引用本文:
Long Shen, Yu Cao, Chang Wen Hu. Synthesis and structure of a new 1D infinite neutral chain based on organotin and selenious acid monoethyl ester[J]. Chinese Chemical Letters,
2009, 20(3): 370-373.
doi:
10.1016/j.cclet.2008.12.010
Citation: Long Shen, Yu Cao, Chang Wen Hu. Synthesis and structure of a new 1D infinite neutral chain based on organotin and selenious acid monoethyl ester[J]. Chinese Chemical Letters, 2009, 20(3): 370-373. doi: 10.1016/j.cclet.2008.12.010
Citation: Long Shen, Yu Cao, Chang Wen Hu. Synthesis and structure of a new 1D infinite neutral chain based on organotin and selenious acid monoethyl ester[J]. Chinese Chemical Letters, 2009, 20(3): 370-373. doi: 10.1016/j.cclet.2008.12.010
Synthesis and structure of a new 1D infinite neutral chain based on organotin and selenious acid monoethyl ester
摘要:
A new 1D infinite neutral chain (Ph3SnO2SeOCH2CH3)n (1) based on organotin and selenious acid monoethyl ester has been synthesized successfully and characterized by IR, elemental analysis, and X-ray single-crystal diffraction. In the compound 1, the Sn atom exists in slightly distorted trigonal bipyramidal geometry and the Se center is tri-coordinated with a distorted pyramidal arrangement. It is noted that the synthesis is facile and selenium oxide is directly introduced into synthesis route replacing organoseleninic acid under room temperature.
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关键词:
- Organotin
- / Selenium oxide
- / Crystal structure
English
Synthesis and structure of a new 1D infinite neutral chain based on organotin and selenious acid monoethyl ester
Abstract:
A new 1D infinite neutral chain (Ph3SnO2SeOCH2CH3)n (1) based on organotin and selenious acid monoethyl ester has been synthesized successfully and characterized by IR, elemental analysis, and X-ray single-crystal diffraction. In the compound 1, the Sn atom exists in slightly distorted trigonal bipyramidal geometry and the Se center is tri-coordinated with a distorted pyramidal arrangement. It is noted that the synthesis is facile and selenium oxide is directly introduced into synthesis route replacing organoseleninic acid under room temperature.
-
Key words:
- Organotin
- / Selenium oxide
- / Crystal structure
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