铯铅卤钙钛矿量子点的可控合成及材料表征—

引用本文: 邱培瑞, 曾宪赟, 唐恪涵, 陈红云, 李国然, 刘阳. 铯铅卤钙钛矿量子点的可控合成及材料表征——一个综合化学实验[J]. 大学化学, 2026, 41(6): 395-403. doi: 10.12461/PKU.DXHX202508073 shu

Citation: Peirui Qiu, Xianyun Zeng, Kehan Tang, Hongyun Chen, Guoran Li, Yang Liu. Synthesis and characterization of cesium lead halide perovskite quantum dots: a comprehensive chemistry experiment[J]. University Chemistry, 2026, 41(6): 395-403. doi: 10.12461/PKU.DXHX202508073 shu

铯铅卤钙钛矿量子点的可控合成及材料表征——一个综合化学实验

邱培瑞 ^1, ,
曾宪赟 ^1, ,
唐恪涵 ^1, ,
陈红云 ^{1,2,
,} ,
李国然 ^1,2, ,
刘阳 ^2,3,

1.
南开大学材料科学与工程学院, 天津 300350;
2.
化学国家级实验教学示范中心(南开大学), 天津 30071;
3.
南开大学化学学院, 天津 30071

通讯作者: 陈红云,Email:hychen@nankai.edu.cn

基金项目:
南开大学2024年本科教育教学改革项目(NKJG2024066)；2023年南开大学实验教学改革项目(23NKZZYQ08)；2022年教育部产学合作协同育人项目(220605940222513)

摘要: 铯铅卤钙钛矿量子点(CsPbX₃，X = Cl/Br/I)因其优异的光学性能，在显示技术、光伏器件、光电探测等领域展现出广阔的应用前景。本文对科学热点CsPbX₃量子点的合成和表征进行教学化改进，通过热注射法制备不同卤素组分的量子点，结合紫外-可见吸收光谱、荧光光谱、离子色谱及电感耦合等离子体发射光谱等表征手段对所制备量子点进行表征，并系统探究了卤素组分(X = Cl/Br/I)对材料光学性能的影响。通过此实验，学生亲身体验了纳米材料制备与表征的完整过程，帮助学生直观地理解材料结构与性能的关联，在引导学生将理论与实践相结合的同时，激发学生自主探究热情，掌握科学系统的研究方法，最终提升学生解决复杂科学问题的能力。

关键词:

English

Synthesis and characterization of cesium lead halide perovskite quantum dots: a comprehensive chemistry experiment

1.
School of Materials Science and Engineering, Nankai University, Tianjin 300350, China;
2.
National Demonstration Center for Experimental Chemistry Education, Nankai University, Tianjin 300071, China;
3.
College of Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: Hongyun Chen, hychen@nankai.edu.cn

Received Date: 25 August 2025
Revised Date: 17 October 2025
Available Online: 28 November 2025

Abstract: Cesium lead halide perovskite quantum dots (CsPbX₃, X = Cl/Br/I) exhibit outstanding optoelectronic properties, enabling their widespread applications in display technologies, photovoltaic devices, and photodetection. This study introduces an optimized synthesis and characterization protocol for CsPbX₃ quantum dots specifically designed for undergraduate education. Students employ the hot injection method to synthesize quantum dots, followed by comprehensive characterization using UV-Vis absorption spectroscopy, photoluminescence spectroscopy, ion chromatography, and inductively coupled plasma optical emission spectroscopy. The experiment systematically examines how halogen composition (X = Cl/Br/I) affects the optical properties of the quantum dots. Through this hands-on experience, students acquire practical skills in nanomaterial preparation and characterization while developing a fundamental understanding of structure-property relationships in quantum dots, particularly the critical role of halogen composition in determining optical characteristics. Furthermore, this experiment fosters innovative thinking by integrating laboratory practice with theoretical knowledge, ultimately enhancing students' problem-solving capabilities in complex scientific scenarios.

Key words:

1. [1]
  J.J. Si, J.H. Jiang, S.H. Su, Y.M. Zhang, M.X. Du, J.P. Xu, H.M. Jia, Z. Zheng, W.W. He, J. Chem. Edu. 2025, 102, 2468.J.J. Si, J.H. Jiang, S.H. Su, Y.M. Zhang, M.X. Du, J.P. Xu, H.M. Jia, Z. Zheng, W.W. He, J. Chem. Edu. 2025, 102, 2468.
2. [2]
  C. Zhang, Z.Y. Wang, Z.Y. Da, J.D. Shi, J.N. Wang, Y.L. Xu, G. Nikolai, S.B. Arshad, M.Q. Wang, ACS Appl. Mater. Interfaces 2024, 16, 20715.C. Zhang, Z.Y. Wang, Z.Y. Da, J.D. Shi, J.N. Wang, Y.L. Xu, G. Nikolai, S.B. Arshad, M.Q. Wang, ACS Appl. Mater. Interfaces 2024, 16, 20715.
3. [3]
  C. She, T.L. Ye, P.X. Yang, G.Y. Chen, Adv. Mater. 2024, 36, 2401498.C. She, T.L. Ye, P.X. Yang, G.Y. Chen, Adv. Mater. 2024, 36, 2401498.
4. [4]
  Y. Li, F.H. Ma, D. Zhao, F. Lu, J.W. Wang, S. Cao, Y.H. Zhou, Mate. Technol. 2020, 36, 637.Y. Li, F.H. Ma, D. Zhao, F. Lu, J.W. Wang, S. Cao, Y.H. Zhou, Mate. Technol. 2020, 36, 637.
5. [5]
  C.T. Wei, W.M. Su, J.T. Li, B. Xu, Q.S. Shan, Y. Wu, F.J. Zhang, M.M. Luo, H.Y. Xiang, Z. Cui, et al., Adv. Mater. 2022, 34, 2107798.C.T. Wei, W.M. Su, J.T. Li, B. Xu, Q.S. Shan, Y. Wu, F.J. Zhang, M.M. Luo, H.Y. Xiang, Z. Cui, et al., Adv. Mater. 2022, 34, 2107798.
6. [6]
  F. S. Mayara, L.C. Ana, A.L. Numbia, J.S. Josenilton, P.M. Marcos, G.C. Caterina, J. Chem. Edu. 2024, 101, 5476.F. S. Mayara, L.C. Ana, A.L. Numbia, J.S. Josenilton, P.M. Marcos, G.C. Caterina, J. Chem. Edu. 2024, 101, 5476.
7. [7]
  J. Guo, Y.H. Fu, W.J. Zheng, M.Y. Xie, Y.C. Huang, Z.Y. Miao, C. Han, W.X. Yin, J.Q. Zhang, X.Y. Yang, et al., Nano Lett. 2024, 24, 417.J. Guo, Y.H. Fu, W.J. Zheng, M.Y. Xie, Y.C. Huang, Z.Y. Miao, C. Han, W.X. Yin, J.Q. Zhang, X.Y. Yang, et al., Nano Lett. 2024, 24, 417.
8. [8]
  P. Mahsa, B. Julia, H. Jan, C. Noura, D.R. Jonathan, J. Chem. Educ.2023, 100, 1613.P. Mahsa, B. Julia, H. Jan, C. Noura, D.R. Jonathan, J. Chem. Educ.2023, 100, 1613.
9. [9]
  L. George, M.P. Ross, P. Weltha, K.Y. Liu, J. Chem. Educ. 2020, 97, 806.L. George, M.P. Ross, P. Weltha, K.Y. Liu, J. Chem. Educ. 2020, 97, 806.
10. [10]
  Y. Bai, M.M. Hao, S.S. Ding, P. Chen, L.Z. Wang, Adv. Mater. 2022, 34, 2105958Y. Bai, M.M. Hao, S.S. Ding, P. Chen, L.Z. Wang, Adv. Mater. 2022, 34, 2105958
11. [11]
  D. Anirban, K.D. Sumit, D.A. Samrat, P. Narayan, ACS Energy Lett. 2018, 3, 329.D. Anirban, K.D. Sumit, D.A. Samrat, P. Narayan, ACS Energy Lett. 2018, 3, 329.
12. [12]
  Y.C. Ji, L.M. Liang, T. Ma, J.N. Hu, Z.Y. Chen, J. Chen, Opt. Mater. 2023, 143, 114254.Y.C. Ji, L.M. Liang, T. Ma, J.N. Hu, Z.Y. Chen, J. Chen, Opt. Mater. 2023, 143, 114254.
13. [13]
  H.Y. Hu, H.Q. Wang, X.T. Huang, Y.H. Geng, J.H. Xu, Z.H. Yuan, Small 2025, 21, e04547.H.Y. Hu, H.Q. Wang, X.T. Huang, Y.H. Geng, J.H. Xu, Z.H. Yuan, Small 2025, 21, e04547.
14. [14]
  W. Fu, J.X. Ma, Z.R. Qiao, L. Xu, L.Y. Wang, M. Ling, X.Q. Fu, G. Li, C. Han, J. Zhang, Langmuir 2023, 39, 16349.W. Fu, J.X. Ma, Z.R. Qiao, L. Xu, L.Y. Wang, M. Ling, X.Q. Fu, G. Li, C. Han, J. Zhang, Langmuir 2023, 39, 16349.
15. [15]
  F.W. Cheng, R.Q. He, S.Q. Nie, C.J. Zhang, J. Yin, J. Li, N.F. Zheng, B.H. Wu, J. Am. Chem. Soc. 2021, 143, 5855.F.W. Cheng, R.Q. He, S.Q. Nie, C.J. Zhang, J. Yin, J. Li, N.F. Zheng, B.H. Wu, J. Am. Chem. Soc. 2021, 143, 5855.
16. [16]
  K. Maksym, P. Loredana, B. Maryna, Science 2017, 358,745.K. Maksym, P. Loredana, B. Maryna, Science 2017, 358,745.
17. [17]
  S. Abhishek, K.R. Vikash, N. Angshuman, ACS Energy Lett. 2017, 2, 1089.S. Abhishek, K.R. Vikash, N. Angshuman, ACS Energy Lett. 2017, 2, 1089.

扫一扫看文章

计量

PDF下载量: 0
文章访问数: 46
HTML全文浏览量: 7

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

铯铅卤钙钛矿量子点的可控合成及材料表征——一个综合化学实验

通讯作者: 陈红云,Email:hychen@nankai.edu.cn

English

Synthesis and characterization of cesium lead halide perovskite quantum dots: a comprehensive chemistry experiment

Corresponding author: Hongyun Chen, hychen@nankai.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

铯铅卤钙钛矿量子点的可控合成及材料表征——一个综合化学实验

通讯作者: 陈红云,Email:hychen@nankai.edu.cn

English

Synthesis and characterization of cesium lead halide perovskite quantum dots: a comprehensive chemistry experiment

Corresponding author: Hongyun Chen, hychen@nankai.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs