高吸附性能胭脂虫红超支化磁性吸附剂的制备及其在环境水检测中的应用

引用本文: 王悦, 贺一晋, 乔晨曦, 郝旖, 张军杰, 吕东梅, 高瑞霞. 高吸附性能胭脂虫红超支化磁性吸附剂的制备及其在环境水检测中的应用[J]. 分析化学, 2023, 51(2): 259-268. doi: 10.19756/j.issn.0253-3820.221361 shu

Citation: WANG Yue, HE Yi-Jin, QIAO Chen-Xi, HAO Yi, ZHANG Jun-Jie, LYU Dong-Mei, GAO Rui-Xia. Preparation of Cochineal Hyperbranched Magnetic Adsorbent with High Adsorption Performance and Its Application in Environmental Water[J]. Chinese Journal of Analytical Chemistry, 2023, 51(2): 259-268. doi: 10.19756/j.issn.0253-3820.221361 shu

高吸附性能胭脂虫红超支化磁性吸附剂的制备及其在环境水检测中的应用

王悦 ^1, ,
贺一晋 ^1, ,
乔晨曦 ^1, ,
郝旖 ^2, ,
张军杰 ^1, ,
吕东梅 ^1, ,
高瑞霞 ^{1,
,}

1.
西安交通大学化学学院, 西安 710049;
2.
西安交通大学药学院, 西安 710061

通讯作者: 高瑞霞,E-mail:ruixiagao@mail.xjtu.edu.cn

基金项目:
陕西省自然科学基金项目(Nos.2020JM-066,2020JQ-019)、中央高校基础研究基金项目(Nos.xjh012020011,xjh012020001)和西安交通大学创新领军人才项目资助。

摘要: 采用缩水甘油醚为功能单体，胭脂虫红为目标物，裸磁球为载体，通过简单的开环聚合反应首次合成了具有高吸附性能的超支化聚缩水甘油醚磁性吸附剂（Fe₃O₄-HPG）用于高效吸附胭脂虫红。通过透射电镜（TEM）、红外光谱（FT-IR）、X射线衍射（XRD）、热重分析仪（TGA）以及振动样品磁强计（VSM）对材料的物理化学性能进行表征。结果表明，Fe₃O₄-HPG具有均一的粒径、良好的磁性和稳定的晶型结构。同时，对Fe₃O₄-HPG进行动力学吸附、热力学吸附和重复利用性实验考察。所制备的吸附剂具有高的吸附量（106.06 mg/g）、快的吸附速率（60 min）以及较好的重复利用性（8次重复循环使用后吸附效率为95.8%）。以合成的Fe₃O₄-HPG作为固相萃取吸附剂并与高效液相色谱联用，实现了对环境水中胭脂虫红的高效吸附、富集和检测，回收率>94.6%。本研究制备的新型胭脂虫红吸附剂具有较好的实际应用能力。

关键词:

English

Preparation of Cochineal Hyperbranched Magnetic Adsorbent with High Adsorption Performance and Its Application in Environmental Water

1.
School of Chemistry, Xi'an Jiaotong University, Xi'an 710049, China;
2.
School of Pharmacy, Xi'an Jiaotong University, Xi'an 710061, China

Corresponding author: GAO Rui-Xia, ruixiagao@mail.xjtu.edu.cn

Received Date: 19 July 2022
Revised Date: 29 August 2022
Fund Project:
Reusability

Abstract: The cochineal hyperbranched polyglycidyl ether magnetic adsorbents (Fe₃O₄-HPG) were synthesized for adsorption of cochineal with glycidyl ether as functional monomer, cochineal as target, and Fe₃O₄ as carrier by a simple and ingenious synthesis method for the first time. The physical and chemical properties of the materials were characterized by transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and vibrating sample magnetometer (VSM). These results showed that Fe₃O₄-HPG had uniform particle size, good magnetism, and stable crystal structure. At the same time, the kinetic adsorption, thermodynamic adsorption, and reusability of Fe₃O₄-HPG were investigated. The prepared materials had high adsorption capacity (106.06 mg/g), fast adsorption rate (60 min) and good reusability (Adsorption efficiency of 95.8% after reusing for 8 times). Moreover, combined with high performance liquid chromatography, the Fe₃O₄-HPG as adsorbents were successfully used to specifically recognize and detect cochineal in environmental water with recoveries over 94.6%.

Key words:

1. [1]
  LIU Xi-Jian, XIAO Wen-Fa, XIE Yan-Ting, LI Rong-Qiu, JIANG Wen-Bin, LI Jian. Ion Exch. Adsorpt., 2012, 28(1):78-85. 刘锡建, 肖稳发, 谢燕婷, 李荣秋, 蒋文斌, 李健. 离子交换与吸附, 2012, 28(1):78-85.
2. [2]
  LIN Qin. Chin. J. Anal. Lab., 2011, 30(8):33-35. 林钦. 分析试验室, 2011, 30(8):33-35.
3. [3]
  WANG Su-Fang, YU Chao, WANG Zhong-Hua. Pharm. Biotechnol., 2007, 14(2):153-156. 王素芳, 俞超, 王忠华. 药物生物技术, 2007, 14(2):153-156.
4. [4]
  TAKAHASHI E, MARCZYLO T H, WATANABE T, NAGAI S, HAYATSU H, NEGISHI T. Mutat. Res. Fundamental Mol. Mech. Mutagenesis, 2001, 480:139-145.TAKAHASHI E, MARCZYLO T H, WATANABE T, NAGAI S, HAYATSU H, NEGISHI T. Mutat. Res. Fundamental Mol. Mech. Mutagenesis, 2001, 480:139-145.
5. [5]
  LIN Xiao-Shan, HANG Yi-Ping, WU Hui-Qin, HUANG Xiao-Lan, ZHU Zhi-Xin, HUANG Fang, LUO Hui-Tai, DENG Xin. Chin. J. Anal. Lab., 2011, 30(11):85-88. 林晓珊, 杭义萍, 吴惠勤, 黄晓兰, 朱志鑫, 黄芳, 罗辉泰, 邓欣. 分析试验室, 2011, 30(11):85-88.
6. [6]
  YAMAGUCHI H, MASUDA T. J. Agric. Food Chem., 2011, 59(18):9770-9775.YAMAGUCHI H, MASUDA T. J. Agric. Food Chem., 2011, 59(18):9770-9775.
7. [7]
  PETRUCI J F S, PEREIRA E A, CARDOSO A A. J. Agric. Food Chem., 2013, 61(9):2263-2267.PETRUCI J F S, PEREIRA E A, CARDOSO A A. J. Agric. Food Chem., 2013, 61(9):2263-2267.
8. [8]
  SCHLEE C, MARKOVA M, SCHRANK J, LAPLAGNE F, SCHNEIDER R, LACHENMEIER D W. J. Chromatogr. B, 2013, 927:223-226.SCHLEE C, MARKOVA M, SCHRANK J, LAPLAGNE F, SCHNEIDER R, LACHENMEIER D W. J. Chromatogr. B, 2013, 927:223-226.
9. [9]
  CRESCENZI C, BAYOUDH S, CORMACK P A G, KLEIN T, ENSING K. Anal. Chem., 2001, 73(10):2171-2177.CRESCENZI C, BAYOUDH S, CORMACK P A G, KLEIN T, ENSING K. Anal. Chem., 2001, 73(10):2171-2177.
10. [10]
  ZHOU Xin, SHANG Jia, LIU Ming-Ming, LIU Han-Lan, HAO Rong, FENG Xiong-Han, LIU Fan. Acta Chim. Sin., 2010, 68(17):1749-1757. 周欣, 尚佳, 刘名茗, 刘汉兰, 郝蓉, 冯雄汉, 刘凡. 化学学报, 2010, 68(17):1749-1757.
11. [11]
  LIU Yuan-Fa, LIU Yue, HUANG Jian-Hua, WANG Xing-Guo. J. Chin. Cereals Oils Assoc., 2008, 23(4):125-128. 刘元法, 刘悦, 黄健花, 王兴国. 中国粮油学报, 2008, 23(4):125-128.
12. [12]
  SONG Shu-Ling, LI Chong-Jiu, MA Xiao-Dong, RAO Zhu, WEI Qian. Chin. J. Anal. Chem., 2008, 36(11):1526-1530. 宋淑玲, 李重九, 马晓东, 饶竹, 韦倩. 分析化学, 2008, 36(11):1526-1530.
13. [13]
  WANG Y, ZHAO W, GAO R, HUSSAIN S, HAO Y, TIAN J, CHEN S, FENG Y, ZHAO Y, QU Y. J. Hazard. Mater., 2022, 424:127216.WANG Y, ZHAO W, GAO R, HUSSAIN S, HAO Y, TIAN J, CHEN S, FENG Y, ZHAO Y, QU Y. J. Hazard. Mater., 2022, 424:127216.
14. [14]
  LU Pei-Pei, WANG Bing, GUO Cong, YU Peng-Fei. Chin. J. Anal. Chem., 2017, 45(1):89-96. 鲁佩佩, 王兵, 郭聪, 于鹏飞. 分析化学, 2017, 45(1):89-96.
15. [15]
  LI Xing-Hong, JIANG Jing, YANG Li-Na, LI Mei-Ting, HE Yi-Fan, ZHANG Hong-Yi, SHI Zhi-Hong. J. Hebei Univ., 2019, 39(1):41-48. 李兴红, 江静, 杨莉纳, 李美婷, 何怡凡, 张红医, 石志红. 河北大学学报, 2019, 39(1):41-48.
16. [16]
  ZHOU Shu-Wei, FU Hong, XUE Xiao-Kang, KE Qiu-Xuan, CHANG Qiao-Ying, YANG Fang. Chin. J. Anal. Chem., 2022, 50(3):472-481. 周书威, 傅红, 薛晓康, 柯秋璇, 常巧英, 杨方. 分析化学, 2022, 50(3):472-481.
17. [17]
  LIAO Su-Lan, CHEN Shao-Yun, LIU Qi-Lin, CHEN Liang-Bi, LI Xiao-Min. Chin. J. Anal. Chem., 2018, 46(1):100-106. 廖素兰, 陈少云, 刘奇琳, 陈良壁, 李晓敏. 分析化学, 2018, 46(1):100-106.
18. [18]
  ZHANG R Y, LI Q, LI J, ZHOU W Q, YE P L, GAO Y, MA G H, SU Z G. Mater. Sci. Eng., C, 2012, 32(8):2628-2633.ZHANG R Y, LI Q, LI J, ZHOU W Q, YE P L, GAO Y, MA G H, SU Z G. Mater. Sci. Eng., C, 2012, 32(8):2628-2633.
19. [19]
  WANG Yue, GUO Kai-Chen, TIAN Xue-Meng, ZHAO Wen-Chang, Kaidiriye·Setiwalidi, GAO Rui-Xia. Chin. J. Anal. Chem., 2020, 48(10):1375-1382. 王悦, 郭恺辰, 田雪蒙, 赵文昌, 凯迪日耶·色提瓦力迪, 高瑞霞. 分析化学, 2020, 48(10):1375-1382.
20. [20]
  ZHU W, PENG H, LUO M, YU N, XIONG H, WANG R, LI Y. Food Chem., 2018, 261:87-95.ZHU W, PENG H, LUO M, YU N, XIONG H, WANG R, LI Y. Food Chem., 2018, 261:87-95.
21. [21]
  HE Y, CHENG Z, QIN Y, XU B, NING L, ZHOU L. Mater. Lett., 2015, 151:100-103.HE Y, CHENG Z, QIN Y, XU B, NING L, ZHOU L. Mater. Lett., 2015, 151:100-103.
22. [22]
  CUI Y, KANG W W, QIN L, MA J H, LIU X G, YANG Y Z. Chem. Eng. J., 2020, 397:1125480.CUI Y, KANG W W, QIN L, MA J H, LIU X G, YANG Y Z. Chem. Eng. J., 2020, 397:1125480.
23. [23]
  TIAN X, GAO R, WANG Y, HE Y, HUSSAIN S, HEINLEIN J, TIAN J, PFEFFERLE L D, TANG X, TANG Y. Green Chem., 2021, 23(10):3623-3632.TIAN X, GAO R, WANG Y, HE Y, HUSSAIN S, HEINLEIN J, TIAN J, PFEFFERLE L D, TANG X, TANG Y. Green Chem., 2021, 23(10):3623-3632.
24. [24]
  ASIEH A, NAJMEDIN A, SANAEISHOAR H, ELHAM T. Polycyclic Aromat. Compd., 2022, DOI: 10.1080/10406638.2022.2036776.ASIEH A, NAJMEDIN A, SANAEISHOAR H, ELHAM T. Polycyclic Aromat. Compd., 2022, DOI: 10.1080/10406638.2022.2036776.
25. [25]
  ATTALLAH O A, AL-GHOBASHY M A, NEBSEN M, SALEM M Y. ACS Sustainable Chem. Eng., 2016, 5(1):133-145.ATTALLAH O A, AL-GHOBASHY M A, NEBSEN M, SALEM M Y. ACS Sustainable Chem. Eng., 2016, 5(1):133-145.
26. [26]
  EZZATI R. Chem. Eng. J., 2020, 392:123705.EZZATI R. Chem. Eng. J., 2020, 392:123705.
27. [27]
  HAMEEDAT F, HAWAMDEH S, ALNABULSI S, ZAYED A. Molecules, 2022, 27(6):1807.HAMEEDAT F, HAWAMDEH S, ALNABULSI S, ZAYED A. Molecules, 2022, 27(6):1807.

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

高吸附性能胭脂虫红超支化磁性吸附剂的制备及其在环境水检测中的应用

通讯作者: 高瑞霞,E-mail:ruixiagao@mail.xjtu.edu.cn

English

Preparation of Cochineal Hyperbranched Magnetic Adsorbent with High Adsorption Performance and Its Application in Environmental Water

Corresponding author: GAO Rui-Xia, ruixiagao@mail.xjtu.edu.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

高吸附性能胭脂虫红超支化磁性吸附剂的制备及其在环境水检测中的应用

通讯作者: 高瑞霞,E-mail:ruixiagao@mail.xjtu.edu.cn

English

Preparation of Cochineal Hyperbranched Magnetic Adsorbent with High Adsorption Performance and Its Application in Environmental Water

Corresponding author: GAO Rui-Xia, ruixiagao@mail.xjtu.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

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CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs