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乙二胺三乙酸与锌(Ⅱ)、钴(Ⅱ)相互作用的固体和溶液化学特性

吴睿 ,  杨玉琛 ,  董鑫 ,  周朝晖

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引用本文: 吴睿, 杨玉琛, 董鑫, 周朝晖. 乙二胺三乙酸与锌(Ⅱ)、钴(Ⅱ)相互作用的固体和溶液化学特性[J]. 应用化学, 2016, 33(1): 70-75. doi: 10.11944/j.issn.1000-0518.2016.01.150208 shu
Citation:  WU Rui, YANG Yuchen, DONG Xin, ZHOU Zhaohui. Solid and Solution Properties of Zinc(Ⅱ) and Cobalt(Ⅱ) with Ethylenediaminetriacetate[J]. Chinese Journal of Applied Chemistry, 2016, 33(1): 70-75. doi: 10.11944/j.issn.1000-0518.2016.01.150208 shu

乙二胺三乙酸与锌(Ⅱ)、钴(Ⅱ)相互作用的固体和溶液化学特性

  • 1.

    厦门大学化学化工学院, 固体表面物理化学国家重点实验室 福建 厦门 361005

    • 通讯作者: 周朝晖,教授;Tel:0592-2184531;Fax:0592-2183047;E-mail:zhzhou@xmu.edu.cn;研究方向:配位催化
  • 基金项目:

    中央高校基本科研业务费专项资金（20720150041） 

摘要: 在水热和弱酸性反应条件下，螯合型表面活性剂前驱体乙二胺三乙酸分别与氯化锌、氯化钴反应，形成水合乙二胺三乙酸金属配合物[M（H2O）6] [M（ED3A）（H2O）]2·2H2O[M=Zn（1），Co（2）；H3ED3A=乙二胺三乙酸，C8H14N2O6]。产物经元素分析、红外、热重、液体核磁共振和X射线单晶衍射结构表征。乙二胺三乙酸和锌（Ⅱ）、钴（Ⅱ）五配位，并与水一起形成典型的[MN2O4]或[MO6]八面体结构。13C核磁共振实验结果表明，溶液中乙二胺三乙酸与锌形成配合物在弱酸性条件下（pH值3～7）稳定存在，在酸性溶液中完全解离，乙二胺三乙酸进一步经分子内成环反应生成3-酮哌嗪二乙酸（H2kpda=C8H12N2O5）。

English

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  • 收稿日期:  2015-06-19
  • 网络出版日期:  2015-10-08
通讯作者: 陈斌, bchen63@163.com
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