三维多孔碳/共价有机框架材料自支撑电极用于多巴胺电化学传感分析

引用本文: 王林玉, 洪莎莎, 黎艳艳, 宋永海, 汪莉. 三维多孔碳/共价有机框架材料自支撑电极用于多巴胺电化学传感分析[J]. 分析化学, 2021, 49(6): 1053-1060. doi: 10.19756/j.issn.0253-3820.210418 shu

Citation: WANG Lin-Yu, HONG Sha-Sha, LI Yan-Yan, SONG Yong-Hai, WANG Li. Dopamine Electrochemical Sensor Based on Three-Dimensional Macroporous Carbon/Covalent Organic Framework Integrated Electrode[J]. Chinese Journal of Analytical Chemistry, 2021, 49(6): 1053-1060. doi: 10.19756/j.issn.0253-3820.210418 shu

三维多孔碳/共价有机框架材料自支撑电极用于多巴胺电化学传感分析

江西师范大学化学化工学院, 南昌 330022

通讯作者: 汪莉,E-mail:lwang@jxnu.edu.cn

基金项目:
国家自然科学基金项目（Nos.21765009，21964010，21465014，21665012）资助。

摘要: 通过简单的水热法使二苯甲酸二肼和1，3，5-三（对甲酰基苯基）苯发生氨醛缩合反应，合成了一种新的共价有机框架材料（COF_TFPB-TDF）。将COF_TFPB-TDF生长到三维多孔碳（3D-KSC）上，得到3D-KSC/COF_TFPB-TDF自支撑电极，采用扫描电子显微镜进行结构表征，结果表明，3D-KSC/COF_TFPB-TDF具有片层结构，同时含有很多孔洞，可以固载其它的材料。采用循环伏安法研究了3D-KSC/COF_TFPB-TDF自支撑电极对多巴胺的检测性能。结果表明，此传感器对多巴胺表现出良好的传感性能，具有低的检出限（0.045 μmol/L）、宽的线性范围（0.13 μmol/L~0.06 mmol/L）和高灵敏度（369 μA/（mmol/L）/cm²），这主要归因于COF_TFPB-TDF较大的比表面积和较多的孔洞结构。因此，此材料具有良好的应用前景。

关键词:

English

Dopamine Electrochemical Sensor Based on Three-Dimensional Macroporous Carbon/Covalent Organic Framework Integrated Electrode

Key Laboratory of Functional Small Organic Molecule, Ministry of Education, College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China

Corresponding author: WANG Li, lwang@jxnu.edu.cn

Received Date: 07 April 2021
Revised Date: 21 April 2021
Fund Project:
Supported by the National Natural Science Foundation of China (Nos.21765009, 21964010, 21465014, 21665012).

Abstract: A novel covalent organic framework (COF_TFPB-TDF) was firstly synthesized by ammonaldehyde condensation reaction between 1,3,5-tris(p-formylphenyl) benzene and 1,4-benzenedicarbohydrazide. Then, three-dimensional macroporous carbon derived from kenaf stem (3D-KSC)/COF_TFPB-TDF integrated electrode was obtained by growing COF_TFPB-TDF on 3D-KSC. Scanning electron microscopy was used to characterize the structure of 3D-KSC/COF_TFPB-TDF. The results showed that 3D-KSC/COF_TF_PB-TDF had lamellar structure and there were many holes to support other materials. The performance of 3D-KSC/COF_TFPB-TDF electrode for detection of dopamine was studied by cyclic voltammetry. The results showed that the sensor had good performance for detecting dopamine, with low detection limit (0.045 μmol/L), wide linear range (0.134 μmol/L-0.06 mmol/L) and high sensitivity (369 μA/(mmol/L)/cm²). These excellent properties were mainly attributed to the larger specific surface area and pore structure of 3D-KSC/COF_TFPB-TDF, which also made the material had a good application prospect in other aspects.

Key words:

1. [1]
  ROY A W, MYKEL A R. Annu. Rev. Psychol., 2020, 71: 79-106.
2. [2]
  IARKOV A, BARRETO G E, GRIZZELL J A, ECHEVERRIA V. Front. Aging Neurosci., 2020, 12: 4.
3. [3]
  CONIO B, MARTINO M, MAGIONCALDA P, ESCELSIOR A, INGLESE M, AMORE M, NORTHOFF G. Mol. Psychiatry, 2020, 25: 82-93.
4. [4]
  GONZAGA M F M, CASTRO L F, NAVES L A, MENDONCA J L, LIMA B O, KESSLER I, CASULARI L A. Front. Endocrinol., 2018, 9: 625.
5. [5]
  EDDIN F B K, FEN Y W. Sensors, 2020, 20(4): 1039.
6. [6]
  VENTON B J, CAO Q. Analyst, 2020, 145: 1158-1168.
7. [7]
  OZCAN A, ILKBAS S, ATILIR O A A. Talanta, 2017, 165: 489-495.
8. [8]
  FAYEMI O E, ADEKUNLE A S, SWAMY B E K, EBENSO E E. J. Electroanal. Chem., 2018, 818: 236-249.
9. [9]
  ZOU J, WU S L, LIU Y, SUN Y J, CAO Y, HSU J P, WEE A T S, JIANG J Z. Carbon, 2018, 130: 652-663.
10. [10]
  FANG J, XIE Z G, WALLACEG, WANG X G. Appl. Surf. Sci., 2017, 412: 131-137.
11. [11]
  SHUKLA S K, LAVON A, SHMULEVICH O, BEN-YOAV H. Talanta, 2018, 181: 57-64.
12. [12]
  SULTAN S C, SEZER E, TEPELI Y, ANIK U. RSC Adv., 2014, 4: 31489-31492.
13. [13]
  YU L, CUI X, LI H J, LU J, KANG Q, SHEN D Z. Analyst, 2019, 144: 4073-4080.
14. [14]
  CHAUHAN N, CHAWLA S, PUNDIR C S, JAIN U. Biosens. Bioelectron., 2017, 89: 377-383.
15. [15]
  PENG Z W, JIANG Z W, HUANG X, LI Y F. RSC Adv., 2016, 6: 13742-13748.
16. [16]
  CAO Y, WANG L N, SHEN C, WANG C Y, HU X Y, WANG G X. Sens. Actuators, B, 2019, 283: 487-494.
17. [17]
  QIU Z W, YANG T, GAO R, JIE G F, HOU W G. J. Electroanal. Chem., 2019, 835: 123-129.
18. [18]
  LI Y, XIE M W, ZHANG X P, LIU Q, LIN D M, XU C G, XIE F Y, SUN X P. Sens. Actuators, B, 2019, 278: 126-132.
19. [19]
  LI Y, C C, YANG Y P, DUN X J, GAO J M, JIN X J. J. Alloys Compd., 2019, 798: 764-772.
20. [20]
  AHIRWAR D, BANO M, KHAN I, GOUND S S, SHEIKH M U D, MONDAL R, KHAN F. J. Solid State Chem., 2019, 273: 233-242.
21. [21]
  ZHANG L, LIANG H B, MA X N, YE C, ZHAO Y. Microchem. J., 2019, 146: 479-485.
22. [22]
  ARAVIND A, MATHEW B. SN Appl. Sci., 2019, 1: 23.
23. [23]
  MARTINS T S, BOTT-NETO J L, RAYMUNDO-PEREIRA P A, TICIANELLI E A, MACHADO S A S. Sens. Actuators, B, 2018, 276: 378-387.
24. [24]
  XU H Y, XIA C K, WANG S Y, HAN F, AKBARI M K, HAI Z Y, ZHUIYKOV S. Sens. Actuators, B, 2018, 267: 93-103.
25. [25]
  WANG L Y, XIE Y, YANG Y X, LIANG H H, WANG L, SONG Y H. ACS Appl. Nano Mater., 2020, 3(2): 1412-1419.
26. [26]
  WU Y Y, DENG P H, TIAN Y L, MAGESA F, LIU J, LI G L, HE Q G. J. Food Compos. Anal., 2019, 84: 103280.
27. [27]
  RAHMAN M M, MARWANI H M, ALGETHAMI F K, ASIRI A M. New J. Chem., 2017, 41: 6262-6271.
28. [28]
  VAROL T O, PERK B, AVCI O, AKPOLAT O, HAKLI O, XUE C M, LI Q, ANIK U. Measurement, 2019, 147: 106867.
29. [29]
  SUN Y F, HE J B, WATERHOUSE G I N, XU L H, ZHANG H Y, QIAO X G, XU Z X. Sens. Actuators, B, 2019, 300: 126993.
30. [30]
  ZHANG T, GAO C W, HUANG W, CHEN Y L, WANG Y, WANG J M. Talanta, 2018, 188: 578-583.
31. [31]
  WANG L, ZHANG Q Y, CHEN S L, XU F G, CHEN S H, JIA J B, TAN H L, HOU H Q, SONG Y H. Anal. Chem., 2014, 86: 1414-1421.
32. [32]
  CAI L L, HOU B J, SHANG Y Y, XU L, ZHOU B, JIANG X N, JIANG X Q. Chem. Phys. Lett., 2019, 736: 136797.
33. [33]
  SUN X J, ZHANG L, ZHANG X H, LIU X X, JIAN J, KONG D C, ZENG D C, YUAN H M, FENG S H. Biosens. Bioelectron., 2020, 153: 112045.
34. [34]
  HOU Y B, SHENG K, LU Y, MA C, LIU W, MEN X J, XU L, YIN S Y, DONG B, BAI X, SONG H W. Microchim. Acta, 2018, 185: 397.
35. [35]
  LI J, XIA J F, ZHANG F F, WANG Z H, LIU Q Y. J. Chin. Chem. Soc., 2018, 65(6): 743-749.
36. [36]
  BAS S Z, CUMMINS C, SELKIRK A, BORAH D, OZMEN M, MORRIS M A. ACS Appl. Nano Mater., 2019, 2(11): 7311-7318.
37. [37]
  BAHRAMI E, AMINI R, VARDAK S. J. Alloys Compd., 2021, 855: 157292.
38. [38]
  KRISHNAMOORTHY K, SUDHA V, KUMAR S M S, THANGAMUTHU R. J. Alloys Compd., 2018, 748: 338-347.
39. [39]
  CAO M C, ZHENG L T, GU Y F, WANG Y T, ZHANG H, XU X H. Microchem. J., 2020, 159: 105465.
40. [40]
  PANOV M S, GRISHANKINA A E, STUPIN D D, LIHACHEV A I, MIRONOV V N, STRASHKOV D M, KHAIRULLINA E M, TUMKIN I I, RYAZANTSEV M N. Materials, 2020, 13(23): 5385.

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沈阳化工大学材料科学与工程学院沈阳 110142

三维多孔碳/共价有机框架材料自支撑电极用于多巴胺电化学传感分析

通讯作者: 汪莉,E-mail:lwang@jxnu.edu.cn

English

Dopamine Electrochemical Sensor Based on Three-Dimensional Macroporous Carbon/Covalent Organic Framework Integrated Electrode

Corresponding author: WANG Li, lwang@jxnu.edu.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

三维多孔碳/共价有机框架材料自支撑电极用于多巴胺电化学传感分析

通讯作者: 汪莉,E-mail:lwang@jxnu.edu.cn

English

Dopamine Electrochemical Sensor Based on Three-Dimensional Macroporous Carbon/Covalent Organic Framework Integrated Electrode

Corresponding author: WANG Li, lwang@jxnu.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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