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两个由两性二酸配体构筑的Cd(Ⅱ)低维配合物的合成、结构及荧光性质

丁芳芳 ,  张娜 ,  张建勇 ,  王敏 ,  高恩庆

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引用本文: 丁芳芳, 张娜, 张建勇, 王敏, 高恩庆. 两个由两性二酸配体构筑的Cd(Ⅱ)低维配合物的合成、结构及荧光性质[J]. 无机化学学报, 2015, 31(10): 1929-1937. doi: 10.11862/CJIC.2015.231 shu
Citation:  DING Fang-Fang, ZHANG Na, ZHANG Jian-Yong, WANG Min, GAO En-Qing. Two Low Dimensional Cd(Ⅱ) Coordination Polymers Constructed from Zwitterionic Dicarboxylate Ligand: Syntheses, Structures, and Fluorescent Properties[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(10): 1929-1937. doi: 10.11862/CJIC.2015.231 shu

两个由两性二酸配体构筑的Cd(Ⅱ)低维配合物的合成、结构及荧光性质

  • 1.

    1 上海应用技术学院材料科学与工程学院, 上海 201418;

  • 2.

    2 电磁散射重点实验室, 上海 200438;

  • 3.

    3 华东师范大学, 上海市绿色化学与化工过程绿色化重点实验室, 上海 200062

    • 通讯作者: 张建勇,E-mail:jianyong1106@163.com
  • 基金项目:

    上海市自然科学基金(No.14ZR1447900) (No.14ZR1447900)

    校复合材料学科建设项目(No.10210Q140001)资助。 (No.10210Q140001)

摘要: 利用合成的两性离子二酸配体1-(4-carboxylatobenzyl)pyridinium-4-carboxylate(HL),通过调变合成条件,制备了2个低维的配合物{Cd(L)2·4H2O}n(1),和{[Cd(L)(N3)]·3H2O}n(2),并对其进行了元素分析(EA)、红外光谱(IR)、热重(TG)、荧光光谱及X-射线单晶衍射测定。分析结果显示化合物1中八配位的Cd(Ⅱ)离子被4个L配体连接形成一维链状结构。而化合物2中六配位的Cd(Ⅱ)离子被双羧基-叠氮三重桥联形成二维层状结构。固体荧光测试表明配体的配位方式明显影响其荧光发射。

English

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  • 收稿日期:  2015-01-27
  • 网络出版日期:  2015-06-04
通讯作者: 陈斌, bchen63@163.com
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