长碳链聚酰胺及其共聚物的拉伸诱导结晶

引用本文: 王莉莉, 朱平, 董侠, 王笃金. 长碳链聚酰胺及其共聚物的拉伸诱导结晶[J]. 高分子学报, 2020, 51(1): 1-11. doi: 10.11777/j.issn1000-3304.2020.19165 shu

Citation: Li-li Wang, Ping Zhu, Xia Dong, Du-jin Wang. Strain-induced Crystallization of Long Chain Polyamide and Its Copolymers[J]. Acta Polymerica Sinica, 2020, 51(1): 1-11. doi: 10.11777/j.issn1000-3304.2020.19165 shu

长碳链聚酰胺及其共聚物的拉伸诱导结晶

王莉莉 ^1,2, ,
朱平 ^1, ,
董侠 ^{1,3,
,} ,
王笃金 ^1,3,

1.
中国科学院化学研究所中国科学院工程塑料重点实验室北京分子科学国家研究中心　北京 100190
2.
青岛大学生物多糖纤维成形与生态纺织国家重点实验室海洋纤维新材料研究院　青岛 266071
3.
中国科学院大学　北京 100049

作者简介:

董侠，女，1973年生. 中国科学院化学研究所研究员，博士生导师. 2001年于东华大学获得博士学位，2001 ~ 2003年在中国科学院化学研究所从事博士后研究，2009 ~ 2010年在美国阿克伦大学做访问学者. 从事长碳链聚酰胺等高分子材料的聚合关键技术、结构与性能、材料加工及改性的应用基础研究与工业化转化，在生物发酵法原料来源的长碳链聚酰胺及其弹性体材料的研究与工程化领域取得重要进展. 已发表学术论文150余篇，授权中国发明专利41项，曾获上海市科技进步一等奖(2017年)、中国化学会高分子科学创新论文奖(2017年)、中国科学院科技促进发展奖科技贡献二等奖(2014年)、北京市科学技术一等奖(2009年)、冯新德高分子奖(2009，2019年)等奖励;

通讯作者: E-mail: xiadong@iccas.ac.cn

摘要: 长碳链聚酰胺(LCPA)作为聚酰胺的特殊品种，较长的亚甲基链和极性酰胺基团使其兼具聚烯烃和聚酰胺的双重特性. 在加工或使用过程中，拉伸诱导结晶现象对长碳链聚酰胺及其共聚物的强度和弹性行为具有重要影响，深入认识其在外场下的微观结构响应对该材料的设计及制备具有重要意义. 围绕拉伸诱导结晶作用，该专论主要基于本团队2010年以来在长碳链聚酰胺及其共聚物的拉伸诱导结晶工作，并综述了国内外的相关研究，涉及拉伸诱导结晶现象、拉伸诱导结晶的影响因素、拉伸诱导结晶与力学性能的构效关系及拉伸诱导结晶的表征方法等方面.

关键词:

English

Strain-induced Crystallization of Long Chain Polyamide and Its Copolymers

1.
Beijing National Laboratory for Molecular Science, CAS Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190
2.
State Key Laboratory of Bio-Fibers and Eco-Textiles, Institute of Marine Biobased Materials, Qingdao University, Qingdao 266071
3.
University of Chinese Academy of Sciences, Beijing 100049

Corresponding author: Xia Dong E-mail: xiadong@iccas.ac.cn

Received Date: 10 September 2019
Revised Date: 06 October 2019
Available Online: 01 January 2020

Abstract: As a special species of polyamide, long chain polyamide (LCPA) provides combined performances of polyolefin and polyamide due to its chemical structure with long methylene chains segments between two neighbor polar amide groups. During the processing or application, strain-induced crystallization (SIC) has a significant effect on the mechanical strength and elasticity of LCPA and LCPA based its copolymers. It is of great importance to further study the microstructural evolution mechanism for the design and production of LCPA and its copolymers under the external field. With a focus on the SIC, this feature article mainly summarizes our group’s work on SIC of LCPA since 2010 and some related studies of other researchers, including the phenomenon of SIC observed in LCPA and its copolymer, the influencing factors of SIC and the corresponding rules, the correlation between SIC and the mechanical properties, and the characterization technics as well.

Key words:

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

长碳链聚酰胺及其共聚物的拉伸诱导结晶

通讯作者: E-mail: xiadong@iccas.ac.cn

English

Strain-induced Crystallization of Long Chain Polyamide and Its Copolymers

Corresponding author: Xia Dong E-mail: xiadong@iccas.ac.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

长碳链聚酰胺及其共聚物的拉伸诱导结晶

通讯作者: E-mail: xiadong@iccas.ac.cn

English

Strain-induced Crystallization of Long Chain Polyamide and Its Copolymers

Corresponding author: Xia Dong E-mail: xiadong@iccas.ac.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs