引用本文:
Jin Du Li, Miao Chen, Sheng Liu, Hao Bo Zhang, Zhi Lu Liu. Synthesis and photoactivity of phenylazonaphthalene peptide nucleic acid monomers[J]. Chinese Chemical Letters,
2008, 19(7): 807-810.
doi:
10.1016/j.cclet.2008.05.023
Citation: Jin Du Li, Miao Chen, Sheng Liu, Hao Bo Zhang, Zhi Lu Liu. Synthesis and photoactivity of phenylazonaphthalene peptide nucleic acid monomers[J]. Chinese Chemical Letters, 2008, 19(7): 807-810. doi: 10.1016/j.cclet.2008.05.023
Citation: Jin Du Li, Miao Chen, Sheng Liu, Hao Bo Zhang, Zhi Lu Liu. Synthesis and photoactivity of phenylazonaphthalene peptide nucleic acid monomers[J]. Chinese Chemical Letters, 2008, 19(7): 807-810. doi: 10.1016/j.cclet.2008.05.023
Synthesis and photoactivity of phenylazonaphthalene peptide nucleic acid monomers
摘要:
Phenylazonaphthalene peptide nucleic acid (PNA) monomers were successfully synthesized,and their photoisomerization was examined.The new PNA monomers showed reversible trans-cis isomerization with UV and visible light irradiation,which might be the foundation of photo-regulating the hybridization between PNA containing phenylazonaphthalene unit and DNA.Simultaneously,the fluorescence of the new PNA monomers might make them especially useful as structural probes.
English
Synthesis and photoactivity of phenylazonaphthalene peptide nucleic acid monomers
Abstract:
Phenylazonaphthalene peptide nucleic acid (PNA) monomers were successfully synthesized,and their photoisomerization was examined.The new PNA monomers showed reversible trans-cis isomerization with UV and visible light irradiation,which might be the foundation of photo-regulating the hybridization between PNA containing phenylazonaphthalene unit and DNA.Simultaneously,the fluorescence of the new PNA monomers might make them especially useful as structural probes.
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