二氧化铈基纳米酶的类过氧化物酶催化机理及其在比色传感领域的应用

引用本文: 李佳敏, 罗莉君, 毕晓雅, 刘晓红, 李丽波, 由天艳. 二氧化铈基纳米酶的类过氧化物酶催化机理及其在比色传感领域的应用[J]. 分析化学, 2023, 51(5): 631-641. doi: 10.19756/j.issn.0253-3820.231024 shu

Citation: LI Jia-Min, LUO Li-Jun, BI Xiao-Ya, LIU Xiao-Hong, LI Li-Bo, YOU Tian-Yan. Peroxidase-like Catalytic Mechanism of CeO₂-based Nanozymes and Their Colorimetric Sensing Applications[J]. Chinese Journal of Analytical Chemistry, 2023, 51(5): 631-641. doi: 10.19756/j.issn.0253-3820.231024 shu

二氧化铈基纳米酶的类过氧化物酶催化机理及其在比色传感领域的应用

江苏大学农业工程学院, 现代农业装备与技术教育部重点实验室, 镇江 212013

通讯作者: 罗莉君,E-mail:ljluo@ujs.edu.cn; 由天艳,E-mail:youty@ujs.edu.cn

基金项目:
国家自然科学基金项目(No. 22074055)、江苏省创新创业计划和江苏省高等学校重点学术项目发展项目(No. PAPD-2018-87)和江苏省与教育部共建协同创新中心项目(No. XTCX2008)资助。

摘要: 纳米酶稳定性好，并且可解决传统人工酶活性不足等难题，因此引起了研究者的广泛关注。其中，二氧化铈（CeO₂）作为催化领域最重要的稀土氧化物之一，具有Ce⁴⁺↔Ce³⁺快速氧化还原转化和存在氧化空位的特点，表现出优异的类过氧化物酶活性。将CeO₂与其它材料结合形成CeO₂基纳米酶，更有利于提高其催化性能。本文首先介绍了多种CeO₂基纳米酶，讨论了其类过氧化物酶的催化机理、动力学和比色传感应用，最后总结了CeO₂基纳米酶研究面临的挑战和未来的发展方向。

关键词:

English

Peroxidase-like Catalytic Mechanism of CeO₂-based Nanozymes and Their Colorimetric Sensing Applications

Key Laboratory of Modern Agricultural Equipment and Technology, Ministry of Education, School of Agricultural Engineering, Jiangsu University, Zhenjiang 212013, China

Corresponding author: LUO Li-Jun, ; YOU Tian-Yan,

Received Date: 20 January 2023
Revised Date: 16 March 2023
Fund Project:
Supported by the National Natural Science Foundation of China (No. 22074055), the Innovation/Entrepreneurship Program of Jiangsu Province and Priority Academic Program Development of Jiangsu Higher Education Institutions (No. PAPD-2018-87) and the Jiangsu Province and Education Ministry Cosponsored Synergistic Innovation Center of Modern Agricultural Equipment (No. XTCX2008).

Abstract: Over the past few decades, a multitude of artificial enzymes have been investigated. With the development of nanoscience, nanozymes have attracted widespread attention of researchers because they can solve the issues of insufficient activity of traditional artificial enzymes. As one of the most interesting and important rare earth oxides in catalysis, CeO₂ exhibits excellent peroxidase-like activity due to its fast Ce⁴⁺ ↔ Ce³⁺ redox switch and the existence of related oxygen vacancies. However, the combination of CeO₂ with other materials to form CeO₂-based nanozymes is beneficial to improve the catalytic performance. This review introduced a variety of CeO₂-based nanozymes, discussed their peroxidase-like catalytic mechanisms, kinetics, and colorimetric sensing applications. Finally, the current challenges and potential future directions of CeO₂-based nanozymes were summarized.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

二氧化铈基纳米酶的类过氧化物酶催化机理及其在比色传感领域的应用

通讯作者: 罗莉君,E-mail:ljluo@ujs.edu.cn; 由天艳,E-mail:youty@ujs.edu.cn

English

Peroxidase-like Catalytic Mechanism of CeO₂-based Nanozymes and Their Colorimetric Sensing Applications

Corresponding author: LUO Li-Jun, ; YOU Tian-Yan,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

二氧化铈基纳米酶的类过氧化物酶催化机理及其在比色传感领域的应用

通讯作者: 罗莉君,E-mail:ljluo@ujs.edu.cn; 由天艳,E-mail:youty@ujs.edu.cn

English

Peroxidase-like Catalytic Mechanism of CeO2-based Nanozymes and Their Colorimetric Sensing Applications

Corresponding author: LUO Li-Jun, ; YOU Tian-Yan,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

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CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs