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基于X-射线单晶衍射精准构筑簇基金属有机框架及其CO2催化转化

于莹莹 ,  徐航

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引用本文: 于莹莹, 徐航. 基于X-射线单晶衍射精准构筑簇基金属有机框架及其CO2催化转化[J]. 大学化学, 2026, 41(10): 132-142. doi: 10.12461/PKU.DXHX202511033 shu
Citation:  Yingying Yu,  Hang Xu. 基于X-射线单晶衍射精准构筑簇基金属有机框架及其CO2催化转化[J]. University Chemistry, 2026, 41(10): 132-142. doi: 10.12461/PKU.DXHX202511033 shu

基于X-射线单晶衍射精准构筑簇基金属有机框架及其CO2催化转化

  • 南开大学化学学院, 天津 300071

    • 通讯作者: 徐航,E-mail:xuhang@nankai.edu.cn
  • 基金项目:

    国家自然科学基金(22271159)

摘要: 为响应国家科技兴邦与可持续战略，本研究将前沿成果融入教学，旨在增强学生社会责任感，拓展专业与学术视野，培养科学思维、创新能力与实践能力，激发科研热情。诺贝尔奖前沿材料金属有机框架(MOFs)，尤其是簇基MOFs，因结构可调、稳定性高且活性位点丰富，在CO2催化转化中展现出广阔前景，已成国内外研究热点。但簇基MOFs合成仍面临“黑箱反应”带来的不可预测性与结构精确调控的挑战。本文以X-射线单晶衍射解析金属团簇结构为起点，系统介绍了从零维金属团簇“自下而上”构筑簇基MOFs的研究进展，并从金属团簇中心、有机配体及孔道客体分子三方面深入探讨调控其CO2催化性能的策略。通过精选的典型案例，有助于本科生直观理解X-射线单晶衍射、簇基MOFs及CO2催化转化等前沿动态，拓展其相关领域认知。

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  • 发布日期:  2025-12-15
  • 收稿日期:  2025-11-05
  • 接受日期:  2025-12-02
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