结合水：从生物氢键网络到人工材料的智能调控

引用本文: 马刚, 靳思雨, 郑波, 高玲燕. 结合水：从生物氢键网络到人工材料的智能调控[J]. 大学化学, 2026, 41(4): 275-279. doi: 10.12461/PKU.DXHX202504088 shu

Citation: Gang Ma, Siyu Jin, Bo Zheng, Lingyan Gao. Bound Water: Intelligent Regulation from Biological Hydrogen-Bond Networks to Artificial Materials[J]. University Chemistry, 2026, 41(4): 275-279. doi: 10.12461/PKU.DXHX202504088 shu

结合水：从生物氢键网络到人工材料的智能调控

西北大学化学与材料科学学院, 教育部合成与天然功能分子重点实验室, 陕西西安 710127

通讯作者: 郑波,E-mail:zhengbo@nwu.edu.cn; 高玲燕,E-mail:gaolingyan@nwu.edu.cn

基金项目:
陕西省基础科学(化学、生物学)研究院青年项目(23JHQ016)

摘要: 结合水通过氢键锚定、疏水缔合等机制，在维持生物大分子结构并发挥其特定功能方面有着重要的作用。受上述自然现象启发，研究者们通过仿生设计与分子工程，将结合水作为功能性结构单元引入聚合物网络，突破了传统“水分致软化”的局限，利用水分子调控材料的力学性能，实现了具备高韧性、环境适应性和能量耗散功能的聚合物材料构筑。本文系统阐述近年来通过在聚合物网络中引入结合水，利用结合水与聚合物结构中基元的相互作用，调控聚合物性能的研究进展。

关键词:

English

Bound Water: Intelligent Regulation from Biological Hydrogen-Bond Networks to Artificial Materials

Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710127, Shaanxi Province, China

Corresponding author: Bo Zheng, ; Lingyan Gao,

Received Date: 28 April 2025
Accepted Date: 30 June 2025
Available Online: 08 September 2025

Abstract: Bound water plays a pivotal role in maintaining biomacromolecular structures and facilitating their specific functions through mechanisms such as hydrogen-bond anchoring and hydrophobic association. Inspired by these natural phenomena, researchers have incorporated bound water as a functional structural unit into polymer networks through biomimetic design and molecular engineering. This innovative approach overcomes the conventional limitation of “water-induced softening” and instead utilizes water molecules to regulate material mechanical properties, enabling the fabrication of polymer materials with high toughness, environmental adaptability, and energy dissipation capabilities. This review systematically summarizes recent advances in polymer performance modulation through the introduction of bound water into polymer networks and the manipulation of interactions between bound water and polymeric structural elements.

Key words:

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

结合水：从生物氢键网络到人工材料的智能调控

通讯作者: 郑波,E-mail:zhengbo@nwu.edu.cn; 高玲燕,E-mail:gaolingyan@nwu.edu.cn

English

Bound Water: Intelligent Regulation from Biological Hydrogen-Bond Networks to Artificial Materials

Corresponding author: Bo Zheng, ; Lingyan Gao,

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

结合水：从生物氢键网络到人工材料的智能调控

通讯作者: 郑波,E-mail:zhengbo@nwu.edu.cn; 高玲燕,E-mail:gaolingyan@nwu.edu.cn

English

Bound Water: Intelligent Regulation from Biological Hydrogen-Bond Networks to Artificial Materials

Corresponding author: Bo Zheng, ; Lingyan Gao,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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