引用本文:
刘茹, 李海平, 侯万国. 三偏磷酸钠交联黄原胶的制备及其溶液流变性[J]. 应用化学,
2015, 32(9): 1061-1069.
doi:
10.11944/j.issn.1000-0518.2015.09.150111
Citation: LIU Ru, LI Haiping, HOU Wanguo. Synthesis of Sodium Trimetaphosphate Crosslinked Xanthan Gum and Rheological Properties of Its Aqueous Solution[J]. Chinese Journal of Applied Chemistry, 2015, 32(9): 1061-1069. doi: 10.11944/j.issn.1000-0518.2015.09.150111
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Citation: LIU Ru, LI Haiping, HOU Wanguo. Synthesis of Sodium Trimetaphosphate Crosslinked Xanthan Gum and Rheological Properties of Its Aqueous Solution[J]. Chinese Journal of Applied Chemistry, 2015, 32(9): 1061-1069. doi: 10.11944/j.issn.1000-0518.2015.09.150111
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三偏磷酸钠交联黄原胶的制备及其溶液流变性
摘要:
以三偏磷酸钠(STMP)为交联剂,合成了水溶性低交联度黄原胶(XG),依据其溶液粘度优化出了最佳合成条件;考察了电解质质量分数、pH值及温度对STMP交联黄原胶(简记为SP-c-XG)溶液流变性的影响,并与XG溶液进行了对比。结果表明,在所研究的电解质(NaCl和CaCl2)质量分数(0~5.0%)、p H值(2~11)和温度(20~70℃)范围内,SP-c-XG和XG溶液的流变曲线均为假塑型,符合Herschel-Bulkley模型;其屈服值、表观粘度和动力学模量随电解质质量分数增大均先下降后上升,而随p H值的升高先升高后降低,随温度升高而降低。SP-c-XG和XG溶液具有相似的流变性,但与XG溶液相比,SP-c-XG溶液具有更高的屈服值和表观粘度,特别是具有更强的弹性和耐温性,在油田强化采油领域具有重要应用前景。
English
Synthesis of Sodium Trimetaphosphate Crosslinked Xanthan Gum and Rheological Properties of Its Aqueous Solution
Abstract:
A water-soluble weakly crosslinked xanthan gum (XG) was synthesized using sodium trimetaphosphate (STMP) as a crosslinker,and the synthesis conditions were optimized based on the viscosity of the STMP crosslinked XG (denoted as SP-c-XG) solutions.Effects of electrolyte (NaCl and Ca Cl2) mass fraction (0~5.0%),p H (2~11),and temperature (20~70℃) on the rheological properties of the SP-c-XG solutions were investigated and compared with those of XG solutions.The results show that,under the studied conditions,the rheological curves of both SP-c-XG and XG solutions are pseudoplastic and can be described by Herschel-Bulkley model.The yield stress,apparent viscosity and dynamic moduli of the SP-c-XG and XG solutions initially decrease and then increase with increasing electrolyte concentration,but they initially increase and then decrease with increasing p H.Increasing temperature results in a decrease in these rheological parameter values for both SP-c-XG and XG solutions.The rheological properties of the SP-c-XG solution are similar to those of the XG solution.However,compared with the XG solution,the SP-c-XG solution exhibits higher yield stress and apparent viscosity,especially stronger elasticity and temperature resistance,indicating its use potential in enhanced oil recovery.
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Key words:
- xanthan gum
- / sodium trimetaphosphate
- / crosslink
- / rheology
- / temperature resistance
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