罗丹明B-锆基金属有机框架复合材料高选择性荧光检测铁离子

引用本文: 陈阳, 赵杰, 张嘉惠, 李静, 杜佩瑶, 卢小泉. 罗丹明B-锆基金属有机框架复合材料高选择性荧光检测铁离子[J]. 分析化学, 2021, 49(4): 642-651. doi: 10.19756/j.issn.0253-3820.201735 shu

Citation: CHEN Yang, ZHAO Jie, ZHANG Jia-Hui, LI Jing, DU Pei-Yao, LU Xiao-Quan. Integration of Rhodamine B into Zirconium-based Metal-organic Framework for Selective Detection of Ferric Ion[J]. Chinese Journal of Analytical Chemistry, 2021, 49(4): 642-651. doi: 10.19756/j.issn.0253-3820.201735 shu

罗丹明B-锆基金属有机框架复合材料高选择性荧光检测铁离子

陈阳 ^1, ,
赵杰 ^1, ,
张嘉惠 ^1, ,
李静 ^1, ,
杜佩瑶 ^{1,
,} ,
卢小泉 ^{2,
,}

1.
天津大学理学院化学系, 天津市分子光电科学重点实验室, 天津 300072;
2.
西北师范大学化学化工学院, 甘肃省生物电化学与环境分析重点实验室, 兰州 730070

通讯作者: 杜佩瑶,E-mail:peiyao.du@tju.edu.cn; 卢小泉,E-mail:luxq@nwnu.edu.cn

基金项目:
国家自然科学基金项目（Nos.21705117，22001193）、甘肃省高等教育研究计划项目（No.2017-D-01）和中央引导地方科技发展专项资金（2020）资助。

摘要: 罗丹明B（RhB）染料用于荧光检测时通常不具有选择性，限制了其在分析传感中的应用。本研究合成了一种将RhB包封在锆基金属有机框架（PCN-777）孔道中的复合材料（RhB@PCN-777），用于水体中Fe³⁺的特异性检测。与单独的RhB相比，RhB@PCN-777的光稳定性有所提高，并且在检测过程中减少了其它离子的干扰。RhB@PCN-777复合材料在水相中发射黄色荧光。在pH=6.0的条件下，RhB@PCN-777可以高灵敏度、高选择性检测Fe³⁺，检出限为0.16 μmol/L。实际水样中Fe³⁺的加标回收率为94.2%~103.9%，表明本方法在实际样品检测中具有良好的实用性。

关键词:

English

Integration of Rhodamine B into Zirconium-based Metal-organic Framework for Selective Detection of Ferric Ion

CHEN Yang ^1, ,
ZHAO Jie ^1, ,
ZHANG Jia-Hui ^1, ,
LI Jing ^1, ,
DU Pei-Yao ^{1,
,} ,
LU Xiao-Quan ^{2,
,}

1.
Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, School of Science, Tianjin University, Tianjin 300072, China;
2.
Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou 730070, China

Corresponding author: DU Pei-Yao, ; LU Xiao-Quan,

Received Date: 07 December 2020
Revised Date: 20 January 2021
Fund Project:
Supported by the National Natural Science Foundation of China (Nos.21575115, 22001193), the Program of Gansu Provincial Higher Education Research Project (No.2017-D-01) and the Special Fund Project for the Central Government to Guide Local Science and Technology Development (2020).

Abstract: Rhodamine B (RhB) dyes usually have no selectivity in fluorescence detection of Fe³⁺, which limits their application in analytical detection. In this study, a composite material (RhB@PCN-777) with RhB encapsulated in a zirconium-based organic framework (PCN-777) channel was synthesized and applied to the specific detection of Fe³⁺ in water. Compared with free RhB, RhB@PCN-777 exhibited drastically improved fluorescence stability and high selectivity for the determination of Fe³⁺. RhB@PCN-777 composite featured a yellow emission at 586 nm when dispersed in aqueous solution, which could detect Fe³⁺ in water with high sensitivity and selectivity, with a detection limit as low as 0.16 μmol/L. Moreover, RhB@PCN-777 was successfully used to detect Fe³⁺ in real water samples with recoveries ranging from 94.2% to 103.9%, indicating that the fluorescent probe had high reliability in actual environmental aqueous samples.

Key words:

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

罗丹明B-锆基金属有机框架复合材料高选择性荧光检测铁离子

通讯作者: 杜佩瑶,E-mail:peiyao.du@tju.edu.cn; 卢小泉,E-mail:luxq@nwnu.edu.cn

English

Integration of Rhodamine B into Zirconium-based Metal-organic Framework for Selective Detection of Ferric Ion

Corresponding author: DU Pei-Yao, ; LU Xiao-Quan,

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

罗丹明B-锆基金属有机框架复合材料高选择性荧光检测铁离子

通讯作者: 杜佩瑶,E-mail:peiyao.du@tju.edu.cn; 卢小泉,E-mail:luxq@nwnu.edu.cn

English

Integration of Rhodamine B into Zirconium-based Metal-organic Framework for Selective Detection of Ferric Ion

Corresponding author: DU Pei-Yao, ; LU Xiao-Quan,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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