注册 English

一个双核β-二酮镝(Ⅲ)配合物的超声化学合成、晶体结构和磁性

刘彩明* ,  黄光熙 ,  熊明

downloadPDF
引用本文: 刘彩明*, 黄光熙, 熊明. 一个双核β-二酮镝(Ⅲ)配合物的超声化学合成、晶体结构和磁性[J]. 无机化学学报, 2014, 30(1): 93-98. doi: 10.11862/CJIC.2014.080 shu
Citation:  LIU Cai-Ming*, HUANG Guang-Xi, XIONG Ming. Ultrasonic Synthesis, Crystal Structure and Magnetic Properties of a Dinuclear Dysprosium(Ⅲ) β-Diketonate Complex[J]. Chinese Journal of Inorganic Chemistry, 2014, 30(1): 93-98. doi: 10.11862/CJIC.2014.080 shu

一个双核β-二酮镝(Ⅲ)配合物的超声化学合成、晶体结构和磁性

  • 基金项目:

    国家自然科学基金（No.90922016）；中央高校基本科研业务费专项资金（No.WK2060190020）资助项目。 

摘要: 用超声波辅助的方法合成得到了一个双核β-二酮镝配合物Dy2(Hpdm)2(dbm)4·2EtOH(1)(H2pdm=2，6-吡啶二甲醇，Hdbm=二苯甲酰甲烷)。单晶X-射线衍射结构分析表明双核镝(Ⅲ)结构单元通过2，6-吡啶二甲醇配体中去质子化的羟基氧原子桥联，每个镝(Ⅲ)离子呈现不规则的八面体配位构型。磁学性质研究表明，该配合物中镝(Ⅲ)离子之间存在着反铁磁性耦合作用，但没有出现磁驰豫行为。

English

    1. [1] Woodruff D N, Winpenny R E P, Layeld R A. Chem. Rev., 2013,113:5110-5148[1] Woodruff D N, Winpenny R E P, Layeld R A. Chem. Rev., 2013,113:5110-5148

    2. [2] Benelli C, Gatteschi D. Chem. Rev., 2002,102:2369-2388[2] Benelli C, Gatteschi D. Chem. Rev., 2002,102:2369-2388

    3. [3] Binnemans K. Chem. Rev., 2009,109:4283-4374[3] Binnemans K. Chem. Rev., 2009,109:4283-4374

    4. [4] Tsukube H, Shinoda S. Chem. Rev., 2002,102:2389-2404[4] Tsukube H, Shinoda S. Chem. Rev., 2002,102:2389-2404

    5. [5] YOU Xiao-Zeng(游效曾). Molecular-based Materials- Opto-electronic Functional Compounds(分子材料:光电功能 化合物). Shanghai: Shanghai Scientific & Technical Publishers, 2001.[5] YOU Xiao-Zeng(游效曾). Molecular-based Materials- Opto-electronic Functional Compounds(分子材料:光电功能 化合物). Shanghai: Shanghai Scientific & Technical Publishers, 2001.

    6. [6] CHEN Fang-Fang(陈芳芳), BIAN Zhu-Qiang(卞祖强), HUANG Chun-Hui(黄春辉). J. Chin. Soc. Rare Earth (中国 稀土学报), 2007,25:385-395[6] CHEN Fang-Fang(陈芳芳), BIAN Zhu-Qiang(卞祖强), HUANG Chun-Hui(黄春辉). J. Chin. Soc. Rare Earth (中国 稀土学报), 2007,25:385-395

    7. [7] ZHU Yu-Cheng(朱玉成), LI Hong-Yan（李红岩), XU Qiu- Lei（徐秋蕾), et al. Chinese J. Inorg. Chem. (无机化学学报), 2011,27:1491-1496[7] ZHU Yu-Cheng(朱玉成), LI Hong-Yan（李红岩), XU Qiu- Lei（徐秋蕾), et al. Chinese J. Inorg. Chem. (无机化学学报), 2011,27:1491-1496

    8. [8] Liu C M, Zuo J L, Zhang D Q, et al. CrystEngComm, 2008,10:1674-1680[8] Liu C M, Zuo J L, Zhang D Q, et al. CrystEngComm, 2008,10:1674-1680

    9. [9] Liu C M, Xiong M, Zhang D Q, et al. Dalton Trans., 2009:5666-5672[9] Liu C M, Xiong M, Zhang D Q, et al. Dalton Trans., 2009:5666-5672

    10. [10] Liu C M, Zhang D Q, Zhu D B. Dalton Trans., 2010,39: 11325-11328[10] Liu C M, Zhang D Q, Zhu D B. Dalton Trans., 2010,39: 11325-11328

    11. [11] Liu C M, Zhang D Q, Hao X, et al. Crystal Growth & Des., 2012,12:2948-2954[11] Liu C M, Zhang D Q, Hao X, et al. Crystal Growth & Des., 2012,12:2948-2954

    12. [12] Li X L, Chen C L, Gao Y L, et al. Chem. Eur. J., 2012, 18:14632-14637[12] Li X L, Chen C L, Gao Y L, et al. Chem. Eur. J., 2012, 18:14632-14637

    13. [13] Liu C M, Zhang D Q, Zhu D B. Inorg. Chem., 2013,52: 8933-8940[13] Liu C M, Zhang D Q, Zhu D B. Inorg. Chem., 2013,52: 8933-8940

    14. [14] Liu C M, Zhang D Q, Zhu D B. Dalton Trans., 2013,42: 14813-4818[14] Liu C M, Zhang D Q, Zhu D B. Dalton Trans., 2013,42: 14813-4818

    15. [15] Bernot K, Luzon J, Bogani L, et al. J. Am. Chem. Soc., 2009,131:5573-5579[15] Bernot K, Luzon J, Bogani L, et al. J. Am. Chem. Soc., 2009,131:5573-5579

    16. [16] Li D P, Wang T W, Li C H, et al. Chem. Commun., 2010,46:2929-2931[16] Li D P, Wang T W, Li C H, et al. Chem. Commun., 2010,46:2929-2931

    17. [17] Liu J, Zhang X P, Wu T. Inorg. Chem., 2012,51:8649- 8651[17] Liu J, Zhang X P, Wu T. Inorg. Chem., 2012,51:8649- 8651

    18. [18] Li D P, Zhang X P, Wang T W, et al. Chem. Commun., 2011,47:6867-6869[18] Li D P, Zhang X P, Wang T W, et al. Chem. Commun., 2011,47:6867-6869

    19. [19] Jiang S D, Wang B W, Su G, et al. Angew. Chem. Int. Ed., 2010,49:7448-7451[19] Jiang S D, Wang B W, Su G, et al. Angew. Chem. Int. Ed., 2010,49:7448-7451

    20. [20] Chen G J, Guo Y N, Tian J L, et al. Chem. Eur. J., 2012,18: 2484-2487[20] Chen G J, Guo Y N, Tian J L, et al. Chem. Eur. J., 2012,18: 2484-2487

    21. [21] Bi Y, Guo Y N, Zhao L, et al. Chem. Eur. J., 2011, 17: 12476-12481[21] Bi Y, Guo Y N, Zhao L, et al. Chem. Eur. J., 2011, 17: 12476-12481

    22. [22] Menelaou M, Ouharrou F, Rodríguez L, et al. Chem. Eur. J., 2012,18:11545-11549[22] Menelaou M, Ouharrou F, Rodríguez L, et al. Chem. Eur. J., 2012,18:11545-11549

    23. [23] Lennartson A, Vestergren M, Håkansson M. Chem. Eur. J., 2005,11:1757-1762[23] Lennartson A, Vestergren M, Håkansson M. Chem. Eur. J., 2005,11:1757-1762

    24. [24] Sheldrick G M. SHELX 97. University of Goettingen, Goettingen, 1997.[24] Sheldrick G M. SHELX 97. University of Goettingen, Goettingen, 1997.

    25. [25] NI Jun(倪钧), GENG Jin-Long(耿金龙), QI Wen-Bin (戚文斌), et al. Chinese J. Inorg. Chem. (无机化学学报), 2001,17:713-717[25] NI Jun(倪钧), GENG Jin-Long(耿金龙), QI Wen-Bin (戚文斌), et al. Chinese J. Inorg. Chem. (无机化学学报), 2001,17:713-717

    26. [26] Murugesu M, Mishra A, Wernsdorfer W, et al. Polyhedron, 2006,25:613-625[26] Murugesu M, Mishra A, Wernsdorfer W, et al. Polyhedron, 2006,25:613-625

    27. [27] Zhao X Q, Lan Y H, Zhao B, et al. Dalton Trans., 2010,39: 4911-4917[27] Zhao X Q, Lan Y H, Zhao B, et al. Dalton Trans., 2010,39: 4911-4917

    28. [28] Yang P P, Gao S F, Song H B, et al. Inorg. Chem., 2011,50: 720-722[28] Yang P P, Gao S F, Song H B, et al. Inorg. Chem., 2011,50: 720-722

    29. [29] van Staveren D R, van Albada G A, Gorter S, et al. Inorg. Chem. Acta, 2000,300:1104-1108[29] van Staveren D R, van Albada G A, Gorter S, et al. Inorg. Chem. Acta, 2000,300:1104-1108

    30. [30] Drew M G B. Coord. Chem. Rev., 1977,24:179-275[30] Drew M G B. Coord. Chem. Rev., 1977,24:179-275

    31. [31] Gamer M T, Lan Y, Roesky P W, et al. Inorg. Chem., 2008,47:6581-6583[31] Gamer M T, Lan Y, Roesky P W, et al. Inorg. Chem., 2008,47:6581-6583

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  724
  • 文章访问数:  1863
  • HTML全文浏览量:  216
文章相关
  • 收稿日期:  2013-08-13
  • 网络出版日期:  2013-11-13
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net