硼宾的合成、结构与化学反应性质研究进展

引用本文: 陈明, 莫贞波. 硼宾的合成、结构与化学反应性质研究进展[J]. 大学化学, 2026, 41(4): 250-263. doi: 10.12461/PKU.DXHX202502123 shu

Citation: Ming Chen, Zhenbo Mo. Research Progress on the Synthesis, Structure, and Chemical Reactivity of Borylenes[J]. University Chemistry, 2026, 41(4): 250-263. doi: 10.12461/PKU.DXHX202502123 shu

硼宾的合成、结构与化学反应性质研究进展

陈明 ,
莫贞波 ^,

南开大学化学学院, 元素有机化学国家重点实验室, 有机新物质创造前沿科学中心, 天津 300071

通讯作者: 莫贞波,E-mail:zhenbo.mo@nankai.eud.cn

基金项目:
感谢国家重点研发计划项目(2023YFF0723900)；国家自然科学基金项目(22071124、22371130、223B2109、22188101、22221002)；南开大学新有机质前沿科学研究中心项目(C029215001)；中央高校基本科研业务费专项资金(63206007)；南开大学的资助。

摘要: 硼宾是一类含有低价主族元素中心(一价硼)的化合物，硼中心同时拥有两个空轨道和一对孤对电子，具有高反应活性，单配位硼宾化合物至今未被成功分离。近年来，随着主族元素化学的发展，路易斯碱稳定的两配位和三配位硼宾化合物的合成与分离取得了较大的进展，两亲性的特征使其不仅能作为电子供体与过渡金属配位，还能促进小分子的活化与转化。本文综述了有关硼宾化合物合成探索和反应化学研究的文献报道，并对该领域未来的发展方向进行了展望。

关键词:

English

Research Progress on the Synthesis, Structure, and Chemical Reactivity of Borylenes

Ming Chen ,
Zhenbo Mo ^,

Frontiers Science Center for New Organic Matter, State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: Zhenbo Mo, zhenbo.mo@nankai.eud.cn

Received Date: 26 February 2025
Accepted Date: 05 June 2025
Available Online: 22 August 2025

Abstract: Borylenes are highly reactive species featuring a low-valent main group element center, characterized by a boron atom in the +I oxidation state. The boron center of borylenes possesses two empty orbitals and a lone pair of electrons; however, monocoordinated free borylenes have yet to be successfully isolated. In recent years, advancements in main group chemistry have led to significant progress in the synthesis and isolation of Lewis base-stabilized dicoordinated and tricoordinated borylenes. These compounds not only serve as donor ligands for coordination with transition metals but also facilitate the activation and transformation of small molecules. This review summarizes the literature reports on the synthetic exploration and reaction chemistry of borylene compounds, and provides perspectives on future research directions in this field.

Key words:

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

硼宾的合成、结构与化学反应性质研究进展

通讯作者: 莫贞波,E-mail:zhenbo.mo@nankai.eud.cn

English

Research Progress on the Synthesis, Structure, and Chemical Reactivity of Borylenes

Corresponding author: Zhenbo Mo, zhenbo.mo@nankai.eud.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

硼宾的合成、结构与化学反应性质研究进展

通讯作者: 莫贞波,E-mail:zhenbo.mo@nankai.eud.cn

English

Research Progress on the Synthesis, Structure, and Chemical Reactivity of Borylenes

Corresponding author: Zhenbo Mo, zhenbo.mo@nankai.eud.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

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