咪唑-芳香多羧酸金属有机骨架化合物的合成、结构及性质

引用本文: 钱岩涛, 彭烨栋, 章文伟. 咪唑-芳香多羧酸金属有机骨架化合物的合成、结构及性质[J]. 无机化学学报, 2015, (5): 857-864. doi: 10.11862/CJIC.2015.148 shu

Citation: QIAN Yan-Tao, PENG Ye-Dong, ZHANG Wen-Wei. Syntheses, Structures and Properties of Metal-Organic Frameworks Based on Imidazolyl-Aromatic Multi-Carboxylate Acid Ligands[J]. Chinese Journal of Inorganic Chemistry, 2015, (5): 857-864. doi: 10.11862/CJIC.2015.148 shu

咪唑-芳香多羧酸金属有机骨架化合物的合成、结构及性质

1.
配位化学国家重点实验室, 南京大学化学化工学院, 南京 210093

通讯作者: 章文伟 wwzhang@nju.edu.cn

基金项目:
国家自然科学基金(No.51173075)资助项目。 (No.51173075)

摘要: 以5-(1H-咪唑)异酞酸(H₂L)为配体,在水热条件下合成了3个金属有机框架化合物:[PrL(HL)(H₂O)₂]·H₂O(1),Er(H_0.5L)₂(2)和[CoL(H₂O)₂]·H₂O(3)。单晶X-射线衍射测试结果表明,3个化合物都属于单斜晶系,P2₁/c空间群。化合物1中,Pr³⁺为九配位,而化合物2和3中,Er³⁺和Co²⁺均为六配位。在镧系配合物1和2中,配体中氮原子未参与配位。1为2D折叠形结构,2为3D框架结构。在过渡金属配合物3中,氮原子与Co²⁺配位,这有助于形成平面二维结构。化合物1和3通过分子间π-π堆积,进一步形成3D结构。3个化合物均展现出较好的热稳定性。

关键词:

金属有机骨架化合物;过渡金属;镧系元素;水热合成;晶体结构

English

Syntheses, Structures and Properties of Metal-Organic Frameworks Based on Imidazolyl-Aromatic Multi-Carboxylate Acid Ligands

1.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Corresponding author: 章文伟 wwzhang@nju.edu.cn

Received Date: 27 January 2015
Fund Project:
国家自然科学基金(No.51173075)资助项目。

Abstract: Three metal-organic frameworks, namely [PrL(HL)(H₂O)₂]·H₂O (1), Er(H_0.5L)₂ (2), and [CoL(H₂O)₂]·H₂O (3) (H₂L=5-(1H-imidazol-1-yl)isophthalic acid), have been synthesized under hydrothermal condition. Single crystal X-ray diffraction indicates that all the three complexes belong to the monoclinic space group P2₁/c. The Pr³⁺ ions in 1 are nine-coordinated, while the Er³⁺ ions in 2 and Co²⁺ ions in 3 are both six-coordinated. In the lanthanide complex 1 and 2, the nitrogen atom does not coordinate with any metal ions. Complex 1 shows a 2D folding framework, while complex 2 exhibits a 3D network. In the transition metal complex 3, the nitrogen atom coordinates with Co²⁺, which helps to form a flat 2D framework. Complex 1 and 3 are further packed into 3D framework by the intermolecular π-π interactions. All the three complexes display good thermal stability.

Key words:

metal-organic framework;transition metal;lanthanide;hydrothermal synthesis;crystal structure

1. [1] (a)Zheng B S, Bai J F, Duan J G, et al. J. Am. Chem. Soc., 2011,133:748-751[1] (a)Zheng B S, Bai J F, Duan J G, et al. J. Am. Chem. Soc., 2011,133:748-751
2. [2]
  (b)Lu Z Z, Zhang R, Li Y Z, et al. J. Am. Chem. Soc., 2011, 133:4172-4174(b)Lu Z Z, Zhang R, Li Y Z, et al. J. Am. Chem. Soc., 2011, 133:4172-4174
3. [3]
  (c)Kim M, Cahill J F, Fei H H, et al. J. Am. Chem. Soc., 2012,134:18082-18088(c)Kim M, Cahill J F, Fei H H, et al. J. Am. Chem. Soc., 2012,134:18082-18088
4. [4]
  (d)Kumar R, Kumar S, Kulandainathan M. Microporous Mesoporous Mater., 2013,168:57-64(d)Kumar R, Kumar S, Kulandainathan M. Microporous Mesoporous Mater., 2013,168:57-64
5. [5]
  (e)Mishra P, Edubilli S, Mandal B, et al. Microporous Mesoporous Mater., 2013,169:75-80(e)Mishra P, Edubilli S, Mandal B, et al. Microporous Mesoporous Mater., 2013,169:75-80
6. [2] (a)Zhang J P, Huang X C, Chen X M. Chem. Soc. Rev., 2009,38:2385-2396[2] (a)Zhang J P, Huang X C, Chen X M. Chem. Soc. Rev., 2009,38:2385-2396
7. [7]
  (b)Hu Y X, Ma H B, Zheng B, et al. Inorg. Chem., 2012,51: 7066-7074(b)Hu Y X, Ma H B, Zheng B, et al. Inorg. Chem., 2012,51: 7066-7074
8. [8]
  (c)Chen M, Bai Z S, Liu Q, et al. CrystEngComm, 2012,14: 8642-8648(c)Chen M, Bai Z S, Liu Q, et al. CrystEngComm, 2012,14: 8642-8648
9. [3] (a)Kawano M, Kawamichi T, Haneda T, et al. J. Am. Chem. Soc., 2007,129:15418-15419[3] (a)Kawano M, Kawamichi T, Haneda T, et al. J. Am. Chem. Soc., 2007,129:15418-15419
10. [10]
  (b)Wang Y T, Fan H H, Wang H Z, et al. Inorg. Chem., 2005, 44:4148-4150(b)Wang Y T, Fan H H, Wang H Z, et al. Inorg. Chem., 2005, 44:4148-4150
11. [11]
  (c)Carlucci L, Ciani G, Proserpio D, et al. New J. Chem., 2003,27:483-489(c)Carlucci L, Ciani G, Proserpio D, et al. New J. Chem., 2003,27:483-489
12. [12]
  (d)Shin D M, Lee I S, Cho D, et al. Inorg. Chem., 2003,42: 7722-7724(d)Shin D M, Lee I S, Cho D, et al. Inorg. Chem., 2003,42: 7722-7724
13. [4] (a)Mahata P, Sundaresan A, Natarajan S. Chem. Commun., 2007:4471-4473[4] (a)Mahata P, Sundaresan A, Natarajan S. Chem. Commun., 2007:4471-4473
14. [14]
  (b)Zhang J J, Wojtas L, Larsen R, et al. J. Am. Chem. Soc., 2009,131:17040-17041(b)Zhang J J, Wojtas L, Larsen R, et al. J. Am. Chem. Soc., 2009,131:17040-17041
15. [15]
  (c)Wu S T, Long L S, Huang R B, et al. Cryst. Growth Des., 2007,7:1746-1752(c)Wu S T, Long L S, Huang R B, et al. Cryst. Growth Des., 2007,7:1746-1752
16. [16]
  (d)Zhu X, Sun P P, Ding J G, et al. Cryst. Growth Des., 2012,12:3992-3997(d)Zhu X, Sun P P, Ding J G, et al. Cryst. Growth Des., 2012,12:3992-3997
17. [17]
  (e)Qin L, Hu J, Zhang M, et al. Cryst. Growth Des., 2013,13: 2111-2117(e)Qin L, Hu J, Zhang M, et al. Cryst. Growth Des., 2013,13: 2111-2117
18. [5] (a)Chen S S, Chen M, Takamizawa S, et al. Chem. Commun., 2011,47:4902-4904[5] (a)Chen S S, Chen M, Takamizawa S, et al. Chem. Commun., 2011,47:4902-4904
19. [19]
  (b)Liu W, Yu J, Jiang J, et al. CrystEngComm, 2011,13:2764-2773(b)Liu W, Yu J, Jiang J, et al. CrystEngComm, 2011,13:2764-2773
20. [20]
  (c)Zhang J, Cheng S, Wang X, et al. CrystEngComm, 2013, 15:6074-6082(c)Zhang J, Cheng S, Wang X, et al. CrystEngComm, 2013, 15:6074-6082
21. [6] (a)Li S L, Tan K, Lan Y Q, et al. Cryst. Growth Des., 2010, 10:1699-1705[6] (a)Li S L, Tan K, Lan Y Q, et al. Cryst. Growth Des., 2010, 10:1699-1705
22. [22]
  (b)Cui P, Ren L J, Chen Z, et al. Inorg. Chem., 2012,51: 2303-2310(b)Cui P, Ren L J, Chen Z, et al. Inorg. Chem., 2012,51: 2303-2310
23. [23]
  (c)Jiang H L, Tatsu Y, Lu Z H, et al. J. Am. Chem. Soc., 2010,132:5586-5587(c)Jiang H L, Tatsu Y, Lu Z H, et al. J. Am. Chem. Soc., 2010,132:5586-5587
24. [24]
  (d)Zhang Q A, Zhang J Y, Yu Q Y, et al. Cryst. Growth Des., 2010,10:4076-4084(d)Zhang Q A, Zhang J Y, Yu Q Y, et al. Cryst. Growth Des., 2010,10:4076-4084
25. [7] (a)Eddaoudi M, Li H, Yaghi O M. J. Am. Chem. Soc., 2000, 122:1391-1397[7] (a)Eddaoudi M, Li H, Yaghi O M. J. Am. Chem. Soc., 2000, 122:1391-1397
26. [26]
  (b)Eddaoudi M, Kim J, Rosi N, et al. Science, 2002,295: 469-472(b)Eddaoudi M, Kim J, Rosi N, et al. Science, 2002,295: 469-472
27. [27]
  (c)Chae H, Siberio-Pérez D, Kim J, et al. Nature, 2004,427: 523-527(c)Chae H, Siberio-Pérez D, Kim J, et al. Nature, 2004,427: 523-527
28. [28]
  (d)Millward A, Yaghi O M. J. Am. Chem. Soc., 2005,127: 17998-17999(d)Millward A, Yaghi O M. J. Am. Chem. Soc., 2005,127: 17998-17999
29. [8] (a)Chen B, Ockwig N, Millward A, et al. Angew. Chem. Int. Ed., 2005,44:4745-4749[8] (a)Chen B, Ockwig N, Millward A, et al. Angew. Chem. Int. Ed., 2005,44:4745-4749
30. [30]
  (b)Zhang J P, Chen X M. J. Am. Chem. Soc., 2008,130: 6010-6017(b)Zhang J P, Chen X M. J. Am. Chem. Soc., 2008,130: 6010-6017
31. [31]
  (c)Hu Y X, Xiang S C, Zhang W W, et al. Chem. Commun., 2009:7551-7553(c)Hu Y X, Xiang S C, Zhang W W, et al. Chem. Commun., 2009:7551-7553
32. [32]
  (d)Tian D, Pang Y, Zhou Y H, et al. CrystEngComm, 2011, 13:957-966(d)Tian D, Pang Y, Zhou Y H, et al. CrystEngComm, 2011, 13:957-966
33. [33]
  (e)Wang L F, Kang L C, Zhang W W, et al. Dalton Trans., 2011,40:9490-9497(e)Wang L F, Kang L C, Zhang W W, et al. Dalton Trans., 2011,40:9490-9497
34. [9] (a)Chen S S, Lü G C, Fan J, et al. Cryst. Growth Des., 2011, 11:1082-1090[9] (a)Chen S S, Lü G C, Fan J, et al. Cryst. Growth Des., 2011, 11:1082-1090
35. [35]
  (b)Chen S S, Zhao Y, Fan J, et al. CrystEngComm, 2012,14: 3564-3576(b)Chen S S, Zhao Y, Fan J, et al. CrystEngComm, 2012,14: 3564-3576
36. [10] Cui K H, Yao S Y, Li H Q, et al. CrystEngComm, 2011,13: 3432-3437[10] Cui K H, Yao S Y, Li H Q, et al. CrystEngComm, 2011,13: 3432-3437
37. [11] Software Packages SMART and SAINT, Siemens Analytical X-ray Instrument Inc., Madison: WI, 1996.[11] Software Packages SMART and SAINT, Siemens Analytical X-ray Instrument Inc., Madison: WI, 1996.
38. [12] Sheldrick G M. SHELX-97, Program for the Refinement of Crystal Structure, University of Göttingen, Göttingen, Germany, 1997.[12] Sheldrick G M. SHELX-97, Program for the Refinement of Crystal Structure, University of Göttingen, Göttingen, Germany, 1997.
39. [13] Carter K, Pope S, Cahill C. CrystEngComm, 2014,16:1873-1884[13] Carter K, Pope S, Cahill C. CrystEngComm, 2014,16:1873-1884
40. [14] Zhou X Y, Guo Y L, Shi Z H, et al. Dalton Trans., 2012,41: 1765-1775[14] Zhou X Y, Guo Y L, Shi Z H, et al. Dalton Trans., 2012,41: 1765-1775

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

咪唑-芳香多羧酸金属有机骨架化合物的合成、结构及性质

通讯作者: 章文伟 wwzhang@nju.edu.cn

English

Syntheses, Structures and Properties of Metal-Organic Frameworks Based on Imidazolyl-Aromatic Multi-Carboxylate Acid Ligands

Corresponding author: 章文伟 wwzhang@nju.edu.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

咪唑-芳香多羧酸金属有机骨架化合物的合成、结构及性质

通讯作者: 章文伟 wwzhang@nju.edu.cn

English

Syntheses, Structures and Properties of Metal-Organic Frameworks Based on Imidazolyl-Aromatic Multi-Carboxylate Acid Ligands

Corresponding author: 章文伟 wwzhang@nju.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

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