可见光催化绿色合成二肽化合物

艾晓梅 林牧然 曾金兰 任继伟

引用本文: 艾晓梅, 林牧然, 曾金兰, 任继伟. 可见光催化绿色合成二肽化合物[J]. 大学化学, 2026, 41(5): 358-367. doi: 10.12461/PKU.DXHX202510007 shu
Citation:  Xiaomei Ai,  Muran Lin,  Jinlan Zeng,  Jiwei Ren. 可见光催化绿色合成二肽化合物[J]. University Chemistry, 2026, 41(5): 358-367. doi: 10.12461/PKU.DXHX202510007 shu

可见光催化绿色合成二肽化合物

    通讯作者: 任继伟,E-mail:renjiwei@tsu.edu.cn
  • 基金项目:

    国家自然科学基金项目(22508288);山东省自然科学基金项目(ZR2023QB153)

摘要: 本文报道了一种可见光催化三苯基膦促进的脱氧酰胺化策略,用于二肽化合物的合成。以金属铱的配合物为催化剂,在蓝光照射下N-保护的氨基酸产生酰基自由基,和氨基酸酯发生偶联反应生成二肽,产物具有较高的产率和非常好的非对映选择性。实验具有试剂廉价易得、反应条件温和、操作简单安全、绿色高效、重现性好等优点,时间可控制在8学时内。

English

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  • 发布日期:  2026-03-03
  • 收稿日期:  2025-10-09
  • 修回日期:  2026-02-06
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