LIU C, QIN M, DENG J, SHI G, ZHOU T. Anal. Chim. Acta, 2020, 1133:88-98.

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  • 收稿日期:  2023-02-10
  • 修回日期:  2023-04-07
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