共价有机框架——新兴的有机多孔材料

引用本文: 杨奔, 沈淑坤, 金普军, 罗雨佳, 胡鉴勇. 共价有机框架——新兴的有机多孔材料[J]. 大学化学, 2026, 41(4): 264-274. doi: 10.12461/PKU.DXHX202502128 shu

Citation: Ben Yang, Shukun Shen, Pujun Jin, Yujia Luo, Jianyong Hu. Covalent organic frameworks: emerging organic porous materials[J]. University Chemistry, 2026, 41(4): 264-274. doi: 10.12461/PKU.DXHX202502128 shu

共价有机框架——新兴的有机多孔材料

杨奔 ^{1,2,
,} ,
沈淑坤 ^1, ,
金普军 ^1, ,
罗雨佳 ^1, ,
胡鉴勇 ^{1,2,
,}

1.
陕西师范大学材料科学与工程学院, 陕西西安 710119;
2.
陕西师范大学应用表面与胶体化学教育部重点实验室, 陕西西安 710119

通讯作者: 杨奔,E-mail:yangben@snnu.edu.cn; 胡鉴勇,E-mail:hujianyong@snnu.edu.cn

基金项目:
国家自然科学基金(62374106,52303242)；陕西省重点研发计划(2024GX-YBXM-560)；陕西省科技创新团队(2022TD-35)；教育部产学合作协同育人项目(230907194294153)。

摘要: 共价有机框架(COFs)是一类由有机分子通过共价键连接形成的有机多孔结晶聚合物。COFs具有开放的孔道、可定制的功能和出色的稳定性等特点，在气体吸附、催化、能源存储和生物等领域极具前景。本文将简要介绍COFs的定义和分类、合成方法、发展历史及在新兴领域的应用。最后，本文对COFs材料未来发展所面临的机遇和挑战进行了展望。

关键词:

English

Covalent organic frameworks: emerging organic porous materials

Ben Yang ^{1,2,
,} ,
Shukun Shen ^1, ,
Pujun Jin ^1, ,
Yujia Luo ^1, ,
Jianyong Hu ^{1,2,
,}

1.
School of Materials Science and Engineering, Shaanxi Normal University, Xi'an 710119, Shaanxi Province, China;
2.
Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, Shaanxi Normal University, Xi'an 710119, Shaanxi Province, China

Corresponding author: Ben Yang, ; Jianyong Hu,

Received Date: 26 February 2025
Accepted Date: 08 April 2025
Available Online: 01 September 2025

Abstract: Covalent organic frameworks (COFs) represent a novel class of crystalline porous polymers formed through covalent bonding between organic building blocks. Characterized by well-defined pore structures, tunable functionalities, and remarkable stability, COFs demonstrate significant potential for applications in gas adsorption/separation, catalysis, energy storage, and biomedical fields. This review provides a concise overview of COFs, including their fundamental concepts, classification schemes, synthetic methodologies, historical development, and emerging applications. The article concludes with perspectives on both the opportunities and challenges in the future advancement of COF materials.

Key words:

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

共价有机框架——新兴的有机多孔材料

通讯作者: 杨奔,E-mail:yangben@snnu.edu.cn; 胡鉴勇,E-mail:hujianyong@snnu.edu.cn

English

Covalent organic frameworks: emerging organic porous materials

Corresponding author: Ben Yang, ; Jianyong Hu,

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

共价有机框架——新兴的有机多孔材料

通讯作者: 杨奔,E-mail:yangben@snnu.edu.cn; 胡鉴勇,E-mail:hujianyong@snnu.edu.cn

English

Covalent organic frameworks: emerging organic porous materials

Corresponding author: Ben Yang, ; Jianyong Hu,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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