Citation:
CHEN Er-Xia, LIU Juan, WANG Fei, ZHANG Jian. Effect of Substituent Groups on the Syntheses of Two Ag Coordination Polymers Based on Tetrazole-yl Acylamide[J]. Chinese Journal of Structural Chemistry,
2015, 34(11): 1729-1734.
doi:
10.14102/j.cnki.0254-5861.2011-0754
Effect of Substituent Groups on the Syntheses of Two Ag Coordination Polymers Based on Tetrazole-yl Acylamide
摘要:
Two novel Ag coordination polymers based on tetrazole-yl acylamide, Ag(NTAA) (1, H-NTAA=N-(1H-tetrazol-5-yl)acetamide) and Ag(NTPA) (2, H-NTPA=N-(1H-tetrazol-5-yl)propionamide) have been synthesized under solvothermal conditions and characterized by single-crystal X-ray diffraction. Compound 1 features a 3-connected 4·82-fes network and com-pound 2 displays a ladder-like chain. The different structures between 1 and 2 are mainly related with the substituent groups of tetrazole-yl acylamide.
English
Effect of Substituent Groups on the Syntheses of Two Ag Coordination Polymers Based on Tetrazole-yl Acylamide
Abstract:
Two novel Ag coordination polymers based on tetrazole-yl acylamide, Ag(NTAA) (1, H-NTAA=N-(1H-tetrazol-5-yl)acetamide) and Ag(NTPA) (2, H-NTPA=N-(1H-tetrazol-5-yl)propionamide) have been synthesized under solvothermal conditions and characterized by single-crystal X-ray diffraction. Compound 1 features a 3-connected 4·82-fes network and com-pound 2 displays a ladder-like chain. The different structures between 1 and 2 are mainly related with the substituent groups of tetrazole-yl acylamide.
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Key words:
- coordination polymers
- / silver
- / crystal structure
- / topology
- / electron donating
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