氧化锌单层空心球阵列薄膜的制备及其紫外光驱动下对二氧化氮的超快气敏响应

引用本文: 王弘, 苏星松, 周飞, 段国韬. 氧化锌单层空心球阵列薄膜的制备及其紫外光驱动下对二氧化氮的超快气敏响应[J]. 分析化学, 2022, 50(7): 1112-1121. doi: 10.19756/j.issn.0253-3820.201607 shu

Citation: WANG Hong, SU Xing-Song, ZHOU Fei, DUAN Guo-Tao. Preparation of Zinc Oxide Monolayer Porous Hollow Sphere Array and Its Ultra-Fast Response to NO₂ at Room Temperature under Ultraviolet Irradiation[J]. Chinese Journal of Analytical Chemistry, 2022, 50(7): 1112-1121. doi: 10.19756/j.issn.0253-3820.201607 shu

氧化锌单层空心球阵列薄膜的制备及其紫外光驱动下对二氧化氮的超快气敏响应

王弘 ^1,2,3, ,
苏星松 ^2, ,
周飞 ^2, ,
段国韬 ^{1,
,}

1.
华中科技大学光学与电子信息学院, 武汉光电国家研究中心, 武汉 430074;
2.
中国科学院固体物理研究所, 中国科学院材料物理重点实验室, 合肥 230031;
3.
中国科学技术大学, 合肥 230026

通讯作者: 段国韬,E-mail:duangt@hust.edu.cn

基金项目:
国家重点研发计划项目(No.2020YFB2008701)和国家自然科学基金项目(No.11674320)资助。

摘要: 基于单层聚苯乙烯胶体球模板辅助水热法,在气体传感器平板电极上原位合成氧化锌(ZnO)阵列薄膜。扫描电子显微镜(SEM)和高分辨透射电子显微镜(HRTEM)表征结果表明,此薄膜由有序排列的单层多孔空心球组成,孔隙大小约4 nm。对所制备的薄膜气体传感器的气敏性能进行了研究,结果表明,在较低的光辐射功率(1.7 mW/cm²)下,ZnO单层空心球阵列薄膜传感器对二氧化氮(NO₂)呈现优异的气敏性能,检出限可达0.098 mg/m³,对2.45 mg/m³的NO₂气体的响应值可达5.7,并显示出超快的响应/恢复速率(3 s/5 s)。利用时域有限差分法分析了单层空心球阵列薄膜在紫外光辐照下的局域场强度,探讨了其秒量级响应/恢复的机制,发现这可能源于单层空心球阵列薄膜球壳层较为均匀的局域场强分布。

关键词:

English

Preparation of Zinc Oxide Monolayer Porous Hollow Sphere Array and Its Ultra-Fast Response to NO₂ at Room Temperature under Ultraviolet Irradiation

1.
Wuhan National Laboratory for Optoelectronics, School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, China;
2.
CAS Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, China;
3.
University of Science and Technology of China, Hefei 230026, China

Corresponding author: DUAN Guo-Tao, duangt@hust.edu.cn

Received Date: 16 October 2020
Revised Date: 25 January 2021
Fund Project:
Supported by the National Key R&D Program of China (No.2020YFB2008701) and the National Natural Science Foundation of China (No.11674320).

Abstract: By using monolayer polystyrene colloidal spheres as the template, ZnO array-film was in-situ synthesized on the plate electrodes for gas sensors by template-assisted hydrothermal method. Scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HRTEM) characterization results showed that the film was composed of ordered monolayer porous hollow spheres with pore size of about 4 nm. The gas-sensing performances of the prepared thin-film gas sensor were investigated. Under UV irradiation with a low optical radiation power (1.7 mW/cm²), the thin-film gas sensor based on ZnO monolayer hollow sphere array showed excellent NO₂-sensing performances with a detection limit of 0.098 mg/m³, and the sensing response toward 2.45 mg/m³ NO₂ gas could reach 5.7 with an ultra-fast response/recovery speed (3 s/5 s). With the finite difference time domain method, the local field intensity of the monolayer hollow sphere array-film was investigated, and it was found that the second-level response/recovery mechanism might be due to the relatively uniform local field intensity distribution of the monolayer hollow sphere array film.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

氧化锌单层空心球阵列薄膜的制备及其紫外光驱动下对二氧化氮的超快气敏响应

通讯作者: 段国韬,E-mail:duangt@hust.edu.cn

English

Preparation of Zinc Oxide Monolayer Porous Hollow Sphere Array and Its Ultra-Fast Response to NO₂ at Room Temperature under Ultraviolet Irradiation

Corresponding author: DUAN Guo-Tao, duangt@hust.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

氧化锌单层空心球阵列薄膜的制备及其紫外光驱动下对二氧化氮的超快气敏响应

通讯作者: 段国韬,E-mail:duangt@hust.edu.cn

English

Preparation of Zinc Oxide Monolayer Porous Hollow Sphere Array and Its Ultra-Fast Response to NO2 at Room Temperature under Ultraviolet Irradiation

Corresponding author: DUAN Guo-Tao, duangt@hust.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Preparation of Zinc Oxide Monolayer Porous Hollow Sphere Array and Its Ultra-Fast Response to NO₂ at Room Temperature under Ultraviolet Irradiation

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs