石墨相氮化碳用于光催化Minisci反应——推荐一个科研成果转化的综合设计实验

引用本文: 王晓羽, 李伊凡, 刘睿伯, 安丽, 曲丹, 刘弈畅, 孙再成. 石墨相氮化碳用于光催化Minisci反应——推荐一个科研成果转化的综合设计实验[J]. 大学化学, 2026, 41(4): 363-371. doi: 10.12461/PKU.DXHX202502065 shu

Citation: Xiaoyu Wang, Yifan Li, Ruibo Liu, Li An, Dan Qu, Yichang Liu, Zaicheng Sun. Graphitic Carbon Nitride Catalyzed Photochemical Minisci Reaction: A Comprehensive Experimental Design Derived from Scientific Research[J]. University Chemistry, 2026, 41(4): 363-371. doi: 10.12461/PKU.DXHX202502065 shu

石墨相氮化碳用于光催化Minisci反应——推荐一个科研成果转化的综合设计实验

北京工业大学化学与生命科学学院, 北京 100124

通讯作者: 刘弈畅,E-mail:yichangliu@bjut.edu.cn; 孙再成,E-mail:sunzc@bjut.edu.cn

摘要: 本文介绍了一个取材自课题组科研成果的本科生化学综合设计实验。本实验涉及石墨相氮化碳的合成，并以其作为光催化剂实现氧化还原活性酯(NHP酯)与喹啉的Minisci反应。通过该实验可令学生了解实际科研中，从催化剂的制备、表征，到实现光催化反应的完整流程。实验中涉及对抽滤、薄层层析、柱层析等基本实验操作的复习，同时训练学生掌握马弗炉、气相色谱、X射线衍射仪(XRD)等大型仪器的使用方法。通过该实验可向学生介绍光催化基本原理，传递“绿色化学”的概念，引申至“双碳战略”。同时拓宽学生视野，锻炼科研思维，增强学生对科研的兴趣。

关键词:

English

Graphitic Carbon Nitride Catalyzed Photochemical Minisci Reaction: A Comprehensive Experimental Design Derived from Scientific Research

College of Chemistry and Life Science, Beijing University of Technology, Beijing 100124, China

Corresponding author: Yichang Liu, ; Zaicheng Sun,

Received Date: 08 February 2025
Accepted Date: 14 April 2025
Available Online: 11 August 2025

Abstract: This paper presents a comprehensive chemistry experiment for undergraduate laboratory teaching, derived from our research group's scientific achievements. The experiment encompasses the synthesis of graphitic carbon nitride (g-C₃N₄) and its application as a photocatalyst in the Minisci reaction between redox-active ester (NHP ester) and quinoline. Through this experiment, students gain insight into the complete scientific research process, ranging from catalyst preparation and characterization to the execution of photocatalytic reactions. The experiment incorporates fundamental laboratory techniques such as suction filtration, thin layer chromatography (TLC), and column chromatography, while also providing training in the operation of advanced instruments including a muffle furnace, gas chromatography (GC), and X-ray powder diffractometer (XRD). This experiment introduces students to the fundamental principles of photocatalysis and the concept of green chemistry, extending to the broader context of carbon peak and neutrality strategies. Furthermore, it aims to broaden students' scientific perspectives, cultivate research-oriented thinking, and enhance their interest in scientific inquiry.

Key words:

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石墨相氮化碳用于光催化Minisci反应——推荐一个科研成果转化的综合设计实验

通讯作者: 刘弈畅,E-mail:yichangliu@bjut.edu.cn; 孙再成,E-mail:sunzc@bjut.edu.cn

English

Graphitic Carbon Nitride Catalyzed Photochemical Minisci Reaction: A Comprehensive Experimental Design Derived from Scientific Research

Corresponding author: Yichang Liu, ; Zaicheng Sun,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

石墨相氮化碳用于光催化Minisci反应——推荐一个科研成果转化的综合设计实验

通讯作者: 刘弈畅,E-mail:yichangliu@bjut.edu.cn; 孙再成,E-mail:sunzc@bjut.edu.cn

English

Graphitic Carbon Nitride Catalyzed Photochemical Minisci Reaction: A Comprehensive Experimental Design Derived from Scientific Research

Corresponding author: Yichang Liu, ; Zaicheng Sun,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

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