引用本文:
Firouzeh Nemati, Hossein Kiani. Zn(NO3)2·6H2O/2,4,6-trichloro-1,3,5-triazine(TCT)a mild and selective system for nitration of phenols[J]. Chinese Chemical Letters,
2010, 21(4): 403-406.
doi:
10.1016/j.cclet.2009.11.017
Citation: Firouzeh Nemati, Hossein Kiani. Zn(NO3)2·6H2O/2,4,6-trichloro-1,3,5-triazine(TCT)a mild and selective system for nitration of phenols[J]. Chinese Chemical Letters, 2010, 21(4): 403-406. doi: 10.1016/j.cclet.2009.11.017
Citation: Firouzeh Nemati, Hossein Kiani. Zn(NO3)2·6H2O/2,4,6-trichloro-1,3,5-triazine(TCT)a mild and selective system for nitration of phenols[J]. Chinese Chemical Letters, 2010, 21(4): 403-406. doi: 10.1016/j.cclet.2009.11.017
Zn(NO3)2·6H2O/2,4,6-trichloro-1,3,5-triazine(TCT)a mild and selective system for nitration of phenols
摘要:
Certain phenols and naphthols were nitrated regioselectively with Zn(NO3)2·6H2O/TCT in acetonitrile as solvent at room temperature and short reaction time in good yields.The reaction condition was mild.TCT is a cheap and commercially available reagent.It performed as an acid catalyst in this transformation.
English
Zn(NO3)2·6H2O/2,4,6-trichloro-1,3,5-triazine(TCT)a mild and selective system for nitration of phenols
Abstract:
Certain phenols and naphthols were nitrated regioselectively with Zn(NO3)2·6H2O/TCT in acetonitrile as solvent at room temperature and short reaction time in good yields.The reaction condition was mild.TCT is a cheap and commercially available reagent.It performed as an acid catalyst in this transformation.
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Key words:
- Nitration
- / Phenols
- / 2,4,6-Trichloro-1,3,5-triazine
- / Regioselective
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