双波长-导数-同步荧光法同时测定溶解态1-甲基菲及其代谢产物

引用本文: 陈晶晶, 郭帅, 朱亚先, 张勇. 双波长-导数-同步荧光法同时测定溶解态1-甲基菲及其代谢产物[J]. 分析化学, 2021, 49(4): 636-641. doi: 10.19756/j.issn.0253-3820.201467 shu

Citation: CHEN Jing-Jing, GUO Shuai, ZHU Ya-Xian, ZHANG Yong. Simultaneous Determination of Dissolved 1-Methylphenanthrene and Its Metabolites by Derivative Synchronous Fluorescence Spectrometry with Double Scans Method[J]. Chinese Journal of Analytical Chemistry, 2021, 49(4): 636-641. doi: 10.19756/j.issn.0253-3820.201467 shu

双波长-导数-同步荧光法同时测定溶解态1-甲基菲及其代谢产物

陈晶晶 ^1, ,
郭帅 ^1, ,
朱亚先 ^2, ,
张勇 ^{1,
,}

1.
近海海洋环境科学国家重点实验室, 厦门大学环境与生态学院, 厦门 361102;
2.
厦门大学化学化工学院, 厦门 361005

通讯作者: 张勇,E-mail:yzhang@xmu.edu.cn

基金项目:
国家自然科学基金项目（No.21627814）资助。

摘要: 建立了双波长-导数-同步荧光法，实现了模拟条件下溶解态1-甲基菲（1-Methlyphenanthrene，1-MP）及其代谢产物1-羟基-2-萘甲酸（1-Hydroxy-2-naphthoic acid，1H2NA）和水杨酸（Salicylic acid，SA）的同时测定。所建方法测定1-MP、1H2NA及SA的线性范围分别为0.02~1.30 μmol/L、0.02~7.60 μmol/L和0.01~5.20 μmol/L，检出限（LOD）分别为0.11、0.33和2.90 nmol/L，相对标准偏差均小于2%，样品加标回收率在97.4%~108.6%之间。本方法具有原位、在线动态实时研究1-MP降解过程及机制的应用潜力。

关键词:

English

Simultaneous Determination of Dissolved 1-Methylphenanthrene and Its Metabolites by Derivative Synchronous Fluorescence Spectrometry with Double Scans Method

1.
State Key Laboratory of Marine Environmental Science of China, College of the Environment & Ecology, Xiamen University, Xiamen 361102, China;
2.
College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China

Corresponding author: ZHANG Yong, yzhang@xmu.edu.cn

Received Date: 05 August 2020
Revised Date: 18 January 2021
Fund Project:
Supported by the National Natural Science Foundation of China (No.21627814).

Abstract: Derivative synchronous fluorescence spectrometry with double scans method was established to simultaneously determine the dissolved 1-methylphenanthrene (1-MP) and its metabolites such as 1-hydroxy-2-naphthoic acid (1H2NA) and salicylic acid (SA). With this method, the linear ranges for determination of 1-MP, 1H2NA and SA were 0.02-1.30 μmol/L, 0.02-7.60 μmol/L and 0.01-5.20 μmol/L, the detection limits (LODs) of 1-MP, 1H2NA and SA were 0.11, 0.33 and 2.90 nmol/L, the relative standard deviations (RSD) were less than 2%, and the recoveries were 97.4%-108.6%. This method was suitable for the simultaneous determination of 1-MP, 1H2NA and SA in the dissolved 1-MP microbial degradation process under the laboratory simulation condition, showing practical application potential in investigation of 1-MP degradation process and mechanism in situ.

Key words:

1-Methylphenanthrene
/ Metabolites
/ Double wavelength
/ Derivative synchronous fluorescence spectrometry

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双波长-导数-同步荧光法同时测定溶解态1-甲基菲及其代谢产物

通讯作者: 张勇,E-mail:yzhang@xmu.edu.cn

English

Simultaneous Determination of Dissolved 1-Methylphenanthrene and Its Metabolites by Derivative Synchronous Fluorescence Spectrometry with Double Scans Method

Corresponding author: ZHANG Yong, yzhang@xmu.edu.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

双波长-导数-同步荧光法同时测定溶解态1-甲基菲及其代谢产物

通讯作者: 张勇,E-mail:yzhang@xmu.edu.cn

English

Simultaneous Determination of Dissolved 1-Methylphenanthrene and Its Metabolites by Derivative Synchronous Fluorescence Spectrometry with Double Scans Method

Corresponding author: ZHANG Yong, yzhang@xmu.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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