一种水杨醛异烟酰腙及其锌配位聚合物的合成、晶体结构和荧光性质

引用本文: 陈延民, 储召华, 郝桂霞, 解庆范. 一种水杨醛异烟酰腙及其锌配位聚合物的合成、晶体结构和荧光性质[J]. 无机化学学报, 2015, (2): 317-322. doi: 10.11862/CJIC.2015.044 shu

Citation: CHEN Yan-Min, CHU Zhao-Hua, HAO Gui-Xia, XIE Qing-Fan. Syntheses, Crystal Structures and Fluorescence Properties of a Hydrazone Schiff Base and its Zinc Coordination Polymer[J]. Chinese Journal of Inorganic Chemistry, 2015, (2): 317-322. doi: 10.11862/CJIC.2015.044 shu

一种水杨醛异烟酰腙及其锌配位聚合物的合成、晶体结构和荧光性质

陈延民 ^1, ,
储召华 ^{2,
,} ,
郝桂霞 ^2, ,
解庆范 ^1,

1.
1. 泉州师范学院化学与生命科学学院, 泉州 362000;
2.
2. 韩山师范学院化学系, 潮州 521041

通讯作者: 储召华, E-mail:hszhchu@126.com

基金项目:
福建省教育厅A类重点项目(No.JA14261) (No.JA14261)

广东省科技厅科技项目(No.2011B090400521)资助 (No.2011B090400521)

摘要: 合成了一种酰腙类Schiff碱4-(二乙胺基)水杨醛异烟酰腙(H₂L·H₂O,1)并制备了它的锌配合物[Zn(L)(Phen)]_∞(2),用元素分析、红外光谱、紫外光谱、荧光光谱和X-射线单晶衍射分析等手段进行了表征.1的晶体属三斜晶系,P1空间群,晶胞参数a=0.71058(4)nm,b=1.0045(2)nm,c=1.3054(3)nm,α=97.383(11)°,β=102.989(12)°,γ=104.038(10)°,V=8.641(3)nm³,Z=2;分子间通过氢键作用形成一维链超分子体系.2的晶体属三方晶系,P3₁空间群,晶胞参数a=1.68654(12)nm,b=1.68654(12)nm,c=0.79656(12)nm,V=1.9622(5)nm³,Z=3;配合物结构基元由1个锌离子、1个菲咯啉和1个酰腙组成,通过吡啶环的桥联作用形成一种双螺旋状配位聚合物.1和2都能发射绿色荧光,最大发射波长分别为524和535nm.

关键词:

锌配合物;晶体结构;荧光性质;水杨醛;异烟酰腙

English

Syntheses, Crystal Structures and Fluorescence Properties of a Hydrazone Schiff Base and its Zinc Coordination Polymer

1.
1. College of Chemistry and Life Science, Quanzhou Normal University, Quanzhou, Fujian 362000, China;
2.
2. Department of Chemistry, HanShan Normal University, Chaozhou, Guangdong 521041, China

Corresponding author: 储召华, E-mail:hszhchu@126.com

Received Date: 08 October 2014
Fund Project:
福建省教育厅A类重点项目(No.JA14261)

广东省科技厅科技项目(No.2011B090400521)资助

Abstract: Ahydrazone Schiff base monohydrate, C₁₇H₂₀N₄O₂·H₂O (1), was synthesized by rection of 4-diethylamino -salicylaldehyde and isoniazide, and its zinc(Ⅱ) coordination polymer, [Zn(L)(Phen)]_∞ (2) with double helix structure, was prepared. They have been characterized by elemental analysis, IR, UV-vis spectra and X-ray diffraction single crystal analysis and the fluorescence property of the compounds were investigated, which result showed that the crystal of 1 belongs to the triclinic system,space group P1 with cell parameters a=0.71058(4) nm, b=1.0045(2) nm, c=1.3054(3) nm, α=97.383(11)°, β=102.989(12)°, γ=104.038(10)°, V=8.641(3) nm³, Z=2, M_r=330.39, D_c=1.270 g·cm^-3 and the crystal of 2 belongs to the trigonal system,space group P₃₂ with cell parameters a=1.68654(12) nm, b=1.68654(12) nm, c=0.79656(12) nm, V=1.9622(5) nm³, Z=3, M_r=555.93, D_c=1.411 g·cm^-3. The compounds 1 and 2 exhibit luminescence with emission maximum at 524 and 535 nm at room temperature, respectively. CCDC: 995121, 1; 994066, 2.

Key words:

zinc complex;crystal structure;fluorescence properties;salicylaldehyde;isonicotinoyl hydrazone

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沈阳化工大学材料科学与工程学院沈阳 110142

一种水杨醛异烟酰腙及其锌配位聚合物的合成、晶体结构和荧光性质

通讯作者: 储召华, E-mail:hszhchu@126.com

English

Syntheses, Crystal Structures and Fluorescence Properties of a Hydrazone Schiff Base and its Zinc Coordination Polymer

Corresponding author: 储召华, E-mail:hszhchu@126.com

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

一种水杨醛异烟酰腙及其锌配位聚合物的合成、晶体结构和荧光性质

通讯作者: 储召华, E-mail:hszhchu@126.com

English

Syntheses, Crystal Structures and Fluorescence Properties of a Hydrazone Schiff Base and its Zinc Coordination Polymer

Corresponding author: 储召华, E-mail:hszhchu@126.com

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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