注册 English

氨基功能化磁性纳米吸附剂固相萃取水中多环芳烃

吴越 ,  王丽 ,  王晓南 ,  阎小青

downloadPDF
引用本文: 吴越, 王丽, 王晓南, 阎小青. 氨基功能化磁性纳米吸附剂固相萃取水中多环芳烃[J]. 分析化学, 2022, 50(7): 1093-1102. doi: 10.19756/j.issn.0253-3820.210848 shu
Citation:  WU Yue,  WANG Li,  WANG Xiao-Nan,  YAN Xiao-Qing. Amino-functionalized Nano Fe3O4 Adsorbent for Magnetic Solid Phase Extraction of Polycyclic Aromatic Hydrocarbons from Environment Water Sample[J]. Chinese Journal of Analytical Chemistry, 2022, 50(7): 1093-1102. doi: 10.19756/j.issn.0253-3820.210848 shu

氨基功能化磁性纳米吸附剂固相萃取水中多环芳烃

  • 山西医科大学公共卫生学院卫生检验教研室, 太原 030001

    • 通讯作者: 阎小青,E-mail:yanxiaoqing83@163.com
  • 基金项目:

    国家自然科学基金项目(No.81502851)和山西医科大学博士启动基金项目(No.055235)资助。

摘要: 采用溶剂热法制备了氨基功能化磁性纳米吸附剂(MNPs-NH2),并将其用于水介质中多环芳烃(PAHs)的磁固相萃取(MSPE),实验结果表明,此吸附剂可选择性地吸附具有4~6个苯环的高分子量PAHs。分子模拟计算以及与其它吸附剂的对比实验结果表明,此吸附剂表面的氨基不仅可促进吸附剂在水中良好分散,而且可通过氢键作用增强对PAHs的吸附。优化了影响萃取效率的各项MSPE参数,建立了水中高分子量PAHs的磁固相萃取-高效液相色谱-荧光检测(MSPE-HPLC-FLD)方法。本方法在0.008~20 ng/mL范围内线性关系良好,检出限为0.002~0.02 ng/mL,定量限为0.004~0.12 ng/mL,高分子量PAHs在两个浓度加标水平(1和10 ng/mL)下的回收率为59.7%~99.0%,相对标准偏差为1.7%~9.0%。本方法可用于环境水样中高分子量PAHs的检测。

English


    1. [1]

      RENGARAJAN T, RAJENDRAN P, NANDAKUMAR N, LOKESHKUMAR B, RAJENDRAN P, NISHIGAKI I. Asian Pac. J. Trop. Biomed., 2015, 5(3):182-189.RENGARAJAN T, RAJENDRAN P, NANDAKUMAR N, LOKESHKUMAR B, RAJENDRAN P, NISHIGAKI I. Asian Pac. J. Trop. Biomed., 2015, 5(3):182-189.

    2. [2]

      BEHERA B K, DAS A, SARKAR D J, WEERATHUNGE P, PARIDA P K, DAS B K, THAVAAMANI P, RAMANATHAN R, BANSAL V. Environ. Pollut., 2018, 241:212-233.BEHERA B K, DAS A, SARKAR D J, WEERATHUNGE P, PARIDA P K, DAS B K, THAVAAMANI P, RAMANATHAN R, BANSAL V. Environ. Pollut., 2018, 241:212-233.

    3. [3]

      JIANG H, HU X R, LI Y, QI J W, SUN X Y, WANG LJ, LI J S. Talanta, 2019, 195:647-654.JIANG H, HU X R, LI Y, QI J W, SUN X Y, WANG LJ, LI J S. Talanta, 2019, 195:647-654.

    4. [4]

      WANG M, CUI S, YAHG X, BI W. Talanta, 2015, 132:922-928.WANG M, CUI S, YAHG X, BI W. Talanta, 2015, 132:922-928.

    5. [5]

      HUANG Y, WEI J, SONG J, CHEN M, LUO Y. Chemosphere, 2013, 92(8):1010-1016.HUANG Y, WEI J, SONG J, CHEN M, LUO Y. Chemosphere, 2013, 92(8):1010-1016.

    6. [6]

      TURAKI U A, ABUGU H O, OKOYE C O B. J. Environ. Health Sci. Eng., 2021, 2(19):1523-1534.TURAKI U A, ABUGU H O, OKOYE C O B. J. Environ. Health Sci. Eng., 2021, 2(19):1523-1534.

    7. [7]

      WESTBERG E, HEDEBRANT U, HAGLUND J, ALSBERG T, ERIKSSON J, SEIDEL A, TÖORNQVIST M. Anal. Bioanal. Chem., 2014, 406(5):1519-1530.WESTBERG E, HEDEBRANT U, HAGLUND J, ALSBERG T, ERIKSSON J, SEIDEL A, TÖORNQVIST M. Anal. Bioanal. Chem., 2014, 406(5):1519-1530.

    8. [8]

      DING J, GAO Q A, LUO D, SHI Z G, FENG Y Q. J. Chromatogr. A, 2010, 1217(47):7351-7358.DING J, GAO Q A, LUO D, SHI Z G, FENG Y Q. J. Chromatogr. A, 2010, 1217(47):7351-7358.

    9. [9]

      LIEW C S M, LI X, LEE H K. Anal. Chem., 2016, 88(18):9095-9102.LIEW C S M, LI X, LEE H K. Anal. Chem., 2016, 88(18):9095-9102.

    10. [10]

      GUO L, TAN S, LI X, Lee H K. J. Chromatogr. A, 2016, 1438:1-9.GUO L, TAN S, LI X, Lee H K. J. Chromatogr. A, 2016, 1438:1-9.

    11. [11]

      SIEMERS A K, MÄNZ J S, PALM W U, WOLFGANG K L R. Chemosphere, 2015, 122:105-114.SIEMERS A K, MÄNZ J S, PALM W U, WOLFGANG K L R. Chemosphere, 2015, 122:105-114.

    12. [12]

      DIAS A N, SIMÃO V, MERIB J, CARASEK E. Anal. Chim. Acta, 2013, 772:33-39.DIAS A N, SIMÃO V, MERIB J, CARASEK E. Anal. Chim. Acta, 2013, 772:33-39.

    13. [13]

      LI Fei, WU Hao-Cheng, LI Yi-Jun, HE Xi-Wen, CHEN LANG-Xing, ZHANG Yu-Kui. Chin. J. Chromatogr., 2020, 38(1):2-13.李菲,吴昊宬,李一峻,何锡文,陈朗星,张玉奎.色谱, 2020, 38(1):2-13.

    14. [14]

      ZHAO X, SHI Y, CAI Y, MOU S. Environ. Sci. Technol., 2008, 42(4):1201-1206.ZHAO X, SHI Y, CAI Y, MOU S. Environ. Sci. Technol., 2008, 42(4):1201-1206.

    15. [15]

      LIU Y, LI H, LIN J. Talanta, 2009, 77(3):1037-1042.LIU Y, LI H, LIN J. Talanta, 2009, 77(3):1037-1042.

    16. [16]

      LONG Y, CHEN Y, YANG F, CHEN C, PAN D, CAI Q, YAO S. Analyst, 2012, 137(11):2716-2722.LONG Y, CHEN Y, YANG F, CHEN C, PAN D, CAI Q, YAO S. Analyst, 2012, 137(11):2716-2722.

    17. [17]

      WANG Y, WANG S, NIU H, MA Y, ZENG T, CAI Y, MENG Z. J. Chromatogr. A, 2013, 1283:20-26.WANG Y, WANG S, NIU H, MA Y, ZENG T, CAI Y, MENG Z. J. Chromatogr. A, 2013, 1283:20-26.

    18. [18]

      DIAS A N, SIMÃO V, MERIB J, CARASEK E. Anal. Chim. Acta, 2013, 772:33-39.DIAS A N, SIMÃO V, MERIB J, CARASEK E. Anal. Chim. Acta, 2013, 772:33-39.

    19. [19]

      BIANCHI F, CHIESI V, CASOLI F, LUCHES P, NASI L, CARERI M, MANGIA A. J. Chromatogr. A, 2012, 1231:8-15.BIANCHI F, CHIESI V, CASOLI F, LUCHES P, NASI L, CARERI M, MANGIA A. J. Chromatogr. A, 2012, 1231:8-15.

    20. [20]

      WANG W, MA R, WU Q, WANG C, WANG Z. J. Chromatogr. A, 2013, 1293:20-27.WANG W, MA R, WU Q, WANG C, WANG Z. J. Chromatogr. A, 2013, 1293:20-27.

    21. [21]

      QIANG H, WANG Z, XIA J, CHEN S, ZHANG X, DING M. Talanta, 2012, 101:388-395.QIANG H, WANG Z, XIA J, CHEN S, ZHANG X, DING M. Talanta, 2012, 101:388-395.

    22. [22]

      ZHAO Q, WEI F, LUO Y B, DING J, XIAO N, FENG Y Q. J. Agric. Food Chem., 2011, 59(24):12794-12800.ZHAO Q, WEI F, LUO Y B, DING J, XIAO N, FENG Y Q. J. Agric. Food Chem., 2011, 59(24):12794-12800.

    23. [23]

      MADLKLZELA L M, NCUBE S, CHIMUKA L. Chromatographia, 2019, 82(8):1171-1189.MADLKLZELA L M, NCUBE S, CHIMUKA L. Chromatographia, 2019, 82(8):1171-1189.

    24. [24]

      CHEN J, CAO S, ZHU M, XI C, ZHANG L, LI X, WANG G, ZHOU Y, CHEN Z. J. Chromatogr. A, 2018, 1547:1-13.CHEN J, CAO S, ZHU M, XI C, ZHANG L, LI X, WANG G, ZHOU Y, CHEN Z. J. Chromatogr. A, 2018, 1547:1-13.

    25. [25]

      NAHAR L K, CORERO R E, NUTT D, HUGHES A L, TURTON S, DURANT C, WILSON S, PATERSON S. J. Anal. Toxicol., 2016, 40(2):117-123.NAHAR L K, CORERO R E, NUTT D, HUGHES A L, TURTON S, DURANT C, WILSON S, PATERSON S. J. Anal. Toxicol., 2016, 40(2):117-123.

    26. [26]

      MUKDASAI S, BUTWONG N, THOMAS C, SRIJARANAI S, SRIJARANAI S. Arab. J. Chem., 2016, 9(3):463-470.MUKDASAI S, BUTWONG N, THOMAS C, SRIJARANAI S, SRIJARANAI S. Arab. J. Chem., 2016, 9(3):463-470.

    27. [27]

      YAN X Q, GUO Y N, ZHENG S J, LIU Q S, ZHANG J L. J. Chromatogr. A, 2021, 1645:462067.YAN X Q, GUO Y N, ZHENG S J, LIU Q S, ZHANG J L. J. Chromatogr. A, 2021, 1645:462067.

    28. [28]

      WANG L, BAO J, WANG L, ZHANG F, LI Y. Chem.-Eur. J., 2006, 12(24):6341-6347.WANG L, BAO J, WANG L, ZHANG F, LI Y. Chem.-Eur. J., 2006, 12(24):6341-6347.

    29. [29]

      XU S N, ZHAO Q, HE H B, YUAN B F, FENG Y Q, YU Q W. Anal. Methods, 2014, 6(17):7046-7053.XU S N, ZHAO Q, HE H B, YUAN B F, FENG Y Q, YU Q W. Anal. Methods, 2014, 6(17):7046-7053.

    30. [30]

      HUO S H, YUAN X P. Analyst, 2012, 137(15):3445-3451.HUO S H, YUAN X P. Analyst, 2012, 137(15):3445-3451.

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  8
  • 文章访问数:  675
  • HTML全文浏览量:  128
文章相关
  • 收稿日期:  2021-11-18
  • 修回日期:  2022-01-15
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net