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1-(1-Alkylsulfonic)-3-methylimidazolium chloride as a reusable Brønsted acid catalyst for the regioselective azidolysis of epoxides under solvent-free conditions

Sobhan Rezayati ,  Eshagh Rezaee Nezhad ,  Rahimeh Hajinasiri

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引用本文: Sobhan Rezayati,  Eshagh Rezaee Nezhad,  Rahimeh Hajinasiri. 1-(1-Alkylsulfonic)-3-methylimidazolium chloride as a reusable Brønsted acid catalyst for the regioselective azidolysis of epoxides under solvent-free conditions[J]. Chinese Chemical Letters, 2016, 27(6): 974-978. doi: 10.1016/j.cclet.2016.02.015 shu
Citation:  Sobhan Rezayati,  Eshagh Rezaee Nezhad,  Rahimeh Hajinasiri. 1-(1-Alkylsulfonic)-3-methylimidazolium chloride as a reusable Brønsted acid catalyst for the regioselective azidolysis of epoxides under solvent-free conditions[J]. Chinese Chemical Letters, 2016, 27(6): 974-978. doi: 10.1016/j.cclet.2016.02.015 shu

1-(1-Alkylsulfonic)-3-methylimidazolium chloride as a reusable Brønsted acid catalyst for the regioselective azidolysis of epoxides under solvent-free conditions

  • a Department of Chemistry, Payame Noor University, P.O. Box 19395-4697, Tehran, Iran;

  • b Chemistry Department, Qaemshahr Branch, Islamic Azad University, P.O. Box 163, Qaemshahr, Iran

  • 基金项目:

    The authors gratefully acknowledge partial support of this study by the Payame Noor University (PNU) of Ilam, I.R. Iran.

摘要: In this study, 1-(1-alkylsulfonic)-3-methylimidazolium chloride as a new, green, and reusable Brønsted acid catalyst was prepared. In this protocol, we used for the regioselective ring-opening reactions of various epoxiodes with sodium azide to afford the corresponding β-azido alcohols in excellent yields and short reaction time under mild and neutral reaction conditions. This method offers several advantages including excellent regioselectivity, clean reactions, simple work-up procedure, a recyclable catalyst, and use of an eco-friendly catalyst.

English

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  • 收稿日期:  2015-12-11
  • 修回日期:  2016-01-11
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