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氖的特殊化学物种：研究进展与成键机制

任建林 ,  李冰 ,  郭燕 ,  刘翔宇

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引用本文: 任建林, 李冰, 郭燕, 刘翔宇. 氖的特殊化学物种：研究进展与成键机制[J]. 大学化学, 2026, 41(9): 182-201. doi: 10.12461/PKU.DXHX202508055 shu
Citation:  Jianlin Ren,  Bing Li,  Yan Guo,  Xiangyu Liu. 氖的特殊化学物种：研究进展与成键机制[J]. University Chemistry, 2026, 41(9): 182-201. doi: 10.12461/PKU.DXHX202508055 shu

氖的特殊化学物种：研究进展与成键机制

  • 宁夏大学化学化工学院, 省部共建煤炭高效利用与绿色化工国家重点实验室, 宁夏 银川 750021

    • 通讯作者: 任建林,E-mail:rjl@nxu.edu.cn
  • 基金项目:

    新工科背景下化学化工类数字化实验教学的应用研究(教育部高教司(教高函[2024]215号))

摘要: 氖是价电子层为2s22p6的闭壳层八隅体，属轻稀有气体，因而在常规条件下表现出极强的化学惰性。近年来，借助高精度计算化学对势能面的系统预测，以及极端条件下原位实验技术(低温基质隔离、高压金刚石对顶砧、同步辐射原位光谱等)的同步发展，研究者已能在实验室尺度诱导氖与特定宿主发生弱相互作用，生成若干“非经典”化学物种。本文在梳理现有文献的基础上，将这些发现归纳为三类：包合物(含内嵌富勒烯化合物)、高压下与碱金属/碱土金属形成的离子型化合物、低温基质中与含硅自由基的范德华复合物(含与四氯化碳的电荷转移复合物)，其成键机制与已报道的氦化合物具有高度相似。

English

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  • 发布日期:  2025-12-03
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