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由吡嗪衍生配体构筑的金属Cd(Ⅱ)配位聚合物的合成、结构及生物活性

王萃娟 ,  毛凯力 ,  代海玉 ,  刘晓雷 ,  孟涛 ,  张志斌 ,  周先礼 ,  王尧宇

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引用本文: 王萃娟, 毛凯力, 代海玉, 刘晓雷, 孟涛, 张志斌, 周先礼, 王尧宇. 由吡嗪衍生配体构筑的金属Cd(Ⅱ)配位聚合物的合成、结构及生物活性[J]. 无机化学学报, 2015, (11): 2221-2228. doi: 10.11862/CJIC.2015.267 shu
Citation:  WANG Cui-Juan, MAO Kai-Li, DAI Hai-Yu, LIU Xiao-Lei, MENG Tao, ZHANG Zhi-Bin, ZHOU Xian-Li, WANG Yao-Yu. Structural Diversity of Two Cadmium(Ⅱ) Polymers Based on Pyrazine Derivative Ligand: Syntheses, Crystal Structures and Bioactivities[J]. Chinese Journal of Inorganic Chemistry, 2015, (11): 2221-2228. doi: 10.11862/CJIC.2015.267 shu

由吡嗪衍生配体构筑的金属Cd(Ⅱ)配位聚合物的合成、结构及生物活性

  • 1.

    1 西南交通大学生命科学与工程学院化学化工系, 成都 610031;

  • 2.

    2 西北大学化学与材料学院, 合成与天然功能分子化学教育部重点实验室, 西安 710069

    • 通讯作者: 王萃娟 ejuan6046@163.com
  • 基金项目:

    国家自然科学基金(No.21401151) (No.21401151)

    四川省科技支撑计划(No.2015GZ0233) (No.2015GZ0233)

    中央高校基本科研业务费专项资金(No.SWJTU12CX049)资助项目。 (No.SWJTU12CX049)

摘要: 在相同的反应条件下,采用吡嗪衍生物作为配体与不同的金属镉盐反应,合成了2个新颖的配位化合物[Cd(L)2]n(1)和[Cd2(L)2(CH3COO)2(H2O)2](2)(HL=4-((3-(pyrazin-2-yl)-1H-pyrazol-1-yl)methyl)benzoicacid),并通过元素分析、热重分析、荧光光谱、X射线单晶衍射对化合物进行分析。结构分析表明1属于三斜晶系,P1空间群。金属Cd(Ⅱ)采用三角双锥构型,最后形成2D三明治结构;而2是双核结构,其中羧酸基团采用双齿螯合与金属配位。1与2的结构差异很大程度上归结于羧酸配位模式的不同以及阴离子的协同效应。此外,对配合物1和2进行了抗氧化活性的研究。

English

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  • 收稿日期:  2015-02-09
  • 网络出版日期:  2015-07-15
通讯作者: 陈斌, bchen63@163.com
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