金属有机框架材料在表面增强拉曼光谱中的应用研究进展

引用本文: 易荣楠, 吴燕, 王俊力, 赵芳, 陈锦杨. 金属有机框架材料在表面增强拉曼光谱中的应用研究进展[J]. 分析化学, 2023, 51(2): 147-159. doi: 10.19756/j.issn.0253-3820.221424 shu

Citation: YI Rong-Nan, WU Yan, WANG Jun-Li, ZHAO Fang, CHEN Jin-Yang. Research Progress in Application of Metal-organic Frameworks in Surface-enhanced Raman Spectroscopy[J]. Chinese Journal of Analytical Chemistry, 2023, 51(2): 147-159. doi: 10.19756/j.issn.0253-3820.221424 shu

金属有机框架材料在表面增强拉曼光谱中的应用研究进展

易荣楠 ^1, ,
吴燕 ^{2,3,
,} ,
王俊力 ^3, ,
赵芳 ^3, ,
陈锦杨 ^{2,3,
,}

1.
湖南警察学院刑事科学技术系, 长沙 410138;
2.
南华大学衡阳医学院, 衡阳 421001;
3.
长江师范学院化学化工学院, 重庆 408100

通讯作者: 吴燕,E-mail:wyan2018@163.com; 陈锦杨,E-mail:chenjinyang@hnu.edu.cn

基金项目:
国家自然科学基金项目(No.21804011)、湖南省科技创新计划项目(No.2021RC2085)、湖南警察学院高层次人才启动基金项目(No.2021KYQD05)和湖南省自然科学基金(No.2022JJ40364)项目资助。

摘要: 金属有机框架材料（MOFs）是一种由金属离子和有机配体通过配位化学原理自组装形成的具有周期性网格晶态的多孔结构材料，其独特的结构和性质使其成为具有广阔应用前景的材料。由于MOFs可极大地提高金属表面增强拉曼光谱（SERS）基底的目标富集和信号增强性能，因此，基于MOFs的SERS基底受到了广泛关注。同时，高效的SERS基底使SERS技术可实现高灵敏、高选择性、无损和快速检测。将MOFs应用于SERS技术，极大地促进了SERS技术的发展并拓宽了其应用范围。本文总结了SERS的发展、MOFs基底的类别及其在SERS中的应用，提出了亟待解决的关键问题和挑战，并对其发展前景进行了展望。

关键词:

English

Research Progress in Application of Metal-organic Frameworks in Surface-enhanced Raman Spectroscopy

1.
Criminal Technology Department, Hunan Police Academy, Changsha 410138, China;
2.
Hengyang Medical School, University of South China, Hengyang 421001, China;
3.
College of Chemistry and Chemical Engineering, Yangtze Normal University, Chongqing 408100, China

Corresponding author: WU Yan, ; CHEN Jin-Yang,

Received Date: 17 August 2022
Revised Date: 24 September 2022
Fund Project:
Supported by the National Natural Science Foundation of China (No. 21804011), the Science and Technology Innovation Program of Hunan Province (No. 2021RC2085), the High-level Talent Start-up Fund of Hunan Police College (No. 2021KYQD05), and the Natural Science Foundation of Hunan Province (No. 2022JJ40364).

Abstract: Metal-organic frameworks (MOFs), which are self-assembled by metal ions and organic ligands through coordination chemistry, have periodically lattice crystalline porous structure, and have been widely used as materials due to their unique structures and properties. Because MOFs can greatly improve the target enrichment and signal enhancement performance of metal surface-enhanced Raman spectroscopy (SERS) substrates, MOFsbased SERS substrates have attracted much attention. The efficient SERS substrate enables SERS technology achieves high sensitivity, high selectivity, nondestructive and rapid detection. The advantages of MOFs and SERS greatly promote the development of SERS technology and widen its application range. In this review, the development of SERS, MOFs based substrate categories and their applications in SERS were reviewed, the key issues to be solved urgently and challenges were discussed, and the future development trend was prospected.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

金属有机框架材料在表面增强拉曼光谱中的应用研究进展

通讯作者: 吴燕,E-mail:wyan2018@163.com; 陈锦杨,E-mail:chenjinyang@hnu.edu.cn

English

Research Progress in Application of Metal-organic Frameworks in Surface-enhanced Raman Spectroscopy

Corresponding author: WU Yan, ; CHEN Jin-Yang,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

金属有机框架材料在表面增强拉曼光谱中的应用研究进展

通讯作者: 吴燕,E-mail:wyan2018@163.com; 陈锦杨,E-mail:chenjinyang@hnu.edu.cn

English

Research Progress in Application of Metal-organic Frameworks in Surface-enhanced Raman Spectroscopy

Corresponding author: WU Yan, ; CHEN Jin-Yang,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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