可持续高分子-纤维素新材料研究进展

引用本文: 段博, 涂虎, 张俐娜. 可持续高分子-纤维素新材料研究进展[J]. 高分子学报, 2020, 51(1): 66-86. doi: 10.11777/j.issn1000-3304.2020.19160 shu

Citation: Bo Duan, Hu Tu, Li-na Zhang. Material Research Progress of the Sustainable Polymer-Cellulose[J]. Acta Polymerica Sinica, 2020, 51(1): 66-86. doi: 10.11777/j.issn1000-3304.2020.19160 shu

可持续高分子-纤维素新材料研究进展

段博 ^, ,
涂虎 ,
张俐娜 ^,

武汉大学化学与分子科学学院　武汉 430072

作者简介: 段博，男，1987年生，副研究员. 2015年毕业于武汉大学化学与分子科学学院并获得理学博士学位. 2016 ~ 2019年在美国斯托瓦斯研究所从事博士后工作，研究生殖干细胞分化微环境. 2019年6月进入武汉大学化学与分子科学学院从事天然高分子方面的研究工作. 主要研究方向为甲壳素、纤维素功能材料的开发;

张俐娜，女，1940年生，教授/博导，中国科学院院士. 1963年毕业于武汉大学化学系. 1985年曾获日本政府学术振兴协会奖学金(JSPS)赴大阪大学研究近2年. 1993年创立天然高分子科研组，2011年当选中国科学院院士，2014年为英国皇家化学会会士. 现任美国化学会刊物ACS Sustainable Chemistry & Engineering的副主编以及多家国内外刊物编委. 基础研究成果已在国内外刊物发表论文600余篇，其中560余篇发表在国际SCI源刊上，被他人引用近18000次；主编专著15部；获准专利100余项；荣获国家自然科学奖二等奖1项，省级自然科学一等奖1项及技术发明一等奖1项；获美国化学会2011年Anselme Payen奖(国际纤维素与可再生资源材料领域最高奖). 曾获全国优秀教师和全国先进工作者等国家级荣誉. 主要研究方向为高分子物理、天然高分子改性材料、复杂多糖的分子和链构象与其生物活性关系;

通讯作者: E-mail: bo_duan@whu.edu.cn; E-mail: zhangln@whu.edu.cn

摘要: 21世纪“绿色”化学已成为世界各国社会经济发展中的研究与开发战略方向. 纤维素是自然界中储量最丰富的天然高分子，是重要的可再生资源以及未来的主要工业原料. 然而由于纤维素存在着大量的分子内以及分子间氢键，其结构致密，难以溶解或熔融进一步加工. 本文简要介绍了近几年来关于直接使用物理溶剂方法(非衍生化)对纤维素材料开发利用的新进展，主要包括以下4个方面：(1)纤维素在“绿色”溶剂-碱/尿素以及离子液体体系中的溶解和再生；(2)纳米纤维素的制备以及组装；(3)木材纳米技术的开发及利用；(4)细菌纤维素基材料等，旨在推进“绿色”技术实现纤维素资源的研究开发及利用.

关键词:

English

Material Research Progress of the Sustainable Polymer-Cellulose

College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072

Corresponding author: Bo Duan, E-mail: bo_duan@whu.edu.cn; Li-na Zhang, E-mail: zhangln@whu.edu.cn

Received Date: 30 August 2019
Revised Date: 27 September 2019
Available Online: 01 January 2020

Abstract: The “Green Chemistry” has become the strategy direction of research and development of the world in the 21^th century. Cellulose, as the most abundant natural polymers, is a very important renewable resource and the main industrial raw material. The cellulose shows many great advances including biocompatibility, biodegradability, high structure stability. However, due to the large amounts of inter- and intra-hydrogen bonding among the cellulose molecules, the cellulose has a dense structure and is very hard to be processed through dissolution or melt, which limit the further exploitation of the cellulose resource. The traditional organic solution of the cellulose often has the problem of high cost and pollution. In recent decades, with the development of the “Green” solvent (alkaline/urea, ionic liquid, etc.) and the cellulose nanotechnology, the researchers have greatly expanded the cellulose application in biomedical, energy storage, optical fields in addition to the traditional spinning and papermaking industry. This review mainly introduces the new methods (“bottom to up” and “up to down”) for the exploitation of cellulose based materials in recent years through the following four sections: (1) the regenerated cellulose based materials from the “green” solution-alkaline/urea aqueous and ionic liquid; (2) the preparation and self-assembly of the nanocellulose; (3) the development and utilization of the wood nanotechnology; (4) bacterial cellulose based functional materials.

Key words:

1. [1]
  Chandhuri S. The Wall Street Journal @ Statista Charts, 2018-12-12
2. [2]
  Macarthur E. Science, 2017, 358(6365): 843 doi: 10.1126/science.aao6749
3. [3]
  Science, 2017, 358(6369): 1362 − 1363
4. [4]
  Lamb J B, Willis B L, Fiorenza E A, Couch C S, Howard R, Rader D N, True J D, Kelly L A, Ahmad A, Jompa J. Science, 2018, 359(6374): 460 − 462 doi: 10.1126/science.aar3320
5. [5]
  People’s Daily Overseas Edition, 2019-07-05
6. [6]
  Zhu Y, Romain C, Williams C K. Nature, 2016, 540: 354 − 362 doi: 10.1038/nature21001
7. [7]
  Smaglik P. Nature, 2000, 406: 807 − 808 doi: 10.1038/35021181
8. [8]
  Wang S, Lu A, Zhang L. Prog Polym Sci, 2016, 53: 169 − 206 doi: 10.1016/j.progpolymsci.2015.07.003
9. [9]
  Cai J, Zhang L, Liu S, Liu Y, Xu X, Chen X, Chu B, Guo X, Xu J, Cheng H, Han C C, Kuga S. Macromolecules, 2008, 41(23): 9345 − 9351 doi: 10.1021/ma801110g
10. [10]
  Jiang Z, Fang Y, Xiang J, Ma Y, Lu A, Kang H, Huang Y, Guo H, Liu R, Zhang L. J Phys Chem B, 2014, 118(34): 10250 − 10257 doi: 10.1021/jp501408e
11. [11]
  Wang S, Sun P, Liu M, Lu A, Zhang L. Phys Chem Chem Phys, 2017, 19(27): 17909 − 17917 doi: 10.1039/C7CP02514A
12. [12]
  Wang S, Sun P, Zhang R, Lu A, Liu M, Zhang L. Phys Chem Chem Phys, 2017, 19(11): 7486 − 7490 doi: 10.1039/C6CP08744B
13. [13]
  Wang Y, Liu L, Chen P, Zhang L, Lu A. Phys Chem Chem Phys, 2018, 20(20): 14223 − 14233 doi: 10.1039/C8CP01268G
14. [14]
  Ye D, Cheng Q, Zhang Q, Wang Y, Chang C, Li L, Peng H, Zhang L. ACS Appl Mater Interfaces, 2017, 9(49): 43154 − 43162 doi: 10.1021/acsami.7b14900
15. [15]
  Zhao D, Huang J, Zhong Y, Li K, Zhang L, Cai J. Adv Funct Mater, 2016, 26(34): 6279 − 6287 doi: 10.1002/adfm.201601645
16. [16]
  Ye D, Lei X, Li T, Cheng Q, Chang C, Hu L, Zhang L. ACS Nano, 2019, 13(4): 4843 − 4853 doi: 10.1021/acsnano.9b02081
17. [17]
  Ye D, Yang P, Lei X, Zhang D, Li L, Chang C, Sun P, Zhang L. Chem Mater, 2018, 30(15): 5175 − 5183 doi: 10.1021/acs.chemmater.8b01799
18. [18]
  Ye D, Chang C, Zhang L. Biomacromolecules, 2019, 20(5): 1989 − 1995 doi: 10.1021/acs.biomac.9b00204
19. [19]
  Zhu K, Qiu C, Lu A, Luo L, Guo J, Cong H, Chen F, Liu X, Zhang X, Wang H, Cai J, Fu Q, Zhang L. ACS Sustain Chem Eng, 2018, 6(4): 5314 − 5321 doi: 10.1021/acssuschemeng.8b00039
20. [20]
  Qiu C, Zhu K, Yang W, Wang Y, Zhang L, Chen F, Fu Q. Biomacromolecules, 2018, 19(11): 4386 − 4395 doi: 10.1021/acs.biomac.8b01262
21. [21]
  Xu D, Chen C, Xie J, Zhang B, Miao L, Cai J, Huang Y, Zhang L. Adv Energy Mater, 2016, 6(6): 1501929 doi: 10.1002/aenm.201501929
22. [22]
  Xu D, Fan L, Gao L, Xiong Y, Wang Y, Ye Q, Yu A, Dai H, Yin Y, Cai J, Zhang L. ACS Appl Mater Interfaces, 2016, 8(27): 17090 − 17097 doi: 10.1021/acsami.6b03555
23. [23]
  Dai L, Zhu W, Lu J, Kong F, Si C, Ni Y. Green Chem, 2019, 21(19): 5222 − 5230 doi: 10.1039/C1039GC01975H
24. [24]
  Swatloski R P, Spear S K, Holbrey J D, Rogers R D. J Am Chem Soc, 2002, 124(18): 4974 − 4975 doi: 10.1021/ja025790m
25. [25]
  Zhang H, Wu J, Zhang J, He J. Macromolecules, 2005, 38(20): 8272 − 8277 doi: 10.1021/ma0505676
26. [26]
  Raghuwanshi V S, Cohen Y, Garnier G, Garvey C J, Russell R A, Darwish T, Garnier G. Macromolecules, 2018, 51(19): 7649 − 7655 doi: 10.1021/acs.macromol.8b01425
27. [27]
  Liu H, Sale K L, Holmes B M, Simmons B A, Singh S. J Phys Chem B, 2010, 114(12): 4293 − 4301 doi: 10.1021/jp9117437
28. [28]
  Rabideau B D, Ismail A E. J Phys Chem B, 2012, 116(32): 9732 − 9743 doi: 10.1021/jp305469p
29. [29]
  Vitz J, Erdmenger T, Haensch C, Schubert U. Green Chem, 2009, 11(3): 417 − 424 doi: 10.1039/b818061j
30. [30]
  Mazza M, Catana D A, Vaca-Garcia C, Cecutti C J C. Cellulose, 2009, 16(2): 207 − 215 doi: 10.1007/s10570-008-9257-x
31. [31]
  Wan J, Zhang J, Yu J, Zhang J. ACS Appl Mater Interfaces, 2017, 9(29): 24591 − 24599 doi: 10.1021/acsami.7b06271
32. [32]
  Zhang J, Zhang H, Wu J, Zhang J, He J, Xiang J F. Phys Chem Chem Phys, 2010, 12: 1941 − 1947 doi: 10.1039/b920446f
33. [33]
  Luo N, Lv Y, Wang D, Zhang J, Wu J, He J, Zhang J. Chem Commun, 2012, 48: 6283 − 6285 doi: 10.1039/c2cc31483e
34. [34]
  Zhang J, Xu L, Yu J, Wu J, Zhang X, He J, Zhang J. Sci China Chem, 2016, 59: 1421 − 1429 doi: 10.1007/s11426-016-0269-5
35. [35]
  Liu J, Zhang J, Zhang B, Zhang X, Xu L, Zhang J, He J, Liu C Y. Cellulose, 2016, 23: 2341 − 2348 doi: 10.1007/s10570-016-0967-1
36. [36]
  Zhang J, Chen W, Feng Y, Wu J, Yu J, He J, Zhang J. Polym Int, 2015, 64: 963 − 970 doi: 10.1002/pi.4883
37. [37]
  Zhang J, Wu J, Yu J, Zhang X, He J, Zhang J. Mater Chem Front, 2017, 1: 1273 − 1290 doi: 10.1039/C6QM00348F
38. [38]
  Zhang J, Luo N, Zhang X, Xu L, Wu J, Yu J, He J, Zhang J. ACS Sustain Chem Eng, 2016, 4(8): 4417 − 4423 doi: 10.1021/acssuschemeng.6b01034
39. [39]
  Mi Q, Ma S-r, Yu J, He J, Zhang J. ACS Sustain Chem Eng, 2016, 4: 656 − 660 doi: 10.1021/acssuschemeng.5b01079
40. [40]
  Nguyen N A, Kim K, Bowland C C, Keum J K, Kearney L T, André N, Labbé N, Naskar A K. Green Chem, 2019, 21(16): 4354 − 4367 doi: 10.1039/C9GC00774A
41. [41]
  Yang S, Lu X, Zhang Y, Xu J, Xin J, Zhang S. Cellulose, 2018, 25(6): 3241 − 3254 doi: 10.1007/s10570-018-1785-4
42. [42]
  Shamshina J L, Zavgorodnya O, Choudhary H, Frye B, Newbury N, Rogers R D. ACS Sustain Chem Eng, 2018, 6(11): 14713 − 14722 doi: 10.1021/acssuschemeng.8b03269
43. [43]
  Fukuzumi H, Saito T, Iwata T, Kumamoto Y, Isogai A. Biomacromolecules, 2008, 10(1): 162 − 165
44. [44]
  Nogi M, Iwamoto S, Nakagaito A N, Yano H. Adv Mater, 2009, 21(16): 1595 − 1598 doi: 10.1002/adma.200803174
45. [45]
  Ansari F, Salajková M, Zhou Q, Berglund L A. Biomacromolecules, 2015, 16: 3916 − 3924 doi: 10.1021/acs.biomac.5b01245
46. [46]
  Kang X, Kuga S, Wang C, Zhao Y, Wu M, Huang Y. ACS Sustain Chem Eng, 2018, 6(3): 2954 − 2960 doi: 10.1021/acssuschemeng.7b02363
47. [47]
  Kang X, Sun P, Kuga S, Wang C, Zhao Y, Wu M, Huang Y. ACS Sustain Chem Eng, 2017, 5(3): 2529 − 2534 doi: 10.1021/acssuschemeng.6b02867
48. [48]
  Ci J, Cao C, Kuga S, Shen J, Wu M, Huang Y. ACS Sustain Chem Eng, 2017, 5(11): 9614 − 9618 doi: 10.1021/acssuschemeng.7b01970
49. [49]
  Saito T, Kimura S, Nishiyama Y, Isogai A. Biomacromolecules, 2007, 8(8): 2485 − 2491 doi: 10.1021/bm0703970
50. [50]
  De France K J, Hoare T, Cranston E D. Chem Mater, 2017, 29(11): 4609 − 4631 doi: 10.1021/acs.chemmater.7b00531
51. [51]
  Wicklein B, Kocjan A, Salazar-Alvarez G, Carosio F, Camino G, Antonietti M, Bergström L. Nat Nanotechnol, 2014, 10: 277 − 283
52. [52]
  Xiong R, Yu S, Smith M J, Zhou J, Krecker M, Zhang L, Nepal D, Bunning T J, Tsukruk V V. ACS Nano, 2019, 13(8): 9047 − 9081 doi: 10.1021/acsnano.1029b03305
53. [53]
  Markstedt K, Mantas A, Tournier I, Martínez Ávila H, Hägg D, Gatenholm P. Biomacromolecules, 2015, 16(5): 1489 − 1496 doi: 10.1021/acs.biomac.5b00188
54. [54]
  Lundahl M J, Klar V, Wang L, Ago M, Rojas O J. Ind Eng Chem Res, 2017, 56(1): 8 − 19 doi: 10.1021/acs.iecr.6b04010
55. [55]
  Richardson J J, Tardy B L, Guo J, Liang K, Rojas O J, Ejima H. ACS Sustain Chem Eng, 2019, 7(6): 6287 − 6294 doi: 10.1021/acssuschemeng.8b06713
56. [56]
  Voisin H, Bergström L, Liu P, Mathew A P J N. Nanomaterials, 2017, 7(3): 57 doi: 10.3390/nano7030057
57. [57]
  Zheng H, Li W, Li W, Wang X, Tang Z, Zhang S X A, Xu Y. Adv Mater, 2018, 30(13): 1705948 doi: 10.1002/adma.201705948
58. [58]
  Xu Y, Atrens A D, Stokes J R. Soft Matter, 2019, 15(8): 1716 − 1720 doi: 10.1039/C8SM02288G
59. [59]
  Chu G, Qu D, Zussman E, Xu Y. Chem Mater, 2017, 29(9): 3980 − 3988 doi: 10.1021/acs.chemmater.7b00361
60. [60]
  Hiratani T, Kose O, Hamad W Y, MacLachlan M J. Mater Horiz, 2018, 5(6): 1076 − 1081 doi: 10.1039/C8MH00586A
61. [61]
  Kaushik M, Basu K, Benoit C, Cirtiu C M, Vali H, Moores A. J Am Chem Soc, 2015, 137(19): 6124 − 6127 doi: 10.1021/jacs.5b02034
62. [62]
  Gu J, Hu C, Zhang W, Dichiara A B. Appl Catal B, 2018, 237: 482 − 490 doi: 10.1016/j.apcatb.2018.06.002
63. [63]
  Ellebracht N C, Jones C W. ACS Catal, 2019, 9(4): 3266 − 3277 doi: 10.1021/acscatal.8b05180
64. [64]
  Qin X, Xia W, Sinko R, Keten S. Nano Lett, 2015, 15(10): 6738 − 6744 doi: 10.1021/acs.nanolett.5b02588
65. [65]
  Biswas S K, Tanpichai S, Witayakran S, Yang X, Shams M I, Yano H. ACS Nano, 2019, 13(2): 2015 − 2023
66. [66]
  Zhu L, Zhou X, Liu Y, Fu Q. ACS Appl Mater Interfaces, 2019, 11(13): 12968 − 12977 doi: 10.1021/acsami.9b00136
67. [67]
  Wu K, Fang J, Ma J, Huang R, Chai S, Chen F, Fu Q. ACS Appl Mater Interfaces, 2017, 9(35): 30035 − 30045 doi: 10.1021/acsami.7b08214
68. [68]
  Yang W, Zhang Y, Liu T, Huang R, Chai S, Chen F, Fu Q. ACS Sustain Chem Eng, 2017, 5(10): 9102 − 9113 doi: 10.1021/acssuschemeng.7b02012
69. [69]
  Cheng Q, Ye D, Chang C, Zhang L. J Membr Sci, 2017, 525: 1 − 8 doi: 10.1016/j.memsci.2016.11.084
70. [70]
  Zhu L, Zong L, Wu X, Li M, Wang H, You J, Li C. ACS Nano, 2018, 12(5): 4462 − 4468 doi: 10.1021/acsnano.8b00566
71. [71]
  Zhu H, Yang X, Cranston E D, Zhu S. Adv Mater, 2016, 28(35): 7652 − 7657 doi: 10.1002/adma.201601351
72. [72]
  Song J, Chen C, Zhu S, Zhu M, Dai J, Ray U, Li Y, Kuang Y, Li Y, Quispe N, Yao Y, Gong A, Leiste U H, Bruck H A, Zhu J Y, Vellore A, Li H, Minus M L, Jia Z, Martini A, Li T, Hu L. Nature, 2018, 554(7691): 224 − 228 doi: 10.1038/nature25476
73. [73]
  Gan W, Chen C, Wang Z, Song J, Kuang Y, He S, Mi R, Sunderland P B, Hu L. Adv Funct Mater, 2019, 29(14): 1807444 doi: 10.1002/adfm.201807444
74. [74]
  Li T, Zhai Y, He S, Gan W, Wei Z, Heidarinejad M, Dalgo D, Mi R, Zhao X, Song J, Dai J, Chen C, Aili A, Vellore A, Martini A, Yang R, Srebric J, Yin X, Hu L. Science, 2019, 364(6442): 760 − 763 doi: 10.1126/science.aau9101
75. [75]
  Chen C, Zhang Y, Li Y, Dai J, Song J, Yao Y, Gong Y, Kierzewski I, Xie J, Hu L. Energy Environ Sci, 2017, 10: 538 − 545 doi: 10.1039/C6EE03716J
76. [76]
  Song H, Xu S, Li Y, Dai J, Hu L. Adv Energy Mater, 2017, 8(4): 1701203
77. [77]
  Xu S, Chen C, Kuang Y, Song J, Gan W, Liu B, Hitz E M, Connell J W, Lin Y, Hu L. Energy Environ Sci, 2018, 11(11): 3231 − 3237 doi: 10.1039/C8EE01468J
78. [78]
  He S, Chen C, Kuang Y, Mi R, Liu Y, Pei Y, Kong W, Gan W, Xie H, Hitz E, Jia C, Chen X, Gong A, Liao J, Li J, Ren Z J, Yang B, Das S, Hu L. Energy Environ Sci, 2019, 12(5): 1558 − 1567 doi: 10.1039/C9EE00945K
79. [79]
  Li T, Liu H, Zhao X, Chen G, Dai J, Pastel G, Jia C, Chen C, Hitz E, Siddhartha D, Yang R, Hu L. Adv Funct Mater, 2018, 28(16): 1707134 doi: 10.1002/adfm.201707134
80. [80]
  Zhu M, Li Y, Chen G, Jiang F, Yang Z, Luo X, Wang Y, Lacey S D, Dai J, Wang C, Jia C, Wan J, Yao Y, Gong A, Yang B, Yu Z, Das S, Hu L. Adv Mater, 2017, 29(44): 1704107 doi: 10.1002/adma.201704107
81. [81]
  Kuang Y, Chen C, He S, Hitz E M, Wang Y, Gan W, Mi R, Hu L. Adv Mater, 2019, 31(23): 1900498
82. [82]
  Picheth G F, Pirich C L, Sierakowski M R, Woehl M A, Sakakibara C N, de Souza C F, Martin A A, da Silva R, de Freitas R A. Int J Biol Macromol, 2017, 104: 97 − 106 doi: 10.1016/j.ijbiomac.2017.05.171
83. [83]
  Foresti M L, Vázquez A, Boury B. Carbohydr Polym, 2017, 157: 447 − 467 doi: 10.1016/j.carbpol.2016.09.008
84. [84]
  Wu Z Y, Liang H W, Chen L F, Hu B C, Yu S H. Acc Chem Res, 2016, 49(1): 96 − 105 doi: 10.1021/acs.accounts.5b00380
85. [85]
  Chen Z, Hu Y, Zhuo H, Liu L, Jing S, Zhong L, Peng X, Sun R C. Chem Mater, 2019, 31: 3301 − 3312 doi: 10.1021/acs.chemmater.9b00259
86. [86]
  Wang S, Jiang F, Xu X, Kuang Y, Fu K, Hitz E, Hu L. Adv Mater, 2017, 29(35): 1702498 doi: 10.1002/adma.201702498
87. [87]
  Liang H W, Wu Z Y, Chen L F, Li C, Yu S H. Nano Energy, 2015, 11: 366 − 376 doi: 10.1016/j.nanoen.2014.11.008
88. [88]
  Guan Q F, Han Z M, Luo T T, Yang H B, Liang H W, Chen S M, Wang G S, Yu S H J N S R. Natl Sci Rev, 2019, 6(1): 64 − 73 doi: 10.1093/nsr/nwy144
89. [89]
  Yang J, Wang L, Zhang W, Sun Z, Li Y, Yang M, Zeng D, Peng B, Zheng W, Jiang X, Yang G. Small, 2018, 14(7): 1702582 doi: 10.1002/smll.201702582
90. [90]
  Geisel N, Clasohm J, Shi X, Lamboni L, Yang J, Mattern K, Yang G, Schäfer K H, Saumer M. Small, 2016, 12(39): 5407 − 5413
91. [91]
  Schaffner M, Rühs P A, Coulter F, Kilcher S, Studart A. Sci Adv, 2017, 3: 6804 doi: 10.1126/sciadv.aao6804
92. [92]
  Yang J, Du M, Wang L, Li S, Wang G, Yang X, Zhang L, Fang Y, Zheng W, Yang G, Jiang X. ACS Appl Mater Interfaces, 2018, 10(39): 33049 − 33059 doi: 10.1021/acsami.8b12083
93. [93]
  Shi Z, Gao X, Ullah M W, Li S, Wang Q, Yang G. Biomaterials, 2016, 111: 40 − 54 doi: 10.1016/j.biomaterials.2016.09.020
94. [94]
  Li S, Huang D, Zhang B, Xu X, Wang M, Yang G, Shen Y. Adv Energy Mater, 2014, 4(10): 1301655 doi: 10.1002/aenm.201301655
95. [95]
  Li S, Huang D, Yang J, Zhang B, Zhang X, Yang G, Wang M, Shen Y. Nano Energy, 2014, 9: 309 − 317 doi: 10.1016/j.nanoen.2014.08.004
96. [96]
  Li Y, Tian Y, Zheng W, Feng Y, Huang R, Shao J, Tang R, Wang P, Jia Y, Zhang J, Zheng W, Yang G, Jiang X. Small, 2017, 13(27): 1700130 doi: 10.1002/smll.201700130
97. [97]
  Zhang B, Zhou J, Li S, Zhang X, Huang D, He Y, Wang M, Yang G, Shen Y. Talanta, 2015, 131: 243 − 248 doi: 10.1016/j.talanta.2014.07.027

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

可持续高分子-纤维素新材料研究进展

通讯作者: E-mail: bo_duan@whu.edu.cn; E-mail: zhangln@whu.edu.cn

English

Material Research Progress of the Sustainable Polymer-Cellulose

Corresponding author: Bo Duan, E-mail: bo_duan@whu.edu.cn; Li-na Zhang, E-mail: zhangln@whu.edu.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

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通讯作者: E-mail: bo_duan@whu.edu.cn; E-mail: zhangln@whu.edu.cn

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Corresponding author: Bo Duan, E-mail: bo_duan@whu.edu.cn; Li-na Zhang, E-mail: zhangln@whu.edu.cn

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CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

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